Transition-state charge stabilization through multiple non-covalent interactions in the guanidinium-catalyzed enantioselective Claisen rearrangement
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Arginine mimetics using α-guanidino acids: introduction of functional groups and stereochemistry adjacent to recognition guanidiniums in peptidesChiral N-Heterocyclic Carbene Catalyzed Annulations of Enals and Ynals with Stable Enols: A Highly Enantioselective Coates-Claisen Rearrangement.Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement.Aromatic interactions as control elements in stereoselective organic reactions.Catalytic asymmetric Claisen rearrangement of enolphosphonates: construction of vicinal tertiary and all-carbon quaternary centersCarbanion-accelerated Claisen rearrangements: asymmetric induction with chiral phosphorus-stabilized anionsPractical Organocatalytic Synthesis of Functionalized Non-C2-Symmetrical Atropisomeric Biaryls.A Computational Study of the Origin of Stereoinduction in NHC-Catalyzed Annulation Reactions of α,β-Unsaturated Acyl Azoliums.Aromatic Claisen Rearrangements of O-prenylated tyrosine and model prenyl aryl ethers: Computational study of the role of water on acceleration of Claisen rearrangements.Acceleration of an aromatic Claisen rearrangement via a designed spiroligozyme catalyst that mimics the ketosteroid isomerase catalytic dyad.Multidimensional steric parameters in the analysis of asymmetric catalytic reactions.The chemistry and biology of organic guanidine derivatives.The cation-π interaction.Direct construction of vicinal all-carbon quaternary stereocenters in natural product synthesis.Computing organic stereoselectivity - from concepts to quantitative calculations and predictions.The Cation-π Interaction in Small-Molecule Catalysis.Catalytic, asymmetric difluorination of alkenes to generate difluoromethylated stereocentersSynergistic Ion-Binding Catalysis Demonstrated via an Enantioselective, Catalytic [2,3]-Wittig Rearrangement.Enantioselective thiourea-catalyzed intramolecular cope-type hydroamination.Copper(II)- and palladium(II)-catalyzed enantioselective Claisen rearrangement of allyloxy- and propargyloxy-indoles to quaternary oxindoles and spirocyclic lactones.Mechanistic basis for high stereoselectivity and broad substrate scope in the (salen)Co(III)-catalyzed hydrolytic kinetic resolution.Asymmetric synthesis of allenyl oxindoles and spirooxindoles by a catalytic enantioselective Saucy-Marbet Claisen rearrangement.Thiourea-catalysed ring opening of episulfonium ions with indole derivatives by means of stabilizing non-covalent interactions.The tandem intermolecular hydroalkoxylation/Claisen rearrangement.Bicyclic guanidinium-catalyzed enantioselective phase-transfer alkylation: direct access to pyrroloindolines and furoindolines.Molecular assembly of an achiral phosphine and a chiral primary amine: a highly efficient supramolecular catalyst for the enantioselective Michael reaction of aldehydes with maleimides.Aromatic interactions in asymmetric catalysis: control of enantioselectivity in Diels-Alder reactions catalysed by camphor-derived hydrazides.Exploiting non-covalent π interactions for catalyst design.An Organocatalytic Cope Rearrangement.Computational insight into the cooperative role of non-covalent interactions in the aza-Henry reaction catalyzed by quinine derivatives: mechanism and enantioselectivity.Claisen rearrangements of benzyl vinyl ethers: theoretical investigation of mechanism, substituent effects, and regioselectivity.Catalytic enantioselective alkylation of sulfenate anions to chiral heterocyclic sulfoxides using halogenated pentanidium salts.Three-dimensional correlation of steric and electronic free energy relationships guides asymmetric propargylation.Bioinspired organocatalytic asymmetric reactions.A mechanistic study of the Lewis acid–Brønsted base–Brønsted acid catalysed asymmetric Michael addition of diethyl malonate to cyclohexenoneIntramolecular hydrogen bonding guides a cationic amphiphilic organocatalyst to highly stereoselective aldol reactions in water
P2860
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P2860
Transition-state charge stabilization through multiple non-covalent interactions in the guanidinium-catalyzed enantioselective Claisen rearrangement
description
2011 nî lūn-bûn
@nan
2011 թուականի Մարտին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի մարտին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Transition-state charge stabil ...... elective Claisen rearrangement
@ast
Transition-state charge stabil ...... elective Claisen rearrangement
@en
Transition-state charge stabil ...... elective Claisen rearrangement
@nl
type
label
Transition-state charge stabil ...... elective Claisen rearrangement
@ast
Transition-state charge stabil ...... elective Claisen rearrangement
@en
Transition-state charge stabil ...... elective Claisen rearrangement
@nl
prefLabel
Transition-state charge stabil ...... elective Claisen rearrangement
@ast
Transition-state charge stabil ...... elective Claisen rearrangement
@en
Transition-state charge stabil ...... elective Claisen rearrangement
@nl
P2860
P356
P1476
Transition-state charge stabil ...... elective Claisen rearrangement
@en
P2093
Christopher Uyeda
Eric N Jacobsen
P2860
P304
P356
10.1021/JA110842S
P407
P577
2011-03-10T00:00:00Z