about
Synthesis of potential early-stage intermediates in the biosynthesis of FR900482 and mitomycin C.A mixed community of actinomycetes produce multiple antibiotics for the fungus farming ant Acromyrmex octospinosus.Revealing the first uridyl peptide antibiotic biosynthetic gene cluster and probing pacidamycin biosynthesisScope and potential of halogenases in biosynthetic applications.Enzymatic assembly of the bis-indole core of rebeccamycin.Gene expression enabling synthetic diversification of natural products: chemogenetic generation of pacidamycin analogs.Pacidamycin biosynthesis: identification and heterologous expression of the first uridyl peptide antibiotic gene cluster.New pacidamycins biosynthetically: probing N- and C-terminal substrate specificity.Isolating antifungals from fungus-growing ant symbionts using a genome-guided chemistry approach.Exploiting the reaction flexibility of a type III polyketide synthase through in vitro pathway manipulation.New pacidamycin antibiotics through precursor-directed biosynthesis.A convenient one-step synthesis of L-aminotryptophans and improved synthesis of 5-fluorotryptophan.Biogenesis of the unique 4',5'-dehydronucleoside of the uridyl peptide antibiotic pacidamycin.Molecular analysis of the role of tyrosine 224 in the active site of Streptomyces coelicolor RppA, a bacterial type III polyketide synthase.
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