A general strategy for regiocontrol in nickel-catalyzed reductive couplings of aldehydes and alkynes.
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Recent advances in homogeneous nickel catalysisChemoselective reductive cross-coupling of 1,5-diene-3-ols with alkynes: a facile entry to stereodefined skipped trienes.A single step approach to piperidines via Ni-catalyzed β-carbon elimination.An expeditious route to eight-membered heterocycles by nickel-catalyzed cycloaddition: low-temperature C(sp)2-C(sp)3 bond cleavageRegioselective allene hydroarylation via one-pot allene hydrosilylation/Pd-catalyzed cross-coupling.Nickel-catalyzed cycloaddition of 1,3-dienes with 3-azetidinones and 3-oxetanones.Dimer involvement and origin of crossover in nickel-catalyzed aldehyde-alkyne reductive couplingsLigand steric contours to understand the effects of N-heterocyclic carbene ligands on the reversal of regioselectivity in Ni-catalyzed reductive couplings of alkynes and aldehydes.Ni(II) salts and 2-propanol effect catalytic reductive coupling of epoxides and alkynesRegiocontrol in catalytic reductive couplings through alterations of silane rate dependenceMechanism and origins of regio- and enantioselectivities in RhI-catalyzed hydrogenative couplings of 1,3-diynes and activated carbonyl partners: intervention of a cumulene intermediateMechanistic Basis for Regioselection and Regiodivergence in Nickel-Catalyzed Reductive CouplingsNickel Catalysis: Synergy between Method Development and Total SynthesisPhase-transfer and other types of catalysis with cyclopropenium ions.Formation of C-C bonds via ruthenium-catalyzed transfer hydrogenation().Regioselective allene hydrosilylation catalyzed by N-heterocyclic carbene complexes of nickel and palladium.A streamlined strategy for aglycone assembly and glycosylation.Catalytic selective synthesis.A convergent route to the CDEF-tetracycle of pectenotoxin-2.Stereoselective borylative ketone-diene coupling.Redox-triggered C-C coupling of diols and alkynes: synthesis of β,γ-unsaturated α-hydroxyketones and furans by ruthenium-catalyzed hydrohydroxyalkylation.1,1-Disubstituted olefin synthesis via Ni-catalyzed Markovnikov hydroalkylation of alkynes with alkyl halides.A Brief Survey of our Contribution to Stable Carbene Chemistry.Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Enables a Regioselective Synthesis of Dihydroisoquinolones.Gold-Catalyzed Oxidation of Propargylic Ethers with Internal C-C Triple Bonds: Impressive Regioselectivity Enabled by Inductive Effect.Gold-catalyzed highly regioselective oxidation of C-C triple bonds without acid additives: propargyl moieties as masked α,β-unsaturated carbonyls.Nickel-Catalyzed Regiodivergent Approach to Macrolide MotifsExo-selective reductive macrocyclization of ynals.Mechanistic study of nickel-catalyzed ynal reductive cyclizations through kinetic analysis.Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes.Metallacycle-Mediated Cross-Coupling in Natural Product Synthesis.Cobalt-catalyzed intramolecular olefin hydroarylation leading to dihydropyrroloindoles and tetrahydropyridoindoles.Nickel-catalyzed regio- and diastereoselective intermolecular three-component coupling of oxabicyclic alkenes with alkynes and organoboronic acids.Pyridine-enhanced head-to-tail dimerization of terminal alkynes by a rhodium-N-heterocyclic-carbene catalyst.Catalytic Hydroalkylation of Allenes.NHC Ligands Tailored for Simultaneous Regio- and Enantiocontrol in Nickel-Catalyzed Reductive Couplings.Nickel-catalyzed, directing-group-assisted [2+2+2] cycloaddition of imine and alkynes.Potential Energy Surfaces for Reactions of X Metal Atoms (X = Cu, Zn, Cd, Ga, Al, Au, or Hg) with YH4 Molecules (Y = C, Si, or Ge) and Transition Probabilities at Avoided Crossings in Some Cases
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P2860
A general strategy for regiocontrol in nickel-catalyzed reductive couplings of aldehydes and alkynes.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
A general strategy for regioco ...... ings of aldehydes and alkynes.
@en
type
label
A general strategy for regioco ...... ings of aldehydes and alkynes.
@en
prefLabel
A general strategy for regioco ...... ings of aldehydes and alkynes.
@en
P2093
P2860
P356
P1476
A general strategy for regioco ...... ings of aldehydes and alkynes.
@en
P2093
Grant J Sormunen
Hasnain A Malik
John Montgomery
P2860
P304
P356
10.1021/JA102262V
P407
P577
2010-05-01T00:00:00Z