Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene

Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene

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http://www.wikidata.org/entity/Q57905797
New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules.Expanding the coordination chemistry of donor-stabilized group-14 metalenes.Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems.The donor-stabilized silylene bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): synthesis, electronic structure, and reactivity.Manganese Silylene Hydride Complexes: Synthesis and Reactivity with Ethylene to Afford Silene Hydride Complexes.Donor-Stabilized Silylene/Phosphine-Supported Carbon(0) Center with High Electron Density.Unprecedented solvent induced inter-conversion between monomeric and dimeric silylene-zinc iodide adducts.Facile access to silicon-functionalized bis-silylene titanium(II) complexes.Synthesis and unexpected coordination of a silicon(II)-based SiCSi pincerlike arene to palladium.Mixed valence η6-arene cobalt(I) and cobalt(II) compound.Stepwise isolation of an unprecedented silylene supported dinuclear gold(i) cation with aurophilic interaction.On the Reactivity of the Silylene PhC(NtBu)2SiNPh2toward Organic SubstratesMetal free and selective activation of one C–F bond in a bound CF3 groupFacile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene LigandA début for base stabilized monoalkylsilylenesSyntheses of Iron Carbonyl N-Heterocyclic Stannylene Complexes
P2860

Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene

Item
http://www.wikidata.org/entity/Q57905797
description
im Juni 2011 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована в червні 2011
@uk
name
Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene
@en
Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene
@nl
type
label
Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene
@en
Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene
@nl
prefLabel
Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene
@en
Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene
@nl
P1433
P1476
P2093
P304
P31
P356
P407
P433
P478
P50
P577
P698
P356
P1433
P1476
Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene
@en
P2093
P304
P31
P356
P407
P433
P478
P50
P577
P698