Catalytic enantioselective cross-couplings of secondary alkyl electrophiles with secondary alkylmetal nucleophiles: Negishi reactions of racemic benzylic bromides with achiral alkylzinc reagents.
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Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: stereospecific formation of diarylalkanes and triarylmethanes.Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsEnantioconvergent cross-couplings of racemic alkylmetal reagents with unactivated secondary alkyl electrophiles: catalytic asymmetric Negishi α-alkylations of N-Boc-pyrrolidine.Nickel/bis(oxazoline)-catalyzed asymmetric Negishi arylations of racemic secondary benzylic electrophiles to generate enantioenriched 1,1-diarylalkanes.Catalysis of Radical Reactions: A Radical Chemistry Perspective.Ni-Catalyzed C-C Couplings Using Alkyl Electrophiles.Copper-Catalyzed Cyclopropanol Ring Opening Csp(3)-Csp(3) Cross-Couplings with (Fluoro)Alkyl Halides.Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Synthesis and reactivity of new aminophenolate complexes of nickel.Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry.Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes.Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity.Single-electron transmetalation: an enabling technology for secondary alkylboron cross-coupling.Nickel-catalyzed cross couplings of benzylic ammonium salts and boronic acids: stereospecific formation of diarylethanes via C-N bond activation.A General, Simple Catalyst for Enantiospecific Cross Couplings of Benzylic Ammonium Triflates and Boronic Acids: No Phosphine Ligand RequiredFunctional-group-tolerant, nickel-catalyzed cross-coupling reaction for enantioselective construction of tertiary methyl-bearing stereocenters.Enantiospecific, regioselective cross-coupling reactions of secondary allylic boronic esters.A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters.Rhodium-Catalyzed Enantioselective Radical Addition of CX4 Reagents to Olefins.Enantioselective Construction of Trifluoromethoxylated Stereogenic Centers by a Nickel-Catalyzed Asymmetric Suzuki-Miyaura Coupling of Secondary Benzyl Bromides.Pd-PEPPSI-IHept(Cl) : A General-Purpose, Highly Reactive Catalyst for the Selective Coupling of Secondary Alkyl Organozincs.Cobalt-Catalyzed Enantioselective Negishi Cross-Coupling of Racemic α-Bromo Esters with Arylzincs.Palladium-Catalyzed Asymmetric Benzylic Alkylation of Active Methylene Compounds with α-Naphthylbenzyl Carbonates and Pivalates.The Selective Cross-Coupling of Secondary Alkyl Zinc Reagents to Five-Membered-Ring Heterocycles Using Pd-PEPPSI-IHept(Cl).Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes.
P2860
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P2860
Catalytic enantioselective cross-couplings of secondary alkyl electrophiles with secondary alkylmetal nucleophiles: Negishi reactions of racemic benzylic bromides with achiral alkylzinc reagents.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年学术文章
@wuu
2012年学术文章
@zh-cn
2012年学术文章
@zh-hans
2012年学术文章
@zh-my
2012年学术文章
@zh-sg
2012年學術文章
@yue
2012年學術文章
@zh
2012年學術文章
@zh-hant
name
Catalytic enantioselective cro ...... th achiral alkylzinc reagents.
@ast
Catalytic enantioselective cro ...... th achiral alkylzinc reagents.
@en
type
label
Catalytic enantioselective cro ...... th achiral alkylzinc reagents.
@ast
Catalytic enantioselective cro ...... th achiral alkylzinc reagents.
@en
prefLabel
Catalytic enantioselective cro ...... th achiral alkylzinc reagents.
@ast
Catalytic enantioselective cro ...... th achiral alkylzinc reagents.
@en
P2093
P2860
P356
P1476
Catalytic enantioselective cro ...... th achiral alkylzinc reagents.
@en
P2093
Christopher J Cordier
Gregory C Fu
Jörg T Binder
P2860
P304
17003-17006
P356
10.1021/JA308460Z
P407
P577
2012-10-05T00:00:00Z