Catalytic asymmetric γ-alkylation of carbonyl compounds via stereoconvergent Suzuki cross-couplings.
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Recent advances in homogeneous nickel catalysisPhotoredox Catalysis in Organic ChemistryStereoconvergent arylations and alkenylations of unactivated alkyl electrophiles: catalytic enantioselective synthesis of secondary sulfonamides and sulfonesCatalytic asymmetric synthesis of secondary nitriles via stereoconvergent Negishi arylations and alkenylations of racemic α-bromonitriles.Nickel-catalyzed enantioselective cross-couplings of racemic secondary electrophiles that bear an oxygen leaving group.Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes.New directing groups for metal-catalyzed asymmetric carbon-carbon bond-forming processes: stereoconvergent alkyl-alkyl Suzuki cross-couplings of unactivated electrophiles.Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsNickel-catalyzed coupling reactions of alkyl electrophiles, including unactivated tertiary halides, to generate carbon-boron bonds.Nickel-catalyzed cross-coupling of photoredox-generated radicals: uncovering a general manifold for stereoconvergence in nickel-catalyzed cross-couplings.Palladium-catalyzed allylic cross-coupling reactions of primary and secondary homoallylic electrophiles.Catalytic enantioselective cross-couplings of secondary alkyl electrophiles with secondary alkylmetal nucleophiles: Negishi reactions of racemic benzylic bromides with achiral alkylzinc reagents.Nickel-catalyzed carbon-carbon bond-forming reactions of unactivated tertiary alkyl halides: Suzuki arylations.Alkenyl carbonyl derivatives in enantioselective redox relay Heck reactions: accessing α,β-unsaturated systemsEnantioselective redox-relay oxidative heck arylations of acyclic alkenyl alcohols using boronic acids.Enantioconvergent cross-couplings of racemic alkylmetal reagents with unactivated secondary alkyl electrophiles: catalytic asymmetric Negishi α-alkylations of N-Boc-pyrrolidine.Catalytic asymmetric C-N bond formation: phosphine-catalyzed intra- and intermolecular γ-addition of nitrogen nucleophiles to allenoates and alkynoatesCatalytic enantioselective cyclization/cross-coupling with alkyl electrophiles.Parameterization of phosphine ligands demonstrates enhancement of nickel catalysis via remote steric effects.Ni-Catalyzed C-C Couplings Using Alkyl Electrophiles.Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Copper-catalyzed cross-coupling reactions of epoxides with gem-diborylmethane: access to γ-hydroxyl boronic esters.Enantioselective assembly of tertiary stereocenters via multicomponent chemoselective cross-coupling of geminal chloro(iodo)alkanes.Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes.Nickel-Catalyzed Asymmetric Kumada Cross-Coupling of Symmetric Cyclic Sulfates.Asymmetric transition metal-catalyzed cross-coupling reactions for the construction of tertiary stereocenters.Stereospecific cross-coupling reactions of aryl-substituted tetrahydrofurans, tetrahydropyrans, and lactones.Enantioselective Heck arylations of acyclic alkenyl alcohols using a redox-relay strategy.Control of Vicinal Stereocenters through Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling.Asymmetric synthesis of trans-β-lactams by a Kinugasa reaction on water.Terminal NiII-OH/-OH2 complexes in trigonal bipyramidal geometries derived from H2O.Construction of quaternary stereogenic carbon centers through copper-catalyzed enantioselective allylic cross-coupling with alkylboranes.Synthesis of chiral α-hydroxy acids via palladium-catalyzed C(sp(3))-H alkylation of lactic acid.Chemoselective reductive alkynylation of tertiary amides by Ir and Cu(i) bis-metal sequential catalysis.Cascade Mn-Mediated γ-Alkylation/oxa-Michael Addition of Enones with 1,3-Dicarbonyls.Palladium-catalyzed intramolecular reductive cross-coupling of Csp2-Csp3 bond formation.Highly Efficient, Convergent, and Enantioselective Synthesis of Phthioceranic Acid.Synthesis of chiral heterocycles by ligand-controlled regiodivergent and enantiospecific Suzuki Miyaura cross-coupling.Asymmetric cross-coupling of alkyl, alkenyl and (hetero)aryl nucleophiles with racemic allyl halides.Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay
P2860
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P2860
Catalytic asymmetric γ-alkylation of carbonyl compounds via stereoconvergent Suzuki cross-couplings.
description
2011 nî lūn-bûn
@nan
2011 թուականի Սեպտեմբերին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի սեպտեմբերին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Catalytic asymmetric γ-alkylat ...... ergent Suzuki cross-couplings.
@ast
Catalytic asymmetric γ-alkylat ...... ergent Suzuki cross-couplings.
@en
type
label
Catalytic asymmetric γ-alkylat ...... ergent Suzuki cross-couplings.
@ast
Catalytic asymmetric γ-alkylat ...... ergent Suzuki cross-couplings.
@en
prefLabel
Catalytic asymmetric γ-alkylat ...... ergent Suzuki cross-couplings.
@ast
Catalytic asymmetric γ-alkylat ...... ergent Suzuki cross-couplings.
@en
P2860
P356
P1476
Catalytic asymmetric γ-alkylat ...... ergent Suzuki cross-couplings.
@en
P2093
Gregory C Fu
Susan L Zultanski
P2860
P304
15362-15364
P356
10.1021/JA2079515
P407
P577
2011-09-13T00:00:00Z