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Low-valent organometallics--synthesis, reactivity, and potential applications[2+2+1] cycloadditions of bis(dialkylamino)acetylenes with SiI2(Idip): syntheses and reactivity studies of unprecedented 2,3,4,5-tetraamino-1 H-siloles.A Fully Phosphane-Substituted Disilene.Chemical tricks to stabilize silanones and their heavier homologues with E=O bonds (E=Si-Pb): from elusive species to isolable building blocks.Carbene-Stabilized Main Group Radicals and Radical IonsDonor-acceptor chemistry in the main group.Cations and dications of heavier group 14 elements in low oxidation states.An Electrophilic Carbene-Anchored Silylene-Phosphinidene.Imidazoliophosphines are true N-heterocyclic carbene (NHC)-phosphenium adducts.Group 13 ligand supported heavy-metal complexes: first structural evidence for gallium-lead and gallium-mercury bonds.Diazabutadiene complexes of selenium as Se2+ transfer reagents.Anchoring of silyl donors on a N-heterocyclic carbene through the cobalt-mediated silylation of benzylic C-H bonds.A theoretical study on the ring expansion of NHCs by silanes.Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene.A stable singlet biradicaloid siladicarbene: (L:)2Si.Expanding the coordination chemistry of donor-stabilized group-14 metalenes.The first bismuth-NHC complexes.Recent advances in the field of main-group mono- and diatomic "allotropes" stabilised by neutral ligands.Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+.Dative bonds in main-group compounds: a case for fewer arrows!Formation of trichlorosilyl-substituted carbon-centered stable radicals through the use of π-accepting carbenes.Controlled growth of dichlorogermanium oligomers from Lewis basic hosts.Reduction of the dihalocyclopentasilanes. A quest for a homocyclic silylene.A Route to Base Coordinate Silicon Difluoride and the Silicon Trifluoride Radical.Thermal Synthesis of Perchlorinated Oligosilanes: A Fresh Look at an Old Reaction.Unraveling the Amine-Induced Disproportionation Reaction of Perchlorinated Silanes-A DFT Study.A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural characterization of a silylsilylene.Si=Si Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene.The donor-stabilized silylene bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): synthesis, electronic structure, and reactivity.Silavinylidene stabilized by an N-heterocyclic carbene: a theoretically predicted stable molecule.A Disilene Base Adduct with a Dative Si-Si Single Bond.Trapping a Silicon(I) Radical with Carbenes: A Cationic cAAC-Silicon(I) Radical and an NHC-Parent-Silyliumylidene Cation.From an Isolable Acyclic Phosphinosilylene Adduct to Donor-Stabilized Si=E Compounds (E=O, S, Se).Adduct Formation, B-H Activation and Ring Expansion at Room Temperature from Reactions of HBcat with NHCs.Nature of Bonding in Donor-Acceptor Interactions Exemplified by Complexes of N-Heterocyclic Carbenes with 1,2,5-Telluradiazoles.Silylene-Functionalized N-Heterocyclic Carbene (Si-NHC).Carbene stabilized interconnected bis-germylene and its silicon analogue with small methyl substituents.Reactivity of NHC Alane Adducts towards N-Heterocyclic Carbenes and Cyclic (Alkyl)(amino)carbenes: Ring Expansion, Ring Opening, and Al-H Bond Activation.Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes.An NHC-Silyl-NHC Pincer Ligand for the Oxidative Addition of C-H, N-H, and O-H Bonds to Cobalt(I) Complexes.
P2860
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P2860
description
scientific article published on 01 January 2009
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована в липні 2009
@uk
name
Lewis Base Stabilized Dichlorosilylene
@en
Lewis Base Stabilized Dichlorosilylene
@nl
type
label
Lewis Base Stabilized Dichlorosilylene
@en
Lewis Base Stabilized Dichlorosilylene
@nl
prefLabel
Lewis Base Stabilized Dichlorosilylene
@en
Lewis Base Stabilized Dichlorosilylene
@nl
P50
P356
P1476
Lewis base stabilized dichlorosilylene
@en
P2093
Herbert W Roesky
Sebastian Merkel
P304
P356
10.1002/ANIE.200901766
P407
P577
2009-01-01T00:00:00Z