Enantioconvergent cross-couplings of racemic alkylmetal reagents with unactivated secondary alkyl electrophiles: catalytic asymmetric Negishi α-alkylations of N-Boc-pyrrolidine.
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Opportunities and challenges for direct C-H functionalization of piperazinesEnantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsCatalytic Kinetic Resolution of Disubstituted Piperidines by Enantioselective Acylation: Synthetic Utility and Mechanistic Insights.Catalytic enantioselective cyclization/cross-coupling with alkyl electrophiles.Ligand-controlled asymmetric arylation of aliphatic α-amino anion equivalents.Stereospecific nickel-catalyzed cross-coupling reactions of alkyl Grignard reagents and identification of selective anti-breast-cancer agents.Direct access to functionalized azepanes by cross-coupling with α-halo eneformamides.Ni-Catalyzed C-C Couplings Using Alkyl Electrophiles.Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry.Dual catalysis. Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis.Tying up Nicotine: New Selective Competitive Antagonist of the Neuronal Nicotinic Acetylcholine Receptors.Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-AnhydridesEnantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis.Palladium-Catalyzed Directed C(sp(3))-H Arylation of Saturated Heterocycles at C-3 Using a Concise Optimization ApproachEnantioselective amine α-functionalization via palladium-catalysed C-H arylation of thioamides.Control of Vicinal Stereocenters through Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling.Metallaphotoredox-catalysed sp(3)-sp(3) cross-coupling of carboxylic acids with alkyl halides.A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters.Direct α-C-H bond functionalization of unprotected cyclic amines.Cobalt-Catalyzed Enantioselective Negishi Cross-Coupling of Racemic α-Bromo Esters with Arylzincs.Practical Alkoxythiocarbonyl Auxiliaries for Iridium(I)-Catalyzed C-H Alkylation of Azacycles.Enantiospecific sp(2)-sp(3) coupling of secondary and tertiary boronic esters.Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C-N Bond Activation.2-Azadienes as Reagents for Preparing Chiral Amines: Synthesis of 1,2-Amino Tertiary Alcohols by Cu-Catalyzed Enantioselective Reductive Couplings with Ketones.(+)-Camphor-mediated kinetic resolution of allylalanes: a strategy towards enantio-enriched cyclohex-2-en-1-ylalane.Enantioselective Radical Cyclization for Construction of 5-Membered Ring Structures by Metalloradical C-H Alkylation.3-Aryl-2,5-Dihydropyrroles via Catalytic Carbonyl-Olefin Metathesis
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Enantioconvergent cross-couplings of racemic alkylmetal reagents with unactivated secondary alkyl electrophiles: catalytic asymmetric Negishi α-alkylations of N-Boc-pyrrolidine.
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article científic
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article scientifique
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articolo scientifico
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artigo científico
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bilimsel makale
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scientific article published on 19 July 2013
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Enantioconvergent cross-coupli ...... ylations of N-Boc-pyrrolidine.
@en
Enantioconvergent cross-coupli ...... ylations of N-Boc-pyrrolidine.
@nl
type
label
Enantioconvergent cross-coupli ...... ylations of N-Boc-pyrrolidine.
@en
Enantioconvergent cross-coupli ...... ylations of N-Boc-pyrrolidine.
@nl
prefLabel
Enantioconvergent cross-coupli ...... ylations of N-Boc-pyrrolidine.
@en
Enantioconvergent cross-coupli ...... ylations of N-Boc-pyrrolidine.
@nl
P2860
P356
P1476
Enantioconvergent cross-coupli ...... kylations of N-Boc-pyrrolidine
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P2093
Christopher J Cordier
Gregory C Fu
P2860
P304
10946-10949
P356
10.1021/JA4054114
P407
P577
2013-07-19T00:00:00Z