Electronic structure of bis(o-iminobenzosemiquinonato)metal complexes (Cu, Ni, Pd). The art of establishing physical oxidation states in transition-metal complexes containing radical ligands.
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Chemistry. Radical ligands confer nobility on base-metal catalystsMolecular and electronic structure of four- and five-coordinate cobalt complexes containing two o-phenylenediamine- or two o-aminophenol-type ligands at various oxidation levels: an experimental, density functional, and correlated ab initio study.Metal-dioxygen and metal-dinitrogen complexes: where are the electrons?Which functional groups of the molybdopterin ligand should be considered when modeling the active sites of the molybdenum and tungsten cofactors? A density functional theory study.Synthesis, structure, and properties of a mixed-valent triiron complex of tetramethyl reductic acid, an ascorbic acid analogue, and its relationship to a functional non-heme iron oxidation catalyst system.Biomimetic metal-radical reactivity: aerial oxidation of alcohols, amines, aminophenols and catechols catalyzed by transition metal complexes.Reflections on Small Molecule Manganese Models that Seek to Mimic Photosynthetic Water Oxidation ChemistryPreparation of a semiquinonate-bridged diiron(II) complex and elucidation of its geometric and electronic structures.Synthetic, spectroscopic, and DFT studies of iron complexes with iminobenzo(semi)quinone ligands: implications for o-aminophenol dioxygenases.Dioxygen reactivity of biomimetic Fe(II) complexes with noninnocent catecholate, o-aminophenolate, and o-phenylenediamine ligands.Group-10 metal complexes of biological molecules and related ligands: structural and functional properties.Electrochemistry, chemical reactivity, and time-resolved infrared spectroscopy of donor-acceptor systems [(Q(x))Pt(pap(y))] (Q = substituted o-quinone or o-iminoquinone; pap = phenylazopyridine).New avenues for ligand-mediated processes--expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands.Heteropentanuclear Oxalato-Bridged nd-4f (n=4, 5) Metal Complexes with NO Ligand: Synthesis, Crystal Structures, Aqueous Stability and Antiproliferative ActivityLinear, Trinuclear Cobalt Complexes with o-Phenylene-bis-Silylamido Ligands.Metal-Metal Interactions in Heterobimetallic Complexes with Dinucleating Redox-Active Ligands.Near-IR absorbing donor-acceptor ligand-to-ligand charge-transfer complexes of nickel(ii).Defining the electronic and geometric structure of one-electron oxidized copper-bis-phenoxide complexes.Metal atom lability in polynuclear complexes.Detailed evaluation of the geometric and electronic structures of one-electron oxidized group 10 (Ni, Pd, and Pt) metal(II)-(disalicylidene)diamine complexes.Site-isolated redox reactivity in a trinuclear iron complexSelective detection and recovery of gold at tannin-immobilized non-conducting electrode.Interactions of Metal-Based and Ligand-Based Electronic Spins in Neutral Tripyrrindione π Dimers.Trigonal Mn3 and Co3 clusters supported by weak-field ligands: a structural, spectroscopic, magnetic, and computational investigation into the correlation of molecular and electronic structureSyntheses and structures of Li, Fe, and Mo derivatives of N,N'-bis(2,6-diisopropylphenyl)-o-phenylenediamine.Structure and dynamics of dioxygen bound to cobalt and iron heme.Metalloradical complexes of manganese and chromium featuring an oxidatively rearranged ligand.Non-innocent ligand behaviour of a bimetallic Cu complex employing a bridging catecholate.UV-vis-NIR and EPR characterisation of the redox series [MQ(3)](2+,+,0,-,2-), M = Ru or Os, and Q = o-quinone derivative.Application of a structure/oxidation-state correlation to complexes of bridging azo ligands.Double oxidation localizes spin in a Ni bis-phenoxyl radical complex.Dinuclear complexes with bis(benzenedithiolate) ligands.Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes.A unique series of dinuclear transition metal-polyradical complexes with a m-phenylenediamine spacer and their catalytic reactivity.[(mu-L)[RuII(acac)2]2]n, n= 2+, +, 0, -, 2-, with L = 3,3',4,4'-tetraimino-3,3',4,4'-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediates.Coordination chemistry of 2-(8-aminoquinolino)-4,6-di-tert-butylphenol with manganese(IV), iron(III), and cobalt(II/III):N,O-coordinated o-iminobenzosemiquinonate(1-) pi radical monoanions vs.o-iminophenolate(2-) dianions.Dinuclear and mononuclear manganese(IV)-radical complexes and their catalytic catecholase activity.Aluminum complexes of the redox-active [ONO] pincer ligand.Four-center oxidation state combinations and near-infrared absorption in [Ru(pap)(Q)2]n (Q = 3,5-di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine, pap = 2-phenylazopyridine).Class III delocalization and exciton coupling in a bimetallic bis-ligand radical complex.
P2860
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P2860
Electronic structure of bis(o-iminobenzosemiquinonato)metal complexes (Cu, Ni, Pd). The art of establishing physical oxidation states in transition-metal complexes containing radical ligands.
description
2001 nî lūn-bûn
@nan
2001年の論文
@ja
2001年学术文章
@wuu
2001年学术文章
@zh
2001年学术文章
@zh-cn
2001年学术文章
@zh-hans
2001年学术文章
@zh-my
2001年学术文章
@zh-sg
2001年學術文章
@yue
2001年學術文章
@zh-hant
name
Electronic structure of bis(o- ...... es containing radical ligands.
@en
Electronic structure of bis(o- ...... es containing radical ligands.
@nl
type
label
Electronic structure of bis(o- ...... es containing radical ligands.
@en
Electronic structure of bis(o- ...... es containing radical ligands.
@nl
prefLabel
Electronic structure of bis(o- ...... es containing radical ligands.
@en
Electronic structure of bis(o- ...... es containing radical ligands.
@nl
P2093
P356
P1476
Electronic structure of bis(o- ...... es containing radical ligands.
@en
P2093
P304
P356
10.1021/JA003831D
P407
P577
2001-03-01T00:00:00Z