Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.
about
Addition of CF3 across unsaturated moieties: a powerful functionalization toolVersatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes.Radical aryl migration enables diversity-oriented synthesis of structurally diverse medium/macro- or bridged-rings.Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagentEnantioselective functionalization of radical intermediates in redox catalysis: copper-catalyzed asymmetric oxytrifluoromethylation of alkenes.Introduction of fluorine and fluorine-containing functional groups.Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents.Recent advances in trifluoromethylation reactions with electrophilic trifluoromethylating reagents.Catalysis of Radical Reactions: A Radical Chemistry Perspective.Copper-catalyzed oxidative carbon-heteroatom bond formation: a recent update.Catalytic Intramolecular Aminofluorination, Oxyfluorination, and Carbofluorination with a Stable and Versatile Hypervalent Fluoroiodine Reagent.Visible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with waterThe dual role of thiourea in the thiotrifluoromethylation of alkenes.Product Control in Alkene Trifluoromethylation: Hydrotrifluoromethylation, Vinylic Trifluoromethylation, and Iodotrifluoromethylation using Togni Reagent.Iron-catalyzed trifluoromethylation with concomitant C-C bond formation via 1,2-migration of an aryl group.Copper-mediated deoxygenative trifluoromethylation of benzylic xanthates: generation of a C-CF(3) bond from an O-based electrophile.Efficient copper-catalyzed direct intramolecular aminotrifluoromethylation of unactivated alkenes with diverse nitrogen-based nucleophiles.Directing-group-assisted copper-catalyzed olefinic trifluoromethylation of electron-deficient alkenes.Copper-catalyzed trifluoromethylation-cyclization of enynes: highly regioselective construction of trifluoromethylated carbocycles and heterocycles.Copper-catalyzed synthesis of trifluoromethyl-substituted isoxazolines.Achiral Pyridine Ligand-Enabled Enantioselective Radical Oxytrifluoromethylation of Alkenes with Alcohols.Copper-catalyzed trifluoromethylation of N-arylacrylamides "on water" at room temperature.Copper-Catalyzed Three-Component Carboazidation of Alkenes with Acetonitrile and Sodium Azide.Metal-free and light-promoted radical iodotrifluoromethylation of alkenes with Togni reagent as the source of CF3 and iodine.Selective Oxytrifluoromethylation of Allylamines with CO2.Iron-Catalyzed Decarboxylative Alkyl Etherification of Vinylarenes with Aliphatic Acids as the Alkyl Source.A redox-economical synthesis of trifluoromethylated enamides with the Langlois reagent.Copper-catalyzed cyclic oxytrifluoromethylation of 2,3-allenoic acids to trifluoromethylated butenolides.Copper-catalyzed acyltrifluoromethylation of alkenes: rapid access to trifluoroethyl indanones and related compounds.Copper-catalyzed trifluoromethylation of trisubstituted allylic and homoallylic alcohols.Iron-catalyzed trifluoromethylation of enamide.Copper-catalyzed arylsulfonylation of N-arylsulfonyl-acrylamides with arylsulfonohydrazides: synthesis of sulfonated oxindoles.Enhancement of neighbouring-group participation in Cu0-promoted cross-coupling gem-difluoromethylenation of aryl/alkenyl halides with 1,3-azolic difluoromethyl bromides.Copper-catalyzed cascade cyclization of 1,5-enynes via consecutive trifluoromethylazidation/diazidation and click reaction: self-assembly of triazole fused isoindolines.PhI(OAc)(2) -mediated radical trifluoromethylation of vinyl azides with Me(3)SiCF(3).Copper-catalysed cyanoalkylative cycloetherification of alkenes to 1,3-dihydroisobenzofurans: development and application to the synthesis of citalopram.Copper-Catalyzed Formal [2+2+1] Heteroannulation of Alkenes, Alkylnitriles, and Water: Method Development and Application to a Total Synthesis of (±)-Sacidumlignan D.Radical-Mediated 1,2-Formyl/Carbonyl Functionalization of Alkenes and Application to the Construction of Medium-Sized Rings.A new strategy to construct a C=C-CF3 subunit via CuBr-catalyzed domino reaction of homopropargyl amines: an efficient synthesis of trifluoromethyl containing building blocks 4-trifluoromethyl-2,3-dihydro-pyrroliums.Phosphine-catalyzed remote β-C-H functionalization of amines triggered by trifluoromethylation of alkenes: one-pot synthesis of bistrifluoromethylated enamides and oxazoles.
P2860
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P2860
Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年学术文章
@wuu
2012年学术文章
@zh-cn
2012年学术文章
@zh-hans
2012年学术文章
@zh-my
2012年学术文章
@zh-sg
2012年學術文章
@yue
2012年學術文章
@zh
2012年學術文章
@zh-hant
name
Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.
@ast
Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.
@en
type
label
Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.
@ast
Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.
@en
prefLabel
Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.
@ast
Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.
@en
P2860
P356
P1476
Copper-catalyzed oxytrifluoromethylation of unactivated alkenes
@en
P2093
Stephen L Buchwald
P2860
P304
12462-12465
P356
10.1021/JA305840G
P407
P50
P577
2012-07-23T00:00:00Z