Catalytic asymmetric synthesis of all-carbon quaternary stereocenters
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1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysisTotal synthesis of asperazineOxidative allylic rearrangement of cycloalkenols: Formal total synthesis of enantiomerically pure trisporic acid B.Enantioselective construction of remote quaternary stereocentresPalladium-Catalyzed Enantioselective Heck Alkenylation of Trisubstituted Allylic Alkenols: A Redox-Relay Strategy to Construct Vicinal StereocentersThe Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total SynthesisPalladium(II)-catalyzed enantioselective C(sp³)-H activation using a chiral hydroxamic acid ligand.The Catalytic Asymmetric Intramolecular Stetter Reaction.An organocatalytic asymmetric Nazarov cyclization.Total synthesis of the strychnos alkaloid (+)-minfiensine: tandem enantioselective intramolecular Heck-iminium ion cyclization.Palladium-catalyzed asymmetric conjugate addition of arylboronic acids to five-, six-, and seven-membered β-substituted cyclic enones: enantioselective construction of all-carbon quaternary stereocenters.Mechanistic analysis of an asymmetric palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones.Concise, stereocontrolled synthesis of the citrinadin B core architecture.Ethylene in organic synthesis: a new route to anticholenergic pyrrolidinoindolines, and other molecules with all carbon-quaternary centers via asymmetric hydrovinylation.The palladium catalyzed asymmetric addition of oxindoles and allenes: an atom-economical versatile method for the construction of chiral indole alkaloidsAxial preferences in allylations via the Zimmerman-Traxler transition state.Contiguous stereogenic quaternary carbons: a daunting challenge in natural products synthesisSynthesis of diverse β-quaternary ketones via palladium-catalyzed asymmetric conjugate addition of arylboronic acids to cyclic enones.Rh-Catalyzed Desymmetrization of α-Quaternary Centers by Isomerization-Hydroacylation.Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones.Catalytic enantioselective synthesis of quaternary carbon stereocentresForming tertiary organolithiums and organocuprates from nitrile precursors and their bimolecular reactions with carbon electrophiles to form quaternary carbon stereocentersCatalytic asymmetric Claisen rearrangement of enolphosphonates: construction of vicinal tertiary and all-carbon quaternary centersNonenzymatic enantioselective synthesis of all-carbon quaternary centers through desymmetrization.An Efficient Protocol for the Palladium-catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst.Welwistatin support studies: expansion and limitation of aryllead(IV) coupling reactions.Rhodium-Catalyzed Enantioselective Cycloisomerization to Cyclohexenes Bearing Quaternary Carbon CentersMo-catalyzed regio-, diastereo-, and enantioselective allylic alkylation of 3-aryloxindoles.Direct Catalytic Asymmetric Mannich Reactions for the Construction of Quaternary Carbon Stereocenters.Aza-cope rearrangement-mannich cyclizations for the formation of complex tricyclic amines: stereocontrolled total synthesis of (+/-)-gelsemine.Enantioselective Tsuji allylations.Diastereoselection in the formation of spirocyclic oxindoles by the intramolecular Heck reaction.Molybdenum-catalyzed asymmetric allylic alkylation of 3-alkyloxindoles: reaction development and applicationsOrganometallic enantiomeric scaffolding. Sequential semipinacol/1,5-"Michael-like" reactions as a strategic approach to bridgehead-quaternary center aza[3.3.1]bicyclics: application to the total synthesis of (-)-adalineIridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α-Alkoxy Ketones.In Pursuit of an Ideal C-C Bond-Forming Reaction: Development and Applications of the Hydrovinylation of Olefins.Natural products as inspiration for the development of asymmetric catalysis.(R)-3-METHYL-3-PHENYL-1-PENTENE VIA CATALYTIC ASYMMETRIC HYDROVINYLATION.Palladium-catalyzed asymmetric allylic alkylation of 3-aryloxindoles with allylidene dipivalate: a useful enol pivalate product.Mechanism and enantioselectivity in palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones: insights from computation and experiment.
P2860
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P2860
Catalytic asymmetric synthesis of all-carbon quaternary stereocenters
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on 14 January 2004
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Catalytic asymmetric synthesis of all-carbon quaternary stereocenters
@en
Catalytic asymmetric synthesis of all-carbon quaternary stereocenters.
@nl
type
label
Catalytic asymmetric synthesis of all-carbon quaternary stereocenters
@en
Catalytic asymmetric synthesis of all-carbon quaternary stereocenters.
@nl
prefLabel
Catalytic asymmetric synthesis of all-carbon quaternary stereocenters
@en
Catalytic asymmetric synthesis of all-carbon quaternary stereocenters.
@nl
P2860
P356
P1476
Catalytic asymmetric synthesis of all-carbon quaternary stereocenters
@en
P2093
Christopher J Douglas
Larry E Overman
P2860
P304
P356
10.1073/PNAS.0307113101
P407
P577
2004-01-14T00:00:00Z