Enantioselective synthesis of all-carbon quaternary stereogenic centers by catalytic asymmetric conjugate additions of alkyl and aryl aluminum reagents to five-, six-, and seven-membered-ring beta-substituted cyclic enones.
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Scalable enantioselective total synthesis of taxanesCopper-catalyzed asymmetric conjugate addition of organometallic reagents to extended Michael acceptorsMultifunctional organoboron compounds for scalable natural product synthesis.Palladium-catalyzed asymmetric conjugate addition of arylboronic acids to five-, six-, and seven-membered β-substituted cyclic enones: enantioselective construction of all-carbon quaternary stereocenters.A new strategy for the synthesis of chiral β-alkynyl esters via sequential palladium and copper catalysis.Synthesis of diverse β-quaternary ketones via palladium-catalyzed asymmetric conjugate addition of arylboronic acids to cyclic enones.Catalytic enantioselective synthesis of quaternary carbon stereocentresCatalytic enantioselective olefin metathesis in natural product synthesis. Chiral metal-based complexes that deliver high enantioselectivity and morePalladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Cyclic ElectrophilesMechanism and enantioselectivity in palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones: insights from computation and experiment.C-C bond formation via copper-catalyzed conjugate addition reactions to enones in water at room temperatureDiastereoselective and enantioselective conjugate addition reactions utilizing α,β-unsaturated amides and lactams.Copper diamidocarbene complexes: characterization of monomeric to tetrameric species.Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications.Catalytic SN2'- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis.Evolution of catalytic stereoselective olefin metathesis: from ancillary transformation to purveyor of stereochemical identity.A multicomponent Ni-, Zr-, and Cu-catalyzed strategy for enantioselective synthesis of alkenyl-substituted quaternary carbons.Quaternary carbon stereogenic centers through copper-catalyzed enantioselective allylic substitutions with readily accessible aryl- or heteroaryllithium reagents and aluminum chlorides.Stereogenic-at-metal Zn- and Al-based N-heterocyclic carbene (NHC) complexes as bifunctional catalysts in Cu-free enantioselective allylic alkylations.Enantioselective synthesis of allylboronates bearing a tertiary or quaternary B-substituted stereogenic carbon by NHC-Cu-catalyzed substitution reactions.Enantioselective synthesis of quaternary carbon stereogenic centers through copper-catalyzed conjugate additions of aryl- and alkylaluminum reagents to acyclic trisubstituted enonesEnantioselective synthesis of boron-substituted quaternary carbons by NHC-Cu-catalyzed boronate conjugate additions to unsaturated carboxylic esters, ketones, or thioesters.Acyclic quaternary centers from asymmetric conjugate addition of alkylzirconium reagents to linear trisubstituted enones.Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.Total synthesis of taxane terpenes: cyclase phase.Formation of vinyl-, vinylhalide- or acyl-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed enantioselective conjugate additions of Si-containing vinylaluminums to β-substituted cyclic enones.Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes.Enantioselective total synthesis of clavirolide C. Applications of Cu-catalyzed asymmetric conjugate additions and Ru-catalyzed ring-closing metathesis.Formation of quaternary stereogenic centers by copper-catalyzed asymmetric conjugate addition reactions of alkenylaluminums to trisubstituted enones.Formation of quaternary centers by copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents.Copper-catalyzed asymmetric conjugate addition of alkylzirconium reagents to cyclic enones to form quaternary centers.Efficient formation of benzylic quaternary centers via palladium catalysis.Multicomponent synthesis of chiral bidentate unsymmetrical unsaturated N-heterocyclic carbenes: copper-catalyzed asymmetric C-C bond formation.Reductive umpolung reactions with low-valent titanium catalysts.Palladium/chiral amine co-catalyzed enantioselective β-arylation of α,β-unsaturated aldehydes.Catalytic enantioselective β-alkylation of α,β-unsaturated aldehydes by combination of transition-metal- and aminocatalysis: total synthesis of bisabolane sesquiterpenes.Formation of quaternary centres by copper catalysed asymmetric conjugate addition to β-substituted cyclopentenones with the aid of a quantitative structure-selectivity relationship.Highly active chiral ruthenium-based metathesis catalysts through a monosubstitution in the N-heterocyclic carbene.Asymmetric borylation of α,β-unsaturated esters catalyzed by novel ring expanded N-heterocyclic carbenes based on chiral 3,4-dihydro-quinazolinium compounds.
P2860
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P2860
Enantioselective synthesis of all-carbon quaternary stereogenic centers by catalytic asymmetric conjugate additions of alkyl and aryl aluminum reagents to five-, six-, and seven-membered-ring beta-substituted cyclic enones.
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年論文
@yue
2008年論文
@zh-hant
2008年論文
@zh-hk
2008年論文
@zh-mo
2008年論文
@zh-tw
2008年论文
@wuu
2008年论文
@zh
2008年论文
@zh-cn
name
Enantioselective synthesis of ...... eta-substituted cyclic enones.
@en
Enantioselective synthesis of ...... eta-substituted cyclic enones.
@nl
type
label
Enantioselective synthesis of ...... eta-substituted cyclic enones.
@en
Enantioselective synthesis of ...... eta-substituted cyclic enones.
@nl
prefLabel
Enantioselective synthesis of ...... eta-substituted cyclic enones.
@en
Enantioselective synthesis of ...... eta-substituted cyclic enones.
@nl
P2093
P2860
P356
P1476
Enantioselective synthesis of ...... eta-substituted cyclic enones.
@en
P2093
Amir H Hoveyda
M Kevin Brown
Tricia L May
P2860
P304
P356
10.1002/ANIE.200802910
P407
P577
2008-01-01T00:00:00Z