Computation-guided development of Au-catalyzed cycloisomerizations proceeding via 1,2-Si or 1,2-H migrations: regiodivergent synthesis of silylfurans.
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1,2-boryl migration empowers regiodivergent synthesis of borylated furans.On the validity of Au-vinylidenes in the gold-catalyzed 1,2-migratory cycloisomerization of skipped propargylpyridines.Synthesis of furans and pyrroles via migratory and double migratory cycloisomerization reactions of homopropargylic aldehydes and imines.Stereocontrolled 1,3-phosphatyloxy and 1,3-halogen migration relay toward highly functionalized 1,3-dienes.Highly selective catalyst-dependent competitive 1,2-C→C, -O→C, and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates.Transition metal-mediated synthesis of monocyclic aromatic heterocyclesGold α-oxo carbenoids in catalysis: catalytic oxygen-atom transfer to alkynes.Allenes and computational chemistry: from bonding situations to reaction mechanisms.New Approaches to the Synthesis of Metal Carbenes.Silver & gold-catalyzed routes to furans and benzofurans.C-C Bond Migration in the Cycloisomerization of 1,6-Enynes.A new reactivity mode for the diazo group: diastereoselective 1,3-aminoalkylation reaction of β-amino-α-diazoesters to give triazolines.Gold(I)-catalyzed formation of furans from γ-acyloxyalkynyl ketones.Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers.Solvent- and ligand-induced switch of selectivity in gold(I)-catalyzed tandem reactions of 3-propargylindoles.Isotopic labelling studies for a gold-catalysed skeletal rearrangement of alkynyl aziridines.Direct α-vinylidenation of aldehydes and subsequent cascade: gold and amine catalysts work synergistically.C-C bond migration in the cycloisomerization of oxygen-tethered 1,6-enynes.Copper/P(tBu)3 -Mediated Regiospecific Synthesis of Fused Furans and Naphthofurans.Synthesis of diversely substituted 2-(furan-3-yl)acetates from allenols through cascade carbonylations.Gold(I)-catalyzed regiodivergent rearrangements: 1,2- and 1,2'-alkyl migration in skipped alkynyl ketones.Palladium(II)-catalyzed stereospecific three-component domino reactions of diyne-enones, nucleophiles, and vinyl ketones.Facile synthesis of substituted 3-aminofurans through a tandem reaction of N-sulfonyl-1,2,3-triazoles with propargyl alcohols.Gold(I)-Catalyzed Cycloisomerization of ortho-(Propargyloxy)arenemethylenecyclopropanes Controlled by Adjacent Substituents at Aromatic Rings.A [3 + 2]-annulation approach to tetrasubstituted furans from MBH-carbonates of acetylenic aldehydes via sequential substitution/cycloisomerization.Synthesis of Alkynylmethylidene-benzoxasiloles through a Rhodium-Catalyzed Cycloisomerization Involving 1,2-Silicon and 1,3-Carbon Migration.Mechanistic Understanding of the Divergent Cyclizations of o-Alkynylbenzaldehyde Acetals and Thioacetals Catalyzed by Metal Halides.A density functional theory study of the mechanism of isomerization of 2-aryl-2H-azirines to 2,3-disubstituted indoles by FeCl2 and Rh2(O2CCF3)4.Mechanistic insight into water-modulated cycloisomerization of enynyl esters using an Au(I) catalyst.An efficient synthesis of 2,5-diimino-furans via Pd-catalyzed cyclization of bromoacrylamides and isocyanides.Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFTMechanism of the N-protecting group dependent annulations of 3-aryloxy alkynyl indoles under gold catalysis: a computational studyMechanism of the Transition-Metal-Catalyzed Hydroarylation of Bromo-Alkynes Revisited: Hydrogen versus Bromine Migration
P2860
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P2860
Computation-guided development of Au-catalyzed cycloisomerizations proceeding via 1,2-Si or 1,2-H migrations: regiodivergent synthesis of silylfurans.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Computation-guided development ...... gent synthesis of silylfurans.
@en
type
label
Computation-guided development ...... gent synthesis of silylfurans.
@en
prefLabel
Computation-guided development ...... gent synthesis of silylfurans.
@en
P2093
P2860
P356
P1476
Computation-guided development ...... gent synthesis of silylfurans.
@en
P2093
Alexander S Dudnik
Vladimir Gevorgyan
Yuanzhi Xia
P2860
P304
P356
10.1021/JA910290C
P407
P577
2010-06-01T00:00:00Z