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Chemistry. Radical ligands confer nobility on base-metal catalysts

Chemistry. Radical ligands confer nobility on base-metal catalysts

http://www.wikidata.org/entity/Q28273019

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Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion Combination of Scanning Probe Microscopy and Coordination Chemistry: Structural and Electronic Study of Bis(methylbenzimidazolyl)ketone and Its Iron Complex Iron catalysts for selective anti-Markovnikov alkene hydrosilylation using tertiary silanes.Electronic Structure Determination of Pyridine N-Heterocyclic Carbene Iron Dinitrogen Complexes and Neutral Ligand Derivatives.Probing Cu(I) in homogeneous catalysis using high-energy-resolution fluorescence-detected X-ray absorption spectroscopy.High-Activity Iron Catalysts for the Hydrogenation of Hindered, Unfunctionalized Alkenes.Selective oxidation of 8,8'-hydroxylated binaphthols to bis-spironaphthalenones or binaphtho-para- and binaphtho-ortho-quinones.Ligand steals spotlight from metal to orchestrate hydrogen production Characterization of Porphyrin-Co(III)-'Nitrene Radical' Species Relevant in Catalytic Nitrene Transfer Reactions.Oxidative addition of carbon-carbon bonds with a redox-active bis(imino)pyridine iron complex.Catalytic hydrogenation activity and electronic structure determination of bis(arylimidazol-2-ylidene)pyridine cobalt alkyl and hydride complexes Electrochemistry, chemical reactivity, and time-resolved infrared spectroscopy of donor-acceptor systems [(Q(x))Pt(pap(y))] (Q = substituted o-quinone or o-iminoquinone; pap = phenylazopyridine).New avenues for ligand-mediated processes--expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands.Isolation of a bis(imino)pyridine molybdenum(i) iodide complex through controlled reduction and interconversion of its reaction products.Linear, Trinuclear Cobalt Complexes with o-Phenylene-bis-Silylamido Ligands.Synthesis and characterisation of p-block complexes of biquinoline at different ligand charge states.Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square-Planar Copper(I) Complex.From 0 to II in One-Electron Steps: A Series of Ruthenium Complexes Supported by TropPPh2.Metal-Metal Interactions in Heterobimetallic Complexes with Dinucleating Redox-Active Ligands.Computational Study of Formic Acid Dehydrogenation Catalyzed by Al(III)-Bis(imino)pyridine.Crystal structure of (1E,1'E)-1,1'-(pyridine-2,6-di-yl)bis-[N-(2,3,4,5,6-penta-fluoro-phen-yl)ethan-1-imine].Synthesis and crystal structure of a disubstituted nickel(II) bis-[(di-methyl-amino-phenyl-imino)-eth-yl]pyridine chloride complex.Near-IR absorbing donor-acceptor ligand-to-ligand charge-transfer complexes of nickel(ii).The non-innocent phenalenyl unit: an electronic nest to modulate the catalytic activity in hydroamination reaction.Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin.Ligand radical localization in a nonsymmetric one-electron oxidized Ni(II) bis-phenoxide complex.Iron-catalysed, general and operationally simple formal hydrogenation using Fe(OTf)3 and NaBH4.Non-innocent ligand behaviour of a bimetallic Cu complex employing a bridging catecholate.Giant residual dipolar 13C-1H couplings in high-spin organoiron complexes: elucidation of their structures in solution by 13C NMR spectroscopy.Double oxidation localizes spin in a Ni bis-phenoxyl radical complex.C-H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity.Synthesis and complexes of fluoroalkoxy carbenes.Redox and anion exchange chemistry of a stibine-nickel complex: writing the L, X, Z ligand alphabet with a single element.Class III delocalization and exciton coupling in a bimetallic bis-ligand radical complex.Group transfer reactions of d0 transition metal complexes: redox-active ligands provide a mechanism for expanded reactivity.Arene non-innocence in dinuclear complexes of Fe, Co, and Ni supported by a para-terphenyl diphosphine.An electron transfer series of octahedral chromium complexes containing a redox non-innocent α-diimine ligand.The new C-C bond formation in the reaction of o-amidophenolate indium(III) complex with alkyl iodides.Synthesis, characterization and catalytic activity of copper(II) complexes containing a redox-active benzoxazole iminosemiquinone ligand.Stable anilinyl radicals coordinated to nickel: X-ray crystal structure and characterization.

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Q28072632-0C802132-89DA-4D7E-B506-077E71440399 Q33619628-24A64797-FE33-485D-AF61-380307B682AA Q34251574-43DDF456-FFCF-43FC-86BE-FA2E2402606B Q34331232-21708194-BEC5-4BF2-92BE-5DD63C53F9D0 Q35637143-FE73023E-B7BF-4696-8D45-E5EC30D18142 Q35896280-068EE0B3-5027-4C8A-B20F-7C9D2532D5B9 Q36286425-74402EB3-7E51-44C6-BA31-3513DB84FD12 Q36498327-AE29E6BD-BC44-4442-9213-CD8E506483A6 Q36570787-672BDCA7-2C7E-470C-A988-4AED62E3F9C5 Q37184402-3AFC5874-F3B8-4B35-AAE6-79B558492BB3 Q37237775-6ADDA36D-63A7-498F-8DA7-98B2D0C5AB89 Q38275681-B6D19AA8-4CC3-490C-B55A-AF0E82B92CF3 Q38543236-0C826CBC-018A-45BA-BDEA-41C4D77C8B73 Q38878764-1A0E23CF-C6D5-4121-A4F2-B1915BE1C7CF Q38889534-91F05650-0995-446D-A7EE-F9B032410232 Q39018862-3F9E4FF2-0E8F-401A-AFCB-0294344732FC Q39377409-47E4C7F1-9ACD-4DBE-90B0-4D243B304464 Q39456957-DAEF8802-EBFE-490B-8475-D6162A97E15C Q40112694-42972CFE-24E4-4B3E-BEDF-2809A14E3763 Q40352825-FAF4DF6F-5DF4-4805-A216-0B35A936664A Q40953339-16D8A4AA-EE30-4E19-A5C8-9F9BE8C935ED Q41077319-F2B26131-4AC2-49D2-862E-6568DB1BB29B Q41671227-3C1880FC-C103-4A98-BC2D-AF6F7C527539 Q41829065-031DFF1A-166B-4FB8-8868-682058A36E71 Q41861439-8BE8EAB8-A0CB-42EE-8593-23B6C50C9DFB Q42208329-FC72A9CD-D5CA-42C6-A0D7-E91C7F34BD39 Q43107609-4C50DC2A-3DE4-4315-A76A-0DFB9E257452 Q43470175-8E1D1BFD-C400-4633-9901-BF864E538921 Q43609955-04A36E56-18F8-4631-B1DB-5616DF362F5C Q43733022-0E9A2137-FEDA-4440-902F-2A5F04AA5C71 Q43978890-B3FE4223-8B73-457C-A8D1-938D2049560C Q44396778-564BBE7E-FF0C-4CBC-B88F-6CE3232C6A27 Q44781122-5972ECD9-8EA0-4FD9-BF4D-A42E54E9C3AA Q45423857-E85FF318-BF42-4144-B600-797B95F969ED Q45839669-EBDA4BE8-00B5-44BD-8B3A-D1EDB9B6A36C Q45982459-926CAFDA-4132-4C14-871A-0BAB5AF911F5 Q45982717-C25ABD9D-BBF3-42F2-AF5F-4B6949F69490 Q46092290-F369B339-8C90-40B0-9D0E-EAFB5FB5FA50 Q46200094-A1478210-DCC7-4003-94AB-CABC5DBA3526 Q46215139-B5A42EF5-AEAE-4790-BA40-88F46CBF4ED7

P2860

Chemistry. Radical ligands confer nobility on base-metal catalysts

http://www.wikidata.org/entity/Q28273019

description

2010 nî lūn-bûn

@nan

2010 թուականի Փետրուարին հրատարակուած գիտական յօդուած

@hyw

2010 թվականի փետրվարին հրատարակված գիտական հոդված

@hy

2010年の論文

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2010年論文

@yue

2010年論文

@zh-hant

2010年論文

@zh-hk

2010年論文

@zh-mo

2010年論文

@zh-tw

2010年论文

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name

Chemistry. Radical ligands confer nobility on base-metal catalysts

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Chemistry. Radical ligands confer nobility on base-metal catalysts

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Chemistry. Radical ligands confer nobility on base-metal catalysts

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type

label

Chemistry. Radical ligands confer nobility on base-metal catalysts

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Chemistry. Radical ligands confer nobility on base-metal catalysts

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Chemistry. Radical ligands confer nobility on base-metal catalysts

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Chemistry. Radical ligands confer nobility on base-metal catalysts

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Chemistry. Radical ligands confer nobility on base-metal catalysts

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Chemistry. Radical ligands confer nobility on base-metal catalysts

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Chemistry. Radical ligands confer nobility on base-metal catalysts

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Karl Wieghardt

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Paul J Chirik

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P2860

Molecular and Electronic Structures of Bis(pyridine-2,6-diimine)metal Complexes [ML2](PF6)n(n= 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)†

Electronic structure of bis(imino)pyridine iron dichloride, monochloride, and neutral ligand complexes: a combined structural, spectroscopic, and computational study.

Electronic structure of bis(o-iminobenzosemiquinonato)metal complexes (Cu, Ni, Pd). The art of establishing physical oxidation states in transition-metal complexes containing radical ligands.

Metal-to-ligand electron transfer in diiminopyridine complexes of Mn-Zn. A theoretical study.

Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation.

Iron-catalyzed, hydrogen-mediated reductive cyclization of 1,6-enynes and diynes: evidence for bis(imino)pyridine ligand participation.

Four-electron oxidative formation of aryl diazenes using a tantalum redox-active ligand complex.

The Organometallic Chemistry of Rh-, Ir-, Pd-, and Pt-Based Radicals: Higher Valent Species

Analysis and Interpretation of Metal-Radical Coupling in a Series of Square Planar Nickel Complexes: Correlated Ab Initio and Density Functional Investigation of [Ni(LISQ)2] (LISQ=3,5-di-tert-butyl-o-diiminobenzosemiquinonate(1-))

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794-5

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scholarly article

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10.1126/SCIENCE.1183281

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5967

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327

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2010-02-12T00:00:00Z

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20150476

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