Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory
about
Chemical behaviour of a prototype boryl(phosphino)carbene.Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene.Stable four-pi-electron, four-membered heterocyclic cations and carbenes.Mechanistic Basis for Regioselection and Regiodivergence in Nickel-Catalyzed Reductive CouplingsPhase-transfer and other types of catalysis with cyclopropenium ions.Tuning the nucleophilicity in cyclopropenylidenes.Transient palladadiphosphanylcarbenes: singlet carbenes with an "inverse" electronic configuration (p(pi)2 instead of sigma2) and unusual transannular metal-carbene interactions (piC-->Pd donation and sigmaPd-->C back-donation).Stable cyclic carbenes and related species beyond diaminocarbenes.Recent developments of cyclopropene chemistry.Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal ComplexesPromotion of Organic Reactions by Non-Benzenoid Carbocyclic Aromatic Ions.Stable P-heterocyclic carbenes: scope and limitations.Borylenes: An Emerging Class of Compounds.Reactivity of cyclic (alkyl)(amino)carbenes (CAACs) and bis(amino)cyclopropenylidenes (BACs) with heteroallenes: comparisons with their N-heterocyclic carbene (NHCs) counterparts.A general strategy for regiocontrol in nickel-catalyzed reductive couplings of aldehydes and alkynes.A persistent P,N-heterocyclic carbene.Stable singlet carbenes as mimics for transition metal centers.A Brief Survey of our Contribution to Stable Carbene Chemistry.Insights into the carbene-initiated aggregation of [Fe(cot)(2)].Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs).Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagent.Triplet states of cyclopropenylidene and its isomers.Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene.Synthesis and structure of carbene-stabilized N-centered cations [L2N]+, [L2NR]2+, [LNR3]2+ , and [L3N]3+.Diaminocyclopropenylidene organocatalysts: beyond N-heterocyclic carbenes.Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon.Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2.Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene-carbene adducts.Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine.An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH].Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes.Cross-coupling reactions between stable carbenes.Synthesis and theoretical investigation of a 1,8-bis(bis(diisopropylamino)cyclopropeniminyl)naphthalene proton sponge derivative.Stable Di- and Tri-coordinated Carbon(II) Supported by an Electron-Rich β-Diketiminate Ligand.Eight-membered-ring diaminocarbenes bearing naphthalene moiety in the backbone: DFT studies, synthesis of amidinium salts, generation of free carbene, metal complexes, and solvent-free copper catalyzed azide-alkyne cycloaddition (CuAAC) reaction.A hybrid carbocyclic/N-heterocyclic carbene ligand.Exploring bis-(amino)cyclopropenylidene as a non-covalent Brønsted base catalyst in conjugate addition reactions.An electronic structure theory investigation of the physical chemistry of the intermolecular complexes of cyclopropenylidene with hydrogen halides.Cyclopropenylidene carbene ligands in palladium catalysed coupling reactions: carbene ligand rotation and application to the Stille reaction.Cyclopropenylidene carbene ligands in palladium C-C coupling catalysis.
P2860
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P2860
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory
description
2006 nî lūn-bûn
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2006 թուականի Մայիսին հրատարակուած գիտական յօդուած
@hyw
2006 թվականի մայիսին հրատարակված գիտական հոդված
@hy
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
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name
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory
@ast
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory
@en
type
label
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory
@ast
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory
@en
prefLabel
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory
@ast
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory
@en
P2860
P356
P1433
P1476
Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory
@en
P2093
V. Lavallo
P2860
P304
P356
10.1126/SCIENCE.1126675
P407
P577
2006-05-05T00:00:00Z