Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
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Building Bridges: Biocatalytic C–C-Bond Formation toward Multifunctional ProductsMetal Catalysis in Thiolation and Selenation Reactions of Alkynes Leading to Chalcogen-Substituted Alkenes and DienesUndirected, Homogeneous C-H Bond Functionalization: Challenges and OpportunitiesAn Umpolung Strategy for the Synthesis of β-Aminoketones via Copper-Catalyzed Electrophilic Amination of Cyclopropanols.Total synthesis of maoecrystal V: early-stage C-H functionalization and lactone assembly by radical cyclizationDirect stereospecific synthesis of unprotected N-H and N-Me aziridines from olefinsExpeditious diastereoselective synthesis of elaborated ketones via remote Csp(3)-H functionalizationOlefin Cyclopropanation via Carbene Transfer Catalyzed by Engineered Cytochrome P450 EnzymesSimultaneous structure-activity studies and arming of natural products by C-H amination reveal cellular targets of eupalmerin acetate.Atmospheric-pressure, liquid-phase, selective aerobic oxidation of alkanes catalysed by metal-organic frameworks.Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazolesPd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acidsC-H bonds as ubiquitous functionality: a general approach to complex arylated imidazoles via regioselective sequential arylation of all three C-H bonds and regioselective N-alkylation enabled by SEM-group transposition.Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.Synthesis of 1,3-diamines through rhodium-catalyzed C-H insertionCu-catalyzed direct amidation of aromatic C-H bonds: an access to arylamines.Chemo- and site-selective derivatizations of natural products enabling biological studies.Synthesis and reactivity of rhodium(II) N-triflyl azavinyl carbenes.Palladium(II)-catalyzed enantioselective C(sp³)-H activation using a chiral hydroxamic acid ligand.Examination of the mechanism of Rh(2)(II)-catalyzed carbazole formation using intramolecular competition experiments.Three-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation.Controlling factors for C-H functionalization versus cyclopropanation of dihydronaphthalenes.Highly stereoselective synthesis of cyclopentanes bearing four stereocentres by a rhodium carbene-initiated domino sequence.An enantiospecific synthesis of jiadifenolide.Enantioselective imidation of sulfides via enzyme-catalyzed intermolecular nitrogen-atom transferIntramolecular C(sp(3))H amination of arylsulfonyl azides with engineered and artificial myoglobin-based catalysts.Catalytic Enantioselective Allylic Amination of Olefins for the Synthesis of ent-Sitagliptin.Enzyme-controlled nitrogen-atom transfer enables regiodivergent C-H amination.Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reactionRecent advances in transition metal-catalyzed N-atom transfer reactions of azidesRuthenium-catalyzed γ-carbolinium ion formation from aryl azides; synthesis of dimebolin.Synthesis and reactivity of unique heterocyclic structures en route to substituted diamines.Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.Rhodium-Catalyzed C-H Amination - An Enabling Method for Chemical Synthesis.Regioselective C-H bond amination by aminoiodanes.Enzymatic C(sp(3))-H Amination: P450-Catalyzed Conversion of Carbonazidates into Oxazolidinones.Reactivity of N-(1,2,4-triazolyl)-substituted 1,2,3-triazoles.Metal-free intermolecular oxidative C-N bond formation via tandem C-H and N-H bond functionalization.Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes.C-H activation generates period-shortening molecules that target cryptochrome in the mammalian circadian clock.
P2860
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P2860
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
description
2008 nî lūn-bûn
@nan
2008 թուականի Յունուարին հրատարակուած գիտական յօդուած
@hyw
2008 թվականի հունվարին հրատարակված գիտական հոդված
@hy
2008年の論文
@ja
2008年論文
@yue
2008年論文
@zh-hant
2008年論文
@zh-hk
2008年論文
@zh-mo
2008年論文
@zh-tw
2008年论文
@wuu
name
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
@ast
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
@en
type
label
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
@ast
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
@en
prefLabel
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
@ast
Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
@en
P2860
P3181
P356
P1433
P1476
Catalytic C-H functionalization by metal carbenoid and nitrenoid insertion
@en
P2093
Huw M L Davies
P2860
P2888
P304
P3181
P356
10.1038/NATURE06485
P407
P577
2008-01-01T00:00:00Z
P5875
P6179
1035666678