Asymmetric carbon-carbon bond formation gamma to a carbonyl group: phosphine-catalyzed addition of nitromethane to allenes.
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1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysisPhosphine-catalyzed formation of carbon-sulfur bonds: catalytic asymmetric synthesis of gamma-thioestersEnantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement.BINEPINES: chiral binaphthalene-core monophosphepine ligands for multipurpose asymmetric catalysis.Chiral phosphines in nucleophilic organocatalysisDirect asymmetric vinylogous Michael addition of cyclic enones to nitroalkenes via dienamine catalysis.Phosphine-catalyzed asymmetric additions of malonate esters to {gamma}-substituted allenoates and allenamides.Catalytic asymmetric γ-alkylation of carbonyl compounds via stereoconvergent Suzuki cross-couplings.Palladacycle catalyzed asymmetric P-H addition of diarylphosphines to N-enoyl phthalimides.Enantioselective Carbon-Sulfur Bond Formation: γ Additions of Aryl Thiols to Allenoates Catalyzed by a Chiral Phosphepine.Phosphine-Catalyzed Doubly Stereoconvergent γ-Additions of Racemic Heterocycles to Racemic Allenoates: The Catalytic Enantioselective Synthesis of Protected α,α-Disubstituted α-Amino Acid Derivatives.Alkenyl carbonyl derivatives in enantioselective redox relay Heck reactions: accessing α,β-unsaturated systemsEnantioselective redox-relay oxidative heck arylations of acyclic alkenyl alcohols using boronic acids.Asymmetric α-amination of 3-substituted oxindoles using chiral bifunctional phosphine catalystsCatalytic asymmetric C-N bond formation: phosphine-catalyzed intra- and intermolecular γ-addition of nitrogen nucleophiles to allenoates and alkynoatesStereoselective phosphine-catalyzed synthesis of highly functionalized diquinanes.Advances in nucleophilic phosphine catalysis of alkenes, allenes, alkynes, and MBHADs.Increasing the reactivity of nitrogen catalysts.Palladacycle promoted base controlled regio- and enantioselective hydrophosphination of 2-pyridylacrylate/amide and the cytotoxicity of their gold complexes.Stereoselective Syntheses of α,β-Unsaturated γ-Amino Esters Through Phosphine-Catalyzed γ-Umpolung Additions of Sulfonamides to γ-Substituted Allenoates.Catalytic Enantioselective Carbon-Oxygen Bond Formation: Phosphine-Catalyzed Synthesis of Benzylic Ethers via the Oxidation of Benzylic C-H BondsPhosphine-catalyzed intramolecular γ-umpolung addition of α-aminoalkylallenic esters: facile synthesis of 3-carbethoxy-2-alkyl-3-pyrrolines.Chiral phosphine-mediated intramolecular [3 + 2] annulation: enhanced enantioselectivity by achiral Brønsted acid.Phosphine-Mediated Iterative Arene Homologation Using Allenes.Phosphine-catalyzed β'-umpolung addition of nucleophiles to activated α-alkyl allenes.Highly enantioselective, intermolecular hydroamination of allenyl esters catalyzed by bifunctional phosphinothioureas.Enantioselective Heck arylations of acyclic alkenyl alcohols using a redox-relay strategy.When asymmetric aminocatalysis meets the vinylogy principle.Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron.Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings.Efficient access to a designed phosphapalladacycle catalyst via enantioselective catalytic asymmetric hydrophosphination.Cyclopropyl iminium activation: reactivity umpolung in enantioselective organocatalytic reaction design.Cascade Mn-Mediated γ-Alkylation/oxa-Michael Addition of Enones with 1,3-Dicarbonyls.Phosphine catalysed (5 + 1) annulation of ynone/cinnamates with primary amines.An elimination/Heck coupling/allylation cascade reaction: synthesis of 2,3-dihydrobenzofurans from allenoate adducts.Enantioselective phospha-Michael addition of diarylphosphines to β,γ-unsaturated α-ketoesters and amides.Phosphine-Catalyzed β,γ-Umpolung Domino Reaction of Allenic Esters: Facile Synthesis of Tetrahydrobenzofuranones Bearing a Chiral Tetrasubstituted Stereogenic Carbon Center.Silver-Catalyzed Amidiniumation of Alkynes: Isolation of a Silver Intermediate, Synthesis of Enamine Amido Carbene Precursors, and an Unprecedented Umpolung of Propiolamide.Enantioselective Morita-Baylis-Hillman reaction promoted by L-threonine-derived phosphine-thiourea catalysts.Chiral phosphine catalyzed asymmetric Michael addition of oxindoles.
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P2860
Asymmetric carbon-carbon bond formation gamma to a carbonyl group: phosphine-catalyzed addition of nitromethane to allenes.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on October 2009
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Asymmetric carbon-carbon bond ...... on of nitromethane to allenes.
@en
Asymmetric carbon-carbon bond ...... on of nitromethane to allenes.
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type
label
Asymmetric carbon-carbon bond ...... on of nitromethane to allenes.
@en
Asymmetric carbon-carbon bond ...... on of nitromethane to allenes.
@nl
prefLabel
Asymmetric carbon-carbon bond ...... on of nitromethane to allenes.
@en
Asymmetric carbon-carbon bond ...... on of nitromethane to allenes.
@nl
P2860
P356
P1476
Asymmetric carbon-carbon bond ...... on of nitromethane to allenes.
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P2093
Gregory C Fu
Sean W Smith
P2860
P304
14231-14233
P356
10.1021/JA9061823
P407
P577
2009-10-01T00:00:00Z