Palladium-catalyzed synthesis of 2,1'-disubstituted tetrahydrofurans from gamma-hydroxy internal alkenes. Evidence for alkene insertion into a Pd-O bond and stereochemical scrambling via beta-hydride elimination.
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Enantioselective copper-catalyzed carboetherification of unactivated alkenes.Copper-catalyzed intramolecular alkene carboetherification: synthesis of fused-ring and bridged-ring tetrahydrofurans.Palladium-Catalyzed Enantioselective Intermolecular Coupling of Phenols and Allylic Alcohols.Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications.The syn/anti-dichotomy in the palladium-catalyzed addition of nucleophiles to alkenes.Stereoselective synthesis of substituted 1,3-oxazolidines via Pd-catalyzed carboamination reactions of O-vinyl-1,2-amino alcohols.Highly diastereoselective Pd-catalyzed carboetherification reactions of acyclic internal alkenes. Stereoselective synthesis of polysubstituted tetrahydrofuransPalladium-Catalyzed Carboetherification and Carboamination Reactions of γ-Hydroxy- and γ-Aminoalkenes for the Synthesis of Tetrahydrofurans and Pyrrolidines.Reconciling the stereochemical course of nucleopalladation with the development of enantioselective wacker-type cyclizations.Stereoselective synthesis of imidazolidin-2-ones via Pd-catalyzed alkene carboamination. Scope and limitations.Gold-catalyzed three-component coupling: oxidative oxyarylation of alkenes.Synthesis of chromans via Pd-catalyzed alkene carboetherification reactions.A new synthesis of imidazolidin-2-ones via Pd-catalyzed carboamination of N-allylureas.Recent Advances in the Stereoselective Synthesis of Tetrahydrofurans.Influence of hydroxylamine conformation on stereocontrol in Pd-catalyzed isoxazolidine-forming reactionsPalladium-catalysed cyclisation of alkenols: Synthesis of oxaheterocycles as core intermediates of natural compounds.Mild conditions for Pd-catalyzed carboamination of N-protected hex-4-enylamines and 1-, 3-, and 4-substituted pent-4-enylamines. Scope, limitations, and mechanism of pyrrolidine formation.Asymmetric Palladium-Catalyzed Alkene Carboamination Reactions for the Synthesis of Cyclic SulfamidesStereoselective synthesis of isoxazolidines through Pd-catalyzed carboetherification of N-butenylhydroxylamines.Two palladium-catalyzed domino reactions from one set of substrates/reagents: efficient synthesis of substituted indenes and cis-stilbenoid hydrocarbons from the same internal alkynes and hindered Grignard reagents.Synthesis of fused-ring and attached-ring bis-tetrahydrofurans via Pd-catalyzed carboetherification.Development of Enantioselective Palladium-Catalyzed Alkene Carboalkoxylation Reactions for the Synthesis of TetrahydrofuransSynthesis of enantiomerically enriched imidazolidin-2-ones through asymmetric palladium-catalyzed alkene carboamination reactions.Alternative pathways for Heck intermediates: palladium-catalyzed oxyarylation of homoallylic alcoholsIntramolecular Pd-catalyzed carboetherification and carboamination. Influence of catalyst structure on reaction mechanism and product stereochemistry.Synthesis of polysubstituted tetrahydrofurans via Pd-catalyzed carboetherification reactionsPalladium-catalyzed synthesis of benzofurans via C-H activation/oxidation tandem reaction and its application to the synthesis of decursivine and serotobenine.Cu-catalyzed intramolecular aryl-etherification reactions of alkoxyl alkynes with diaryliodonium salts via cleavage of a stable C-O bond.Synthesis of Cyclic Guanidines Bearing N-Arylsulfonyl and N-Cyano Protecting Groups via Pd-Catalyzed Alkene Carboamination Reactions.
P2860
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P2860
Palladium-catalyzed synthesis of 2,1'-disubstituted tetrahydrofurans from gamma-hydroxy internal alkenes. Evidence for alkene insertion into a Pd-O bond and stereochemical scrambling via beta-hydride elimination.
description
2005 nî lūn-bûn
@nan
2005年の論文
@ja
2005年論文
@yue
2005年論文
@zh-hant
2005年論文
@zh-hk
2005年論文
@zh-mo
2005年論文
@zh-tw
2005年论文
@wuu
2005年论文
@zh
2005年论文
@zh-cn
name
Palladium-catalyzed synthesis ...... via beta-hydride elimination.
@en
type
label
Palladium-catalyzed synthesis ...... via beta-hydride elimination.
@en
prefLabel
Palladium-catalyzed synthesis ...... via beta-hydride elimination.
@en
P2860
P356
P1476
Palladium-catalyzed synthesis ...... via beta-hydride elimination.
@en
P2093
Michael B Hay
P2860
P304
16468-16476
P356
10.1021/JA054754V
P407
P577
2005-11-01T00:00:00Z