Catalytic asymmetric synthesis of tertiary alkyl fluorides: Negishi cross-couplings of racemic α,α-dihaloketones.
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Enantioselective nucleophile-catalyzed synthesis of tertiary alkyl fluorides via the α-fluorination of ketenes: synthetic and mechanistic studies.Stereoconvergent arylations and alkenylations of unactivated alkyl electrophiles: catalytic enantioselective synthesis of secondary sulfonamides and sulfonesAn in situ directing group strategy for chiral anion phase-transfer fluorination of allylic alcoholsEnantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsPalladium-catalyzed enantioselective 1,1-fluoroarylation of aminoalkenes.Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Benzylic Ethers with Isotopically-Labeled Grignard ReagentsNi-Catalyzed C-C Couplings Using Alkyl Electrophiles.Copper-Catalyzed Cyclopropanol Ring Opening Csp(3)-Csp(3) Cross-Couplings with (Fluoro)Alkyl Halides.Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Direct Asymmetric Alkylation of Ketones: Still Unconquered.Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes.Enantioselective Construction of Trifluoromethoxylated Stereogenic Centers by a Nickel-Catalyzed Asymmetric Suzuki-Miyaura Coupling of Secondary Benzyl Bromides.Cobalt-Catalyzed Enantioselective Negishi Cross-Coupling of Racemic α-Bromo Esters with Arylzincs.Catalyst free synthesis of α-fluoro-β-hydroxy ketones/α-fluoro-ynols via electrophilic fluorination of tertiary propargyl alcohols using Selectfluor™ (F-TEDA-BF4).NIS-mediated oxidative cyclization of N-(2-trifluoromethyl-3-alkynyl) hydroxylamines: a facile access to 4-trifluoromethyl-5-acylisoxazoles.Rhodium(I)-Complexes Catalyzed 1,4-Conjugate Addition of Arylzinc Chlorides to N-Boc-4-pyridone.Catalytic Enantioselective α-Fluorination of 2-Acyl Imidazoles via Iridium Complexes.The Application of Copper/Iron Cocatalysis in Cross-Coupling Reactions.Difluoromethylation of (hetero)aryl chlorides with chlorodifluoromethane catalyzed by nickel.Formal enantioconvergent substitution of alkyl halides via catalytic asymmetric photoredox radical coupling.Enantioselective fluorination of α-branched aldehydes and subsequent conversion to α-hydroxyacetals via stereospecific C-F bond cleavage.Synthesis of chiral α-trifluoromethyl alcohols and ethers via enantioselective Hiyama cross-couplings of bisfunctionalized electrophilesCopper-Catalyzed Innate Ethoxycarbonyldifluoromethylation of Electron-Rich Arenes
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Catalytic asymmetric synthesis of tertiary alkyl fluorides: Negishi cross-couplings of racemic α,α-dihaloketones.
description
article científic
@ca
article scientifique
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articolo scientifico
@it
artigo científico
@pt
bilimsel makale
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scientific article published on 31 March 2014
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vedecký článok
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vetenskaplig artikel
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videnskabelig artikel
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vědecký článek
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name
Catalytic asymmetric synthesis ...... of racemic α,α-dihaloketones.
@en
Catalytic asymmetric synthesis ...... of racemic α,α-dihaloketones.
@nl
type
label
Catalytic asymmetric synthesis ...... of racemic α,α-dihaloketones.
@en
Catalytic asymmetric synthesis ...... of racemic α,α-dihaloketones.
@nl
prefLabel
Catalytic asymmetric synthesis ...... of racemic α,α-dihaloketones.
@en
Catalytic asymmetric synthesis ...... of racemic α,α-dihaloketones.
@nl
P2860
P356
P1476
Catalytic asymmetric synthesis ...... of racemic α,α-dihaloketones.
@en
P2093
Gregory C Fu
P2860
P304
P356
10.1021/JA501815P
P407
P50
P577
2014-03-31T00:00:00Z