about
Gold catalysis: catalyst oxidation state dependent dichotomy in the cyclization of furan-yne systems with aromatic tethers.Atom-efficient gold(I)-chloride-catalyzed synthesis of α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols: substrate scope and experimental and theoretical mechanistic investigation.Mechanism of gold(I)-catalyzed rearrangements of acetylenic amine-N-oxides: computational investigations lead to a new mechanism confirmed by experiment.Gold-catalyzed 1,2-migration of silicon, tin, and germanium en route to C-2 substituted fused pyrrole-containing heterocycles.Gold-catalyzed double migration-benzannulation cascade toward naphthalenes.Metal-catalyzed 1,2-shift of diverse migrating groups in allenyl systems as a new paradigm toward densely functionalized heterocycles.1,2-Halogen migration in haloallenyl ketones: regiodivergent synthesis of halofurans.Multisubstituted N-fused heterocycles via transition metal-catalyzed cycloisomerization protocolsGold(I)-catalyzed synthesis of (1E,3E)-dienes from propargylic esters.Ligand effects in homogeneous Au catalysis.Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis.Gold α-oxo carbenoids in catalysis: catalytic oxygen-atom transfer to alkynes.When cyclopropenes meet gold catalysts.Allenes and computational chemistry: from bonding situations to reaction mechanisms.Exploring the gold mine: [Au]-catalysed transformations of enynals, enynones and enynols.Computation-guided development of Au-catalyzed cycloisomerizations proceeding via 1,2-Si or 1,2-H migrations: regiodivergent synthesis of silylfurans.Gold-catalyzed intramolecular allylation of silyl alkynes induced by silane alcoholysis.Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.A Robust Dimethylgold(III) Complex Stabilized by a 2-Pyridyl-2-pyrrolide Ligand.Metal-catalyzed cycloetherification reactions of β,γ- and γ,δ-allendiols: chemo-, regio-, and stereocontrol in the synthesis of oxacycles.Gold(I)-catalysed synthesis of a furan analogue of thiamine pyrophosphate.Cross-coupling/cyclization reactions of two different allenic moieties.Gold-catalyzed synthesis of iodofulvenes.Controlled heterocyclization/cross-coupling domino reaction of β,γ-allendiols and α-allenic esters: method and mechanistic insight for the preparation of functionalized buta-1,3-dienyl dihydropyrans.On the Accessible Reaction Channels of Vinyl Gold(I) Species: π- and σ-Pathways.Intramolecular anti-Phosphinoauration of Alkynes: An FLP-Motivated Approach to Stable Aurated Phosphindolium Complexes.Gold-alkynyls in catalysis: alkyne activation, gold cumulenes and nuclearity.Efficient addition of alcohols, amines and phenol to unactivated alkenes by Au(III) or Pd(II) stabilized by CuCl2.Cyclization of gold acetylides: synthesis of vinyl sulfonates via gold vinylidene complexes.Direct Synthesis of α-Allenols from TMS-Protected Alkynes and Aldehydes Mediated by Tetrabutylammonium Fluoride.Metal-Catalyzed Cyclization Reactions of 2,3,4-Trien-1-ols: A Joint Experimental-Computational Study.Dual Gold Catalysis: Bidirectional Processes and Tandem sp3 -C-H Insertion Reactions.Gold-Catalyzed Formal Cyclisation/Dimerization of Thiophene-Tethered Diynes.Study of substrate dependence on the chemoselectivity of the gold-catalysed cycloisomerisation of aryl substituted 1,7-enynes.Cyclopropyl carbinol rearrangement for benzo-fused nitrogen ring synthesis.Gold-catalyzed tandem intramolecular heterocyclization/Petasis-Ferrier rearrangement of 2-(prop-2-ynyloxy)benzaldehydes as an expedient route to benzo[b]oxepin-3(2 H)-ones.Controlled rearrangement of lactam-tethered allenols with brominating reagents: a combined experimental and theoretical study on α- versus β-keto lactam formation.Coinage Metal Complexes of Phosphonite Analogues of 2-Diphenylphosphino-1,1′-binaphthyl (H-MOP) and 2-Diphenylphosphino-2′-methoxy-1,1′-binaphthyl (MeO-MOP)Catalytic gold rush
P2860
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P2860
description
2005 nî lūn-bûn
@nan
2005 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2005 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2005年の論文
@ja
2005年学术文章
@wuu
2005年学术文章
@zh-cn
2005年学术文章
@zh-hans
2005年学术文章
@zh-my
2005年学术文章
@zh-sg
2005年學術文章
@yue
name
The golden gate to catalysis.
@ast
The golden gate to catalysis.
@en
The golden gate to catalysis.
@nl
type
label
The golden gate to catalysis.
@ast
The golden gate to catalysis.
@en
The golden gate to catalysis.
@nl
prefLabel
The golden gate to catalysis.
@ast
The golden gate to catalysis.
@en
The golden gate to catalysis.
@nl
P2860
P356
P1476
The golden gate to catalysis
@en
P2093
Norbert Krause
P2860
P304
P356
10.1039/B416516K
P577
2005-01-10T00:00:00Z