Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates. A Practical Method for Preparing Allylic Amines and Congeners of High Enantiomeric Purity
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Molecular rearrangements in the construction of complex moleculesMechanism-based Inactivation by Aromatization of the Transaminase BioA Involved in Biotin Biosynthesis in Mycobaterium tuberculosisLarge-scale asymmetric synthesis of the bioprotective agent JP4-039 and analogsAllylic Amines as Key Building Blocks in the Synthesis of (E)-Alkene Peptide IsosteresTransition-state charge stabilization through multiple non-covalent interactions in the guanidinium-catalyzed enantioselective Claisen rearrangementCatalytic asymmetric synthesis of allylic thiol derivatives.Enantioselective synthesis and application to the allylic imidate rearrangement of amine-coordinated palladacycle catalysts of cobalt sandwich complexesDesign and synthesis of potential mechanism-based inhibitors of the aminotransferase BioA involved in biotin biosynthesis.Catalytic asymmetric Claisen rearrangement of enolphosphonates: construction of vicinal tertiary and all-carbon quaternary centersCatalytic Asymmetric Synthesis of Branched Chiral Allylic Phenyl Ethers from (E)-Allylic Alcohols.Non-racemic (scalemic) planar-chiral five-membered metallacycles: routes, means, and pitfalls in their synthesis and characterization.Formation and utility of azasilacyclopentadienes derived from silacyclopropenes and nitrilesAsymmetric Synthesis of (+)-Iso-6-Cassine via Stereoselective Intramolecular Amidomercuration.Palladacycles: Effective Catalysts for a Multicomponent Reaction with Allylpalladium(II)-Intermediates.Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications.Toward a symphony of reactivity: cascades involving catalysis and sigmatropic rearrangementsRecent advances in the Overman rearrangement: synthesis of natural products and valuable compounds.Scope and mechanism of formal S(N)2' substitution reactions of a monomeric imidozirconium complex with allylic electrophiles.A formal [3,3]-sigmatropic rearrangement route to quaternary alpha-vinyl amino acids: use of allylic N-PMP trifluoroacetimidates.An Efficient Synthesis of de novo Imidates via Aza-Claisen Rearrangements of N-Allyl Ynamides.Palladium(II)-catalyzed enantioselective synthesis of 2-vinyl oxygen heterocyclesHighly efficient gold(I)-catalyzed Overman rearrangement in water.Mechanism of the cobalt oxazoline palladacycle (COP)-catalyzed asymmetric synthesis of allylic esters.Enantioselective propargylic [1,3]-rearrangements: copper-catalyzed O-to-N migrations toward C-N bond formation.Rh(II)-catalyzed reaction of alpha-diazocarbonyl compounds bearing beta-trichloroacetylamino substituent: C-H insertion versus 1,2-H shift.Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols.Microwave accelerated aza-Claisen rearrangement.Heteromultimetallic catalysis for sustainable organic syntheses.Rhodium-Catalyzed Diastereoselective Cyclization of Allenyl-Sulfonylcarbamates: A Stereodivergent Approach to 1,3-Aminoalcohol Derivatives.Stereoselective Dynamic Cyclization of Allylic Azides: Synthesis of Tetralins, Chromanes, and Tetrahydroquinolines.Rh-Catalyzed Chemo- and Enantioselective Hydrogenation of Allylic Hydrazones.Enantioselective sp(3) C-H alkylation of γ-butyrolactam by a chiral Ir(I) catalyst for the synthesis of 4-substituted γ-amino acids.Enantioselective synthesis of β-substituted chiral allylic amines via Rh-catalyzed asymmetric hydrogenation.A highly enantioselective Overman rearrangement through asymmetric counteranion-directed palladium catalysis.Unusual mechanisms in Claisen rearrangements: an ionic fragmentation leading to a meta-selective rearrangement.The Allylic Trihaloacetimidate RearrangementThe Orthoester Johnson-Claisen Rearrangement in the Synthesis of Bioactive Molecules, Natural Products, and Synthetic Intermediates - Recent AdvancesPalladium-Catalyzed Tunable Functionalization of Allylic Imidates: Regioselective Aminodiacetoxylation and AziridinationStereoselective synthesis of hydroxylated 3-aminoazepanes using a multi-bond forming, three-step tandem processStereoselective synthesis of polyhydroxylated aminocyclohexanes
P2860
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P2860
Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates. A Practical Method for Preparing Allylic Amines and Congeners of High Enantiomeric Purity
description
2003 nî lūn-bûn
@nan
2003 թուականի Հոկտեմբերին հրատարակուած գիտական յօդուած
@hyw
2003 թվականի հոտեմբերին հրատարակված գիտական հոդված
@hy
2003年の論文
@ja
2003年論文
@yue
2003年論文
@zh-hant
2003年論文
@zh-hk
2003年論文
@zh-mo
2003年論文
@zh-tw
2003年论文
@wuu
name
Catalytic Asymmetric Rearrange ...... rs of High Enantiomeric Purity
@ast
Catalytic Asymmetric Rearrange ...... rs of High Enantiomeric Purity
@en
type
label
Catalytic Asymmetric Rearrange ...... rs of High Enantiomeric Purity
@ast
Catalytic Asymmetric Rearrange ...... rs of High Enantiomeric Purity
@en
prefLabel
Catalytic Asymmetric Rearrange ...... rs of High Enantiomeric Purity
@ast
Catalytic Asymmetric Rearrange ...... rs of High Enantiomeric Purity
@en
P356
P1476
Catalytic Asymmetric Rearrange ...... rs of High Enantiomeric Purity
@en
P2093
Carolyn E. Anderson
Larry E. Overman
P304
12412-12413
P356
10.1021/JA037086R
P407
P577
2003-10-01T00:00:00Z