Catalytic enantioselective Diels--Alder reactions: methods, mechanistic fundamentals, pathways, and applications.
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Enantioselective Diels-Alder reactions catalyzed by hydrogen bondingCatalytic enantioselective formation of chiral-bridged dienes which are themselves ligands for enantioselective catalysisSYNTHESIS OF SPIROBORATE ESTERS FROM 1,2-AMINOALCOHOLS, ETHYLENE GLYCOL AND TRIISOPROPYL BORATE: PREPARATION OF (S)-1-(1,3,2-DIOXABOROLAN-2-YLOXY)-3-METHYL-1,1-DIPHENYLBUTAN-2-AMINEDiscoveries from the Abyss: The Abyssomicins and Their Total Synthesis.Molecular complexity via C-H activation: a dehydrogenative Diels-Alder reaction.1-Meth-oxy-3-o-tolyl-bicyclo-[2.2.2]oct-5-ene-2,2-dicarbonitrile.Silver-catalyzed formal inverse electron-demand Diels-Alder reaction of 1,2-diazines and siloxy alkynes.Quantum and Molecular Mechanical (QM/MM) Monte Carlo Techniques for Modeling Condensed-Phase Reactions.Enantioselective route to platensimycin: an intramolecular Robinson annulation approachFrom nature to the laboratory and into the clinicCatalytic Asymmetric [4 + 2] Additions with Aliphatic Nitroalkenes.Reversal of the regiochemistry in the rhodium-catalyzed [4+3] cycloaddition between vinyldiazoacetates and dienesPermuting Diels-Alder and Robinson Annulation Stereopatterns.Design and Synthesis of Molecular Scaffolds with Anti-infective Activity.Use of the intramolecular Heck reaction for forming congested quaternary carbon stereocenters. Stereocontrolled total synthesis of (+/-)-gelsemine.Computational evaluation of enantioselective Diels-Alder reactions mediated by Corey's cationic oxazaborolidine catalystsTotal synthesis and absolute configuration of the bisanthraquinone antibiotic BE-43472BEnantioselective Reduction of Prochiral Ketones using Spiroborate Esters as Catalysts.Natural products as inspiration for the development of asymmetric catalysis.Chiral NHC-catalyzed oxodiene Diels-Alder reactions with alpha-chloroaldehyde bisulfite saltsRecent advances in the chemistry and biology of naturally occurring antibiotics.Superelectrophilic intermediates in nitrogen-directed aromatic borylation.The art of total synthesis through cascade reactionsBifunctional asymmetric catalysis: cooperative Lewis acid/base systems.Catalytic asymmetric synthesis of all-carbon quaternary stereocentersAsymmetric organocatalysis at the service of medicinal chemistryDifferences in the Abilities to Mechanically Eliminate Activation Energies for Unimolecular and Bimolecular Reactions.Enantioselective Organocatalytic Diels-Alder Trapping of Photochemically Generated Hydroxy-o-Quinodimethanes.Zn-catalyzed enantio- and diastereoselective formal [4 + 2] cycloaddition involving two electron-deficient partners: asymmetric synthesis of piperidines from 1-azadienes and nitro-alkenes.Rhodium-catalyzed 1,3-acyloxy migration and subsequent intramolecular [4+2] cycloaddition of vinylallene and unactivated alkyne.Total synthesis of (±)-maoecrystal V.Cyclobutenone as a highly reactive dienophile: expanding upon Diels-Alder paradigms.Enantioselective organo-SOMO cascade cycloadditions: a rapid approach to molecular complexity from simple aldehydes and olefins.Improved dienophilicity of nitrocycloalkenes: prospects for the development of a trans-Diels-Alder paradigm.Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts.Cationic tricoordinate boron intermediates: borenium chemistry from the organic perspective.Enhancing the scope of the Diels-Alder reaction through isonitrile chemistry: emergence of a new class of acyl-activated dienophilesMechanistically Inspired Route toward Hexahydro-2H-chromenes via Consecutive [4 + 2] Cycloadditions.Intramolecular Diels-Alder reactions of cycloalkenones: translation of high endo selectivity to trans junctions.
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P2860
Catalytic enantioselective Diels--Alder reactions: methods, mechanistic fundamentals, pathways, and applications.
description
article científic
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article scientifique
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articolo scientifico
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artigo científico
@pt
bilimsel makale
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scientific article published on May 2002
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Catalytic enantioselective Die ...... s, pathways, and applications.
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Catalytic enantioselective Die ...... s, pathways, and applications.
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type
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Catalytic enantioselective Die ...... s, pathways, and applications.
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Catalytic enantioselective Die ...... s, pathways, and applications.
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prefLabel
Catalytic enantioselective Die ...... s, pathways, and applications.
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Catalytic enantioselective Die ...... s, pathways, and applications.
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P1433
P1476
Catalytic enantioselective Die ...... s, pathways, and applications.
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P2093
P304
P577
2002-05-01T00:00:00Z