Carbon(sp3)Fluorine Bond-Forming Reductive Elimination from Palladium(IV) Complexes
about
Reductive functionalization of a rhodium(III)-methyl bond by electronic modification of the supporting ligand.Studying regioisomer formation in the Pd-catalyzed fluorination of aryl triflates by deuterium labeling.Catalytic enantioselective cyclization and C3-fluorination of polyenes.Transition metal-catalyzed fluorination of multi carbon-carbon bonds: new strategies for fluorinated heterocycles.Introduction of fluorine and fluorine-containing functional groups.Experiment and computation: a combined approach to study the reactivity of palladium complexes in oxidation states 0 to IV.Carbon-Hydrogen (C-H) Bond Activation at Pd(IV): A Frontier in C-H Functionalization Catalysis.Palladium-catalyzed directing group-assisted C8-triflation of naphthalenes.Vanadium-Catalyzed C(sp(3))-H Fluorination Reactions.Ligand-Enabled Stereoselective β-C(sp(3))-H Fluorination: Synthesis of Unnatural Enantiopure anti-β-Fluoro-α-amino Acids.Pd-catalyzed C-H fluorination with nucleophilic fluoride.Halide-Dependent Mechanisms of Reductive Elimination from Gold(III)The development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes.Investigations into Transition Metal Catalyzed Arene Trifluoromethylation ReactionsVisible light-promoted metal-free C-H activation: diarylketone-catalyzed selective benzylic mono- and difluorination.Anion-Dependent Switch in C-X Reductive Elimination Diastereoselectivity.Visible light-promoted metal-free sp(3)-C-H fluorination.Palladium-Catalyzed C-H Arylation Using Aryltrifluoroborates in Conjunction with a Mn(III) Oxidant under Mild Conditions.Regioselective palladium-catalyzed intramolecular oxidative aminofluorination of unactivated alkenes.Taming the High Reactivity of Gold(III) Fluoride: Fluorido Gold(III) Complexes with N-Based Ligands.Unprecedented 1,3-migration of the aryl ligand in metallacyclic aryl α-naphthyl Pt(IV) difluorides to produce β-arylnaphthyl Pt(II) complexes.The Versatile Behavior of Platinum Alkyne Complexes towards XeF2 : Formation of Fluorovinyl and Fluorido Complexes.A Hydrazone-Based exo-Directing-Group Strategy for β C-H Oxidation of Aliphatic Amines.A DFT Study on the Conversion of Aryl Iodides to Alkyl Iodides: Reductive Elimination of R-I from Alkylpalladium Iodide Complexes with Accessible β-Hydrogens.Stereoselective construction of sterically hindered oxaspirocycles via chiral bidentate directing group-mediated C(sp3)-O bond formation.Selective aryl-fluoride reductive elimination from a platinum(IV) complex.
P2860
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P2860
Carbon(sp3)Fluorine Bond-Forming Reductive Elimination from Palladium(IV) Complexes
description
scientific article published on 28 February 2012
@en
наукова стаття, опублікована в лютому 2012
@uk
name
Carbon(sp3)Fluorine Bond-Forming Reductive Elimination from Palladium(IV) Complexes
@en
type
label
Carbon(sp3)Fluorine Bond-Forming Reductive Elimination from Palladium(IV) Complexes
@en
prefLabel
Carbon(sp3)Fluorine Bond-Forming Reductive Elimination from Palladium(IV) Complexes
@en
P2860
P356
P1476
Carbon(sp(3))-fluorine bond-forming reductive elimination from palladium(IV) complexes
@en
P2093
J Brannon Gary
Joy M Racowski
P2860
P304
P356
10.1002/ANIE.201107816
P407
P50
P577
2012-02-28T00:00:00Z