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Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates.Regio- and stereospecific rhodium-catalyzed allylic alkylation with an acyl anion equivalent: an approach to acyclic α-ternary β,γ-unsaturated aryl ketones.The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total SynthesisEnantioselective protonation.A Cooperative N-Heterocyclic Carbene/Palladium Catalysis System.PREPARATION OF (S)-2-Allyl-2-methylcyclohexanone (Cyclohexanone, 2-methyl-2-(2-propen-1-yl)-, (2S)-).Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation.Evolution of a unified, stereodivergent approach to the synthesis of communesin F and perophoramidine.Palladium-catalyzed asymmetric conjugate addition of arylboronic acids to five-, six-, and seven-membered β-substituted cyclic enones: enantioselective construction of all-carbon quaternary stereocenters.Transition metal-catalyzed decarboxylative allylation and benzylation reactionsMechanistic analysis of an asymmetric palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones.Synthesis of diverse β-quaternary ketones via palladium-catalyzed asymmetric conjugate addition of arylboronic acids to cyclic enones.Catalytic double stereoinduction in asymmetric allylic alkylation of oxindoles.Palladium-catalyzed allylic alkylation of carboxylic acid derivatives: N-acyloxazolinones as ester enolate equivalents.An Efficient Protocol for the Palladium-catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst.Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes.Ligand controlled highly regio- and enantioselective synthesis of alpha-acyloxyketones by palladium-catalyzed allylic alkylation of 1,2-enediol carbonatesNatural products as inspiration for the development of asymmetric catalysis.Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketonesDevelopment of asymmetric deacylative allylation.Mechanism and enantioselectivity in palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones: insights from computation and experiment.Asymmetric counteranion-directed catalysis: concept, definition, and applications.Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams.Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones.Catalytic enantioselective approach to the eudesmane sesquiterpenoids: total synthesis of (+)-carissone.Enantio-, diastereo-, and regioselective iridium-catalyzed asymmetric allylic alkylation of acyclic β-ketoesters.A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres.Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.A unified approach to the daucane and sphenolobane bicyclo[5.3.0]decane core: enantioselective total syntheses of daucene, daucenal, epoxydaucenal B, and 14-para-anisoyloxydauc-4,8-diene.Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysisCatalytic enantioselective alkylation of substituted dioxanone enol ethers: ready access to Calpha-tetrasubstituted hydroxyketones, acids, and estersBiosynthetically inspired divergent approach to monoterpene indole alkaloids: total synthesis of mersicarpine, leuconodines B and D, leuconoxine, melodinine E, leuconolam, and rhazinilam.Enantioselective synthesis of a hydroxymethyl-cis-1,3-cyclopentenediol building block.The catalytic enantioselective total synthesis of (+)-liphagal.Ring-contraction strategy for the practical, scalable, catalytic asymmetric synthesis of versatile γ-quaternary acylcyclopentenes.Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork-Danheiser approach: preparation of mono-, bi-, and tricyclic systems.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Silyl ketene imines: highly versatile nucleophiles for catalytic, asymmetric synthesis.Homogeneous pd-catalyzed enantioselective decarboxylative protonation.Pd-catalyzed enantioselective allyl-allyl cross-coupling.
P2860
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P2860
description
2007 nî lūn-bûn
@nan
2007年の論文
@ja
2007年論文
@yue
2007年論文
@zh-hant
2007年論文
@zh-hk
2007年論文
@zh-mo
2007年論文
@zh-tw
2007年论文
@wuu
2007年论文
@zh
2007年论文
@zh-cn
name
Enantioselective Tsuji allylations.
@en
type
label
Enantioselective Tsuji allylations.
@en
prefLabel
Enantioselective Tsuji allylations.
@en
P2860
P356
P1476
Enantioselective Tsuji allylations.
@en
P2093
Brian M Stoltz
P2860
P304
P356
10.1002/ASIA.200700183
P577
2007-12-01T00:00:00Z