Three-dimensional correlation of steric and electronic free energy relationships guides asymmetric propargylation.
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Enantiodivergent Fluorination of Allylic Alcohols: Data Set Design Reveals Structural Interplay between Achiral Directing Group and Chiral Anion.Designer substrate library for quantitative, predictive modeling of reaction performanceDevelopment and Investigation of a Site Selective Palladium-Catalyzed 1,4-Difunctionalization of Isoprene using Pyridine-Oxazoline Ligands.Enantioselective synthesis of anti- and syn-homopropargyl alcohols via chiral Brønsted acid catalyzed asymmetric allenylboration reactions.Chromium(II)-catalyzed enantioselective arylation of ketonesLigand-controlled asymmetric arylation of aliphatic α-amino anion equivalents.Multidimensional steric parameters in the analysis of asymmetric catalytic reactions.Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate.Parameterization of phosphine ligands demonstrates enhancement of nickel catalysis via remote steric effects.Parametrization of Non-covalent Interactions for Transition State Interrogation Applied to Asymmetric Catalysis.Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study.Analyzing site selectivity in Rh2(esp)2-catalyzed intermolecular C-H amination reactions.Chiral Brønsted Acid-Catalyzed Enantioselective α-Amidoalkylation Reactions: A Joint Experimental and Predictive Study.Electronic tuning of site-selectivity.C-Propargylation Overrides O-Propargylation in Reactions of Propargyl Chloride with Primary Alcohols: Rhodium-Catalyzed Transfer Hydrogenation.Diastereo- and enantioselective reactions of bis(pinacolato)diboron, 1,3-enynes, and aldehydes catalyzed by an easily accessible bisphosphine-Cu complex.Mini-ISES identifies promising carbafructopyranose-based salens for asymmetric catalysis: Tuning ligand shape via the anomeric effect.Enantioselective Heck arylations of acyclic alkenyl alcohols using a redox-relay strategy.Enantioselective aza-Michael addition of imides by using an integrated strategy involving the synthesis of a family of multifunctional catalysts, usage of multiple catalysis, and rational design of experiment.Multidimensional Correlations in Asymmetric Catalysis through Parameterization of Uncatalyzed Transition States.Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization.Silver-catalyzed allenylation and enantioselective propargylation reactions of ketones.Highly enantioselective sulfa-Michael addition reactions using N-heterocyclic carbene as a non-covalent organocatalyst.Regularized regression analysis of digitized molecular structures in organic reactions for quantification of steric effects.Asymmetric Conjugate Addition of Benzofuran-2-ones to Alkyl 2-Phthalimidoacrylates: Modeling Structure-Stereoselectivity Relationships with Steric and Electronic Parameters.Study on the Catalytic Behavior of Bifunctional Hydrogen-Bonding Catalysts Guided by Free Energy Relationship Analysis of Steric Parameters.Ligand-Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins.Quantitative structure-activity relationship correlation between molecular structure and the Rayleigh enantiomeric enrichment factor.Using IR vibrations to quantitatively describe and predict site-selectivity in multivariate Rh-catalyzed C-H functionalization.Methane activation by metal-free Lewis acid centers only--a computational design and mechanism study.Copper-catalyzed synthesis of allenylboronic acids. Access to sterically encumbered homopropargylic alcohols and amines by propargylboration.Predictive and mechanistic multivariate linear regression models for reaction development.Uncovering Subtle Ligand Effects of Phosphines Using Gold(I) Catalysis.Enantioselective fluorination of homoallylic alcohols enabled by the tuning of non-covalent interactionsMachine learning meets volcano plots: computational discovery of cross-coupling catalystsCorrelating sterics in catalysisCombining traditional 2D and modern physical organic-derived descriptors to predict enhanced enantioselectivity for the key aza-Michael conjugate addition in the synthesis of Prevymis™ (letermovir)
P2860
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P2860
Three-dimensional correlation of steric and electronic free energy relationships guides asymmetric propargylation.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年学术文章
@wuu
2011年学术文章
@zh
2011年学术文章
@zh-cn
2011年学术文章
@zh-hans
2011年学术文章
@zh-my
2011年学术文章
@zh-sg
2011年學術文章
@yue
2011年學術文章
@zh-hant
name
Three-dimensional correlation ...... des asymmetric propargylation.
@en
Three-dimensional correlation ...... des asymmetric propargylation.
@nl
type
label
Three-dimensional correlation ...... des asymmetric propargylation.
@en
Three-dimensional correlation ...... des asymmetric propargylation.
@nl
prefLabel
Three-dimensional correlation ...... des asymmetric propargylation.
@en
Three-dimensional correlation ...... des asymmetric propargylation.
@nl
P2860
P356
P1433
P1476
Three-dimensional correlation ...... des asymmetric propargylation.
@en
P2093
Kaid C Harper
Matthew S Sigman
P2860
P304
P356
10.1126/SCIENCE.1206997
P407
P577
2011-09-01T00:00:00Z