Enantioselective functionalization of radical intermediates in redox catalysis: copper-catalyzed asymmetric oxytrifluoromethylation of alkenes.
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Addition of CF3 across unsaturated moieties: a powerful functionalization toolRadicals: Reactive Intermediates with Translational PotentialEnantioselective copper-catalyzed carboetherification of unactivated alkenes.Copper-catalyzed regioselective ortho C-H cyanation of vinylarenes.Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes.Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium SaltsCatalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines.Copper-catalyzed oxidative carbon-heteroatom bond formation: a recent update.Progress in Enantioselective Radical Cyclizations.Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones.Selective C-H trifluoromethylation of benzimidazoles through photoredox catalysis.Rhodium-Catalyzed Geminal Oxyfluorination and Oxytrifluoro-Methylation of Diazocarbonyl Compounds.Regioselective aerobic oxidative Heck reactions with electronically unbiased alkenes: efficient access to α-alkyl vinylarenes.Visible-light-induced oxidant and metal-free dehydrogenative cascade trifluoromethylation and oxidation of 1,6-enynes with waterThe dual role of thiourea in the thiotrifluoromethylation of alkenes.Product Control in Alkene Trifluoromethylation: Hydrotrifluoromethylation, Vinylic Trifluoromethylation, and Iodotrifluoromethylation using Togni Reagent.Achiral Pyridine Ligand-Enabled Enantioselective Radical Oxytrifluoromethylation of Alkenes with Alcohols.Metal-free and light-promoted radical iodotrifluoromethylation of alkenes with Togni reagent as the source of CF3 and iodine.Selective Oxytrifluoromethylation of Allylamines with CO2.Enantioselective cyclizations and cyclization cascades of samarium ketyl radicals.Radical Enantioselective C(sp3 )-H Functionalization.A redox-economical synthesis of trifluoromethylated enamides with the Langlois reagent.Lewis Acid Catalyzed Asymmetric Three-Component Coupling Reaction: Facile Synthesis of α-Fluoromethylated Tertiary Alcohols.Iridium-catalyzed synthesis of diaryl ethers by means of chemoselective C-F bond activation and the formation of B-F bonds.Copper-Catalyzed Formal [2+2+1] Heteroannulation of Alkenes, Alkylnitriles, and Water: Method Development and Application to a Total Synthesis of (±)-Sacidumlignan D.Stereoselective Ketone Rearrangements with Hypervalent Iodine Reagents.Mn(OAc)3-mediated phosphonation-lactonization of alkenoic acids: synthesis of phosphono-γ-butyrolactones.Copper-mediated/catalyzed oxyalkylation of alkenes with alkylnitriles.Stereoselective Formation of Substituted 1,3-Dioxolanes through a Three-Component Assembly during the Oxidation of Alkenes with Hypervalent Iodine(III).Enantioselective radical process for synthesis of chiral indolines by metalloradical alkylation of diverse C(sp3)-H bonds.Metal-free alkene oxy- and amino-perfluoroalkylations carbocation formation by using perfluoro acid anhydrides: unique reactivity between styrenes and perfluoro diacyl peroxidesRadikalische enantioselektive C(sp3)-H-Funktionalisierung
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P2860
Enantioselective functionalization of radical intermediates in redox catalysis: copper-catalyzed asymmetric oxytrifluoromethylation of alkenes.
description
article científic
@ca
article scientifique
@fr
articolo scientifico
@it
artigo científico
@pt
bilimsel makale
@tr
scientific article published on 16 October 2013
@en
vedecký článok
@sk
vetenskaplig artikel
@sv
videnskabelig artikel
@da
vědecký článek
@cs
name
Enantioselective functionaliza ...... ifluoromethylation of alkenes.
@en
Enantioselective functionaliza ...... ifluoromethylation of alkenes.
@nl
type
label
Enantioselective functionaliza ...... ifluoromethylation of alkenes.
@en
Enantioselective functionaliza ...... ifluoromethylation of alkenes.
@nl
prefLabel
Enantioselective functionaliza ...... ifluoromethylation of alkenes.
@en
Enantioselective functionaliza ...... ifluoromethylation of alkenes.
@nl
P2860
P356
P1476
Enantioselective functionaliza ...... rifluoromethylation of alkenes
@en
P2093
Stephen L Buchwald
P2860
P304
12655-12658
P356
10.1002/ANIE.201307790
P407
P50
P577
2013-10-16T00:00:00Z