Mechanistic Origin of Antagonist Effects of Usual Anionic Bases (OH−, CO32−) as Modulated by their Countercations (Na+, Cs+, K+) in Palladium-Catalyzed Suzuki-Miyaura Reactions
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Expanding the palette of phenanthridinium cations.Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link.Suzuki-Miyaura cross-coupling of unprotected, nitrogen-rich heterocycles: substrate scope and mechanistic investigation.Transmetalation in the Suzuki-Miyaura coupling: the fork in the trail.Chemoselective boronic ester synthesis by controlled speciation.Accessing 2,1-borazaronaphthols: self-arylation of 1-alkyl-2-aryl-3-bromo-2,1-borazaronaphthalenes.Sustainable catalysis: rational Pd loading on MIL-101Cr-NH2 for more efficient and recyclable Suzuki-Miyaura reactions.Stereospecific cross-coupling of secondary organotrifluoroborates: potassium 1-(benzyloxy)alkyltrifluoroborates.Pd-catalyzed alkynylation of 2-chloroacetates and 2-chloroacetamides with potassium alkynyltrifluoroborates.Modular synthesis of triarylmethanes through palladium-catalyzed sequential arylation of methyl phenyl sulfone.Chemical Potential of the Solvent: A Crucial Player for Rationalizing Host-Guest Affinities.Suzuki-Miyaura Cross-Coupling Reactions of Highly Fluorinated Arylboronic Esters: Catalytic Studies and Stoichiometric Model Reactions on the Transmetallation Step.Synthesis of Polyflourinated Biphenyls; Pushing the Boundaries of Suzuki-Miyaura Cross Coupling with Electron-Poor Substrates.Synthesis of Benzo[c]silole Derivatives Bearing a Tetrasubstituted Exocyclic C=C Double Bond by Palladium-Catalyzed Domino Reactions.Tandem Chemoselective Suzuki-Miyaura Cross-Coupling Enabled by Nucleophile Speciation Control.Tandem metal relay catalysis: from cyclopropene to polysubstituted furan.Exhaustive Suzuki-Miyaura reactions of polyhalogenated heteroarenes with alkyl boronic pinacol esters.Mechanism of Palladium-Catalyzed Suzuki-Miyaura Reactions: Multiple and Antagonistic Roles of Anionic “Bases” and Their CountercationsThe Transmetalation Process in Suzuki-Miyaura Reactions: Calculations Indicate Lower Barrier via Boronate IntermediateAn Efficient and Reliable Catalyst System Using Hemilabile Aphos forB-Alkyl Suzuki-Miyaura Cross-Coupling Reaction with Alkenyl HalidesEfficient Suzuki⁻Miyaura C-C Cross-Couplings Induced by Novel Heterodinuclear Pd-bpydc-Ln Scaffolds
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P2860
Mechanistic Origin of Antagonist Effects of Usual Anionic Bases (OH−, CO32−) as Modulated by their Countercations (Na+, Cs+, K+) in Palladium-Catalyzed Suzuki-Miyaura Reactions
description
im April 2012 veröffentlichter wissenschaftlicher Artikel
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wetenschappelijk artikel
@nl
наукова стаття, опублікована у квітні 2012
@uk
name
Mechanistic Origin of Antagoni ...... lyzed Suzuki-Miyaura Reactions
@en
Mechanistic Origin of Antagoni ...... lyzed Suzuki-Miyaura Reactions
@nl
type
label
Mechanistic Origin of Antagoni ...... lyzed Suzuki-Miyaura Reactions
@en
Mechanistic Origin of Antagoni ...... lyzed Suzuki-Miyaura Reactions
@nl
prefLabel
Mechanistic Origin of Antagoni ...... lyzed Suzuki-Miyaura Reactions
@en
Mechanistic Origin of Antagoni ...... lyzed Suzuki-Miyaura Reactions
@nl
P2860
P356
P1476
Mechanistic Origin of Antagoni ...... lyzed Suzuki-Miyaura Reactions
@en
P2093
Gaëtan Le Duc
P2860
P304
P356
10.1002/CHEM.201200516
P407
P577
2012-04-18T00:00:00Z