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A Highly Active Catalyst for the Room-Temperature Amination and Suzuki Coupling of Aryl ChloridesSynthesis of N-Aryl-2-allyl Pyrrolidines via Palladium-catalyzed Carboamination Reactions of γ-(N-Arylamino)alkenes with Vinyl Bromides.Selective synthesis of 5- or 6-aryl octahydrocyclopenta[b]pyrroles from a common precursor through control of competing pathways in a Pd-catalyzed reaction.Stereoselective synthesis of substituted 1,3-oxazolidines via Pd-catalyzed carboamination reactions of O-vinyl-1,2-amino alcohols.Synthesis of substituted tetrahydroindoloisoquinoline derivatives via intramolecular Pd-catalyzed alkene carboamination reactionsSynthesis of polycyclic nitrogen heterocycles via alkene aminopalladation/carbopalladation cascade reactions.Use of aryl chlorides as electrophiles in Pd-catalyzed alkene difunctionalization reactions.Pd-catalyzed carboamination of oxazolidin-2-ones: a stereoselective route to trans-2,5-disubstituted pyrrolidines.Stereocontrolled synthesis of bicyclic sulfamides via Pd-catalyzed alkene carboamination reactions. Control of 1,3-asymmetric induction by manipulating mechanistic pathways.Stereoselective synthesis of imidazolidin-2-ones via Pd-catalyzed alkene carboamination. Scope and limitations.Palladium-catalyzed synthesis of 2,1'-disubstituted tetrahydrofurans from gamma-hydroxy internal alkenes. Evidence for alkene insertion into a Pd-O bond and stereochemical scrambling via beta-hydride elimination.Synthesis of chromans via Pd-catalyzed alkene carboetherification reactions.Stereoselective synthesis of cis- or trans-3,5-disubstituted pyrazolidines via Pd-catalyzed carboamination reactions: use of allylic strain to control product stereochemistry through N-substituent manipulation.Synthesis of substituted 2-aminoimidazoles via Pd-catalyzed alkyne carboamination reactions. Application to the synthesis of preclathridine natural products.Intramolecular alkene carboamination reactions for the synthesis of enantiomerically enriched tropane derivatives.A new synthesis of imidazolidin-2-ones via Pd-catalyzed carboamination of N-allylureas.Recent Advances in the Stereoselective Synthesis of Tetrahydrofurans.Influence of hydroxylamine conformation on stereocontrol in Pd-catalyzed isoxazolidine-forming reactionsEnantioselective Synthesis of Tetrahydroquinolines, Tetrahydroquinoxalines, and Tetrahydroisoquinolines via Pd-Catalyzed Alkene Carboamination Reactions.Palladium-catalyzed alkene carboamination reactions for the synthesis of substituted piperazines.Palladium-Catalyzed Alkene Carboamination Reactions of Electron-Poor Nitrogen NucleophilesMild conditions for Pd-catalyzed carboamination of N-protected hex-4-enylamines and 1-, 3-, and 4-substituted pent-4-enylamines. Scope, limitations, and mechanism of pyrrolidine formation.Asymmetric palladium-catalyzed carboamination reactions for the synthesis of enantiomerically enriched 2-(arylmethyl)- and 2-(alkenylmethyl)pyrrolidines.Mild conditions for the synthesis of functionalized pyrrolidines via Pd-catalyzed carboamination reactions.Asymmetric Palladium-Catalyzed Alkene Carboamination Reactions for the Synthesis of Cyclic SulfamidesStereoselective synthesis of isoxazolidines through Pd-catalyzed carboetherification of N-butenylhydroxylamines.Synthesis of saturated 1,4-benzodiazepines via Pd-catalyzed carboamination reactions.Palladium-catalyzed synthesis of cyclopentane-fused benzocyclobutenes via tandem directed carbopalladation/C-H bond functionalization.Synthesis of fused-ring and attached-ring bis-tetrahydrofurans via Pd-catalyzed carboetherification.A concise stereoselective synthesis of Preussin, 3-epi-Preussin, and analogues.Development of Enantioselective Palladium-Catalyzed Alkene Carboalkoxylation Reactions for the Synthesis of TetrahydrofuransPalladium-catalyzed tandem N-arylation/carboamination reactions for the stereoselective synthesis of N-aryl-2-benzyl pyrrolidinesSynthesis of enantiomerically enriched imidazolidin-2-ones through asymmetric palladium-catalyzed alkene carboamination reactions.Asymmetric total synthesis of (+)-merobatzelladine B.Synthesis of Polycyclic Nitrogen Heterocycles via Cascade Pd-Catalyzed Alkene Carboamination/Diels-Alder Reactions.Asymmetric Pd-Catalyzed Alkene Carboamination Reactions for the Synthesis of 2-Aminoindane Derivatives.Intramolecular Pd-catalyzed carboetherification and carboamination. Influence of catalyst structure on reaction mechanism and product stereochemistry.Synthesis of polysubstituted tetrahydrofurans via Pd-catalyzed carboetherification reactionsInfluence of catalyst structure and reaction conditions on anti- versus syn-aminopalladation pathways in Pd-catalyzed alkene carboamination reactions of N-allylsulfamides.Enantioconvergent synthesis of (+)-aphanorphine via asymmetric Pd-catalyzed alkene carboamination.
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description
hulumtues
@sq
researcher
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wetenschapper
@nl
հետազոտող
@hy
name
John P Wolfe
@nl
John P Wolfe
@sl
John P. Wolfe
@en
John P. Wolfe
@es
type
label
John P Wolfe
@nl
John P Wolfe
@sl
John P. Wolfe
@en
John P. Wolfe
@es
prefLabel
John P Wolfe
@nl
John P Wolfe
@sl
John P. Wolfe
@en
John P. Wolfe
@es
P106
P1153
7401795411
P21
P31
P496
0000-0002-7538-6273