New directing groups for metal-catalyzed asymmetric carbon-carbon bond-forming processes: stereoconvergent alkyl-alkyl Suzuki cross-couplings of unactivated electrophiles.
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Stereoconvergent arylations and alkenylations of unactivated alkyl electrophiles: catalytic enantioselective synthesis of secondary sulfonamides and sulfonesEnantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C BondsNickel-catalyzed coupling reactions of alkyl electrophiles, including unactivated tertiary halides, to generate carbon-boron bonds.Nickel-catalyzed cross-coupling of photoredox-generated radicals: uncovering a general manifold for stereoconvergence in nickel-catalyzed cross-couplings.Catalytic enantioselective cross-couplings of secondary alkyl electrophiles with secondary alkylmetal nucleophiles: Negishi reactions of racemic benzylic bromides with achiral alkylzinc reagents.Nickel-catalyzed carbon-carbon bond-forming reactions of unactivated tertiary alkyl halides: Suzuki arylations.Enantioconvergent cross-couplings of racemic alkylmetal reagents with unactivated secondary alkyl electrophiles: catalytic asymmetric Negishi α-alkylations of N-Boc-pyrrolidine.Nickel/bis(oxazoline)-catalyzed asymmetric Negishi arylations of racemic secondary benzylic electrophiles to generate enantioenriched 1,1-diarylalkanes.Catalytic enantioselective cyclization/cross-coupling with alkyl electrophiles.Ligand-controlled asymmetric arylation of aliphatic α-amino anion equivalents.Catalytic asymmetric synthesis of tertiary alkyl fluorides: Negishi cross-couplings of racemic α,α-dihaloketones.Ni-Catalyzed C-C Couplings Using Alkyl Electrophiles.Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations.Synthesis and reactivity of new aminophenolate complexes of nickel.Transition metal-catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry.Iterative protecting group-free cross-coupling leading to chiral multiply arylated structures.Copper-catalyzed cross-coupling reactions of epoxides with gem-diborylmethane: access to γ-hydroxyl boronic esters.Enantioselective assembly of tertiary stereocenters via multicomponent chemoselective cross-coupling of geminal chloro(iodo)alkanes.Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes.Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis.Stereospecific nickel-catalyzed cross-coupling reactions of benzylic ethers and esters.Nickel-Catalyzed Cross-Coupling of Redox-Active Esters with Boronic Acids.Retention or inversion in stereospecific nickel-catalyzed cross-coupling of benzylic carbamates with arylboronic esters: control of absolute stereochemistry with an achiral catalyst.Functional-group-tolerant, nickel-catalyzed cross-coupling reaction for enantioselective construction of tertiary methyl-bearing stereocenters.Stereospecific cross-coupling of secondary organotrifluoroborates: potassium 1-(benzyloxy)alkyltrifluoroborates.Asymmetric transition metal-catalyzed cross-coupling reactions for the construction of tertiary stereocenters.A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters.Mechanistic Study of an Improved Ni Precatalyst for Suzuki-Miyaura Reactions of Aryl Sulfamates: Understanding the Role of Ni(I) Species.Mechanism and Origins of Ligand-Controlled Stereoselectivity of Ni-Catalyzed Suzuki-Miyaura Coupling with Benzylic Esters: A Computational Study.Construction of quaternary stereogenic carbon centers through copper-catalyzed enantioselective allylic cross-coupling with alkylboranes.Synthesis of chiral α-hydroxy acids via palladium-catalyzed C(sp(3))-H alkylation of lactic acid.Cobalt-Catalyzed Enantioselective Negishi Cross-Coupling of Racemic α-Bromo Esters with Arylzincs.Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C-N Bond Activation.Nickel-Catalyzed Enantioselective Conjunctive Cross-Coupling of 9-BBN Borates.Nickel-Catalyzed Heck-Type Monofluoroacetation of Styrenes for Facile Synthesis of Allylic Fluorides.Palladium-catalyzed intramolecular reductive cross-coupling of Csp2-Csp3 bond formation.Highly Efficient, Convergent, and Enantioselective Synthesis of Phthioceranic Acid.Base-promoted coupling of carbon dioxide, amines, and diaryliodonium salts: a phosgene- and metal-free route to O-aryl carbamates.Synthesis of chiral heterocycles by ligand-controlled regiodivergent and enantiospecific Suzuki Miyaura cross-coupling.Reductive coupling of benzyl oxalates with highly functionalized alkyl bromides by nickel catalysis.
P2860
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P2860
New directing groups for metal-catalyzed asymmetric carbon-carbon bond-forming processes: stereoconvergent alkyl-alkyl Suzuki cross-couplings of unactivated electrophiles.
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年論文
@yue
2012年論文
@zh-hant
2012年論文
@zh-hk
2012年論文
@zh-mo
2012年論文
@zh-tw
2012年论文
@wuu
2012年论文
@zh
2012年论文
@zh-cn
name
New directing groups for metal ...... of unactivated electrophiles.
@ast
New directing groups for metal ...... of unactivated electrophiles.
@en
type
label
New directing groups for metal ...... of unactivated electrophiles.
@ast
New directing groups for metal ...... of unactivated electrophiles.
@en
prefLabel
New directing groups for metal ...... of unactivated electrophiles.
@ast
New directing groups for metal ...... of unactivated electrophiles.
@en
P2093
P2860
P356
P1476
New directing groups for metal ...... of unactivated electrophiles.
@en
P2093
Ashraf Wilsily
Francesco Tramutola
Gregory C Fu
Nathan A Owston
P2860
P304
P356
10.1021/JA301612Y
P407
P577
2012-03-26T00:00:00Z