Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.
about
Cryptic post-transition state bifurcations that reduce the efficiency of lactone-forming Rh-carbenoid C-H insertions.Catalytic asymmetric transannulation of NH-1,2,3-triazoles with olefins.Metal-Free Preparation of Cycloalkyl Aryl Sulfides via Di-tert-butyl Peroxide-Promoted Oxidative C(sp3)[BOND]H Bond Thiolation of Cycloalkanes.Rhodium-catalyzed NH insertion of pyridyl carbenes derived from pyridotriazoles: a general and efficient approach to 2-picolylamines and imidazo[1,5-a]pyridinesReactivity of N-(1,2,4-triazolyl)-substituted 1,2,3-triazoles.Ruthenium-catalyzed cycloadditions of 1-haloalkynes with nitrile oxides and organic azides: synthesis of 4-haloisoxazoles and 5-halotriazoles.Cascade alkylarylation of substituted N-allylbenzamides for the construction of dihydroisoquinolin-1(2H)-ones and isoquinoline-1,3(2H,4H)-dionesArylation of rhodium(II) azavinyl carbenes with boronic acids.Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines.Ring expansion and rearrangements of rhodium(II) azavinyl carbenes.Transannulation of 1-sulfonyl-1,2,3-triazoles with heterocumulenesVersatile reactivity of rhodium-iminocarbenes derived from N-sulfonyl triazoles.A Rh(II)-catalyzed multicomponent reaction by trapping an α-amino enol intermediate in a traditional two-component reaction pathway.Stereoselective 1,3-insertions of rhodium(II) azavinyl carbenesNew Approaches to the Synthesis of Metal Carbenes.Recent Advances in the Synthesis of Heterocycles and Related Substances Based on α-Imino Rhodium Carbene Complexes Derived from N-Sulfonyl-1,2,3-triazoles.Enantioselective Intermolecular C-H Functionalization of Allylic and Benzylic sp(3) C-H Bonds Using N-Sulfonyl-1,2,3-triazoles.Diversity-oriented synthesis of heterocycles and macrocycles by controlled reactions of oxetanes with α-iminocarbenes.Ring expansion of alkynyl cyclopropanes to highly substituted cyclobutenes via a N-sulfonyl-1,2,3-triazole intermediate.Sulfonyl-1,2,3-triazoles: convenient synthones for heterocyclic compounds.Unveiling latent α-iminocarbene reactivity for intermolecular cascade reactions through alkyne oxidative amination.Rh-Catalyzed Denitrogenative Reaction of N-Sulfonyl-1,2,3-triazoles with Isatoic Anhydrides and Oxadiazolones.α-Diazo oxime ethers for N-heterocycle synthesis.Synthesis of azasilacyclopentenes and silanols via Huisgen cycloaddition-initiated C-H bond insertion cascades.Diazo- and transition-metal-free C-H insertion: a direct synthesis of β-lactams.Rhodium-catalyzed denitrogenative thioacetalization of N-sulfonyl-1,2,3-triazoles with disulfides: an entry to diverse transformation of terminal alkynes.Rhodium-Catalyzed Intramolecular C-H Bond Activation with Triazoles: Preparation of Stereodefined Pyrrolidines and Other Related Cyclic Compounds.The benzoyl peroxide-promoted functionalization of simple alkanes with 2-aryl phenyl isonitrile.One-Pot Aminoethylation of Indoles/Pyrroles with Alkynes and Sulfonyl Azides.N,N'-diamidocarbenes facilitate selective C-H insertions and transfer hydrogenations.Rhodium-catalyzed denitrogenative [2,3] sigmatropic rearrangement: an efficient entry to sulfur-containing quaternary centers.Tandem 1,2-sulfur migration and (aza)-Diels-Alder reaction of β-thio-α-diazoimines: rhodium catalyzed synthesis of (fused)-polyhydropyridines, and cyclohexenes.Metal free and selective activation of one C–F bond in a bound CF3 group
P2860
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P2860
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.
description
2011 nî lūn-bûn
@nan
2011 թուականի Յունիսին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի հունիսին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.
@ast
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.
@en
type
label
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.
@ast
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.
@en
prefLabel
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.
@ast
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.
@en
P2093
P2860
P356
P1476
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.
@en
P2093
Jamal A Malik
Mikhail Zibinsky
Stepan Chuprakov
P2860
P304
10352-10355
P356
10.1021/JA202969Z
P407
P50
P577
2011-06-20T00:00:00Z