The biosynthesis of polyketide-derived polycyclic ethers.
about
Evidence that epoxide-opening cascades promoted by water are stepwise and become faster and more selective after the first cyclization.A late-stage intermediate in salinomycin biosynthesis is revealed by specific mutation in the biosynthetic gene cluster.Natural products version 2.0: connecting genes to molecules.Total synthesis of (+)-roxaticin via C-C bond forming transfer hydrogenation: a departure from stoichiometric chiral reagents, auxiliaries, and premetalated nucleophiles in polyketide construction.Electrophilic and nucleophilic enzymatic cascade reactions in biosynthesis.Genetic screening strategy for rapid access to polyether ionophore producers and products in actinomycetesHydroxyl-substituted ladder polyethers via selective tandem epoxidation/cyclization sequence.Enzymatic chemistry of cyclopropane, epoxide, and aziridine biosynthesis.Stereodivergent organocatalytic intramolecular Michael addition/lactonization for the asymmetric synthesis of substituted dihydrobenzofurans and tetrahydrofurans.Epoxide-opening cascades in the synthesis of polycyclic polyether natural products.Synthesis of marine polycyclic polyethers via endo-selective epoxide-opening cascadesMicroalgae in the postgenomic era: a blooming reservoir for new natural products.Polyketide biosynthesis in dinoflagellates: what makes it different?Synthetic endeavours towards oxasqualenoid natural products containing 2,5-disubstituted tetrahydrofurans--eurylene and teurilene.Comparative perspective and synthetic applications of transition metal mediated oxidative cyclisation of 1,5-dienes towards cis-2,5-disubstituted tetrahydrofurans.Formation of the Δ(18,19) Double Bond and Bis(spiroacetal) in Salinomycin Is Atypically Catalyzed by SlnM, a Methyltransferase-like Enzyme.Absolute configuration of brevisamide and brevisin: confirmation of a universal biosynthetic process for Karenia brevis polyethers.Intermediates in monensin biosynthesis: A late step in biosynthesis of the polyether ionophore monensin is crucial for the integrity of cation binding.A dioxane template for highly selective epoxy alcohol cyclizations.Identification and Interrogation of the Herbicidin Biosynthetic Gene Cluster: First Insight into the Biosynthesis of a Rare Undecose Nucleoside Antibiotic.Insights into lasalocid A ring formation by chemical chain termination in vivo.A New Strategy for Enantioselective Construction of Multisubstituted Five-Membered Oxygen Heterocycles via a Domino Michael/Hemiketalization Reaction.Regioselective dehydration of α-hydroxymethyl tetrahydrofurans using Burgess' reagent under microwave irradiation.Cytotoxic Spiroepoxide Lactone and Its Putative Biosynthetic Precursor from Goniobranchus Splendidus.
P2860
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P2860
The biosynthesis of polyketide-derived polycyclic ethers.
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年学术文章
@wuu
2008年学术文章
@zh-cn
2008年学术文章
@zh-hans
2008年学术文章
@zh-my
2008年学术文章
@zh-sg
2008年學術文章
@yue
2008年學術文章
@zh
2008年學術文章
@zh-hant
name
The biosynthesis of polyketide-derived polycyclic ethers.
@en
The biosynthesis of polyketide-derived polycyclic ethers.
@nl
type
label
The biosynthesis of polyketide-derived polycyclic ethers.
@en
The biosynthesis of polyketide-derived polycyclic ethers.
@nl
prefLabel
The biosynthesis of polyketide-derived polycyclic ethers.
@en
The biosynthesis of polyketide-derived polycyclic ethers.
@nl
P2860
P356
P1476
The biosynthesis of polyketide-derived polycyclic ethers.
@en
P2093
Andrew R Gallimore
P2860
P304
P356
10.1039/B807902C
P577
2008-11-21T00:00:00Z