Synthetic and structural studies on [Fe2(SR)2(CN)x(CO)6-x](x-) as active site models for Fe-only hydrogenases.
about
X-ray structure of the [FeFe]-hydrogenase maturase HydE from Thermotoga maritimaA simple complex on the verge of breakdown: isolation of the elusive cyanoformate ionPowering the planet: chemical challenges in solar energy utilizationSmall molecule mimics of hydrogenases: hydrides and redox.Vibrational analysis of the model complex (mu-edt)[Fe(CO)(3)](2) and comparison to iron-only hydrogenase: the activation scale of hydrogenase model systemsBorane-protected cyanides as surrogates of H-bonded cyanides in [FeFe]-hydrogenase active site models.Favorable Protonation of the (μ-edt)[Fe(2)(PMe(3))(4)(CO)(2)(H-terminal)](+) Hydrogenase Model Complex Over Its Bridging μ-H Counterpart: A Spectroscopic and DFT Study.Synthetic models for the active site of the [FeFe]-hydrogenase: catalytic proton reduction and the structure of the doubly protonated intermediate.Diiron azadithiolates as models for the [FeFe]-hydrogenase active site and paradigm for the role of the second coordination sphereSpectroscopic Investigations of [FeFe] Hydrogenase Maturated with [(57)Fe2(adt)(CN)2(CO)4](2-)Extending the motif of the [FeFe]-hydrogenase active site models: protonation of Fe2(NR)2(CO)6-xLx species.Preparation and Protonation of Fe2(pdt)(CNR)6, Electron-Rich Analogues of Fe2(pdt)(CO)6New nitrosyl derivatives of diiron dithiolates related to the active site of the [FeFe]-hydrogenases.Approaches to efficient molecular catalyst systems for photochemical H2 production using [FeFe]-hydrogenase active site mimics.De novo design of functional proteins: Toward artificial hydrogenases.Excited state relaxation processes of H2-evolving Ru-Pd supramolecular photocatalysts containing a linear or non-linear bridge: a DFT and TDDFT study.Encapsulating [FeFe]-hydrogenase model compounds in peptide hydrogels dramatically modifies stability and photochemistry.Chelating tris(amidate) ligands: versatile scaffolds for nickel(II).Biomimetic model for [FeFe]-hydrogenase: asymmetrically disubstituted diiron complex with a redox-active 2,2'-bipyridyl ligand.Isolation, observation, and computational modeling of proposed intermediates in catalytic proton reductions with the hydrogenase mimic Fe2(CO)6S2C6H4.Synthesis, structures and electrochemical properties of nitro- and amino-functionalized diiron azadithiolates as active site models of Fe-only hydrogenases.A reduced 2Fe2S cluster probe of sulfur-hydrogen versus sulfur-gold interactions.Molybdenum carbonyl complexes with pyridylimino acidato ligands.Photoswitchable electrochemical behaviour of a [FeFe] hydrogenase model with a dithienylethene derivative.Hydrophilic Quaternary Ammonium-Group-Containing [FeFe]-Hydrogenase Models: Synthesis, Structures, and Electrocatalytic Hydrogen Production.Synthesis, characterization, and H/D exchange of μ-hydride-containing [FeFe]-hydrogenase subsite models formed by protonation reactions of (μ-TDT)Fe2(CO)4(PMe3)2 (TDT = SCH2SCH2S) with protic acids.Nitrogen heterocyclic carbene containing pentacoordinate iron dicarbonyl as a [Fe]-hydrogenase active site model.Synthesis, characterization, and electrochemical properties of diiron propaneditellurolate (PDTe) complexes as active site models of [FeFe]-hydrogenases.Effect of the S-to-S bridge on the redox properties and H2 activation performance of diiron complexes related to the [FeFe]-hydrogenase active site.Characterization of a monocyanide model of FeFe hydrogenases - highlighting the importance of the bridgehead nitrogen for catalysis.[FeFe] Hydrogenase active site model chemistry in a UiO-66 metal-organic framework.Bio-Inspired Iron and Nickel ComplexesAmphiphilic polymeric micelles as microreactors: improving the photocatalytic hydrogen production of the [FeFe]-hydrogenase mimic in waterInaccessibility of the μ-hydride species in [FeFe] hydrogenasesNew Approach to [FeFe]-Hydrogenase Models Using Aromatic ThioketonesCrystallographic and spectroscopic assignment of the proton transfer pathway in [FeFe]-hydrogenases
P2860
Q27650297-634EDD8E-56BB-4677-91AE-97383ED258DFQ28237452-CD4EDDE2-9742-4C45-9FB4-C0DCB007F891Q28317749-68387503-499C-415D-BD82-510C599BDF36Q33393660-7A7C9C8B-9F7B-4128-BD79-881698AAB117Q33812355-6385701A-219C-4A2C-9FB2-40A013FBFB75Q35191300-9B1352C7-B162-4344-9808-6671A41B5730Q36398848-2802CE8C-5E45-4DBF-AC4D-FE4C25E413A6Q36445476-8587C16B-58D7-4CD7-90C6-404E847C0F8DQ36701939-57BB17D3-8582-448A-A2A1-99D2FD51DB4EQ36706563-D370C9E6-CD8A-4BD0-9857-00E1CFC08FFCQ36737258-A8D3C352-6C30-41C2-9D72-C16AC8FF8AA0Q36768109-85B9DEA3-32E9-4FA8-9333-E0727441BA67Q37329226-A9F7DE47-A0B9-4567-B0D6-05CB3DE92AA8Q37943688-934106D3-A188-4120-82B9-09E132CE5856Q38166651-18224410-FE4C-413B-BB10-B3AC2E302A33Q38829180-455D9613-DF02-47D7-9DB7-F3DA4810A215Q39550641-C22D5593-A051-4B13-84F1-AE417B4C0320Q43214077-A9AB2346-4EA2-4C4C-8069-5B5BE53737C0Q44504559-590F6B2C-6FD8-4F70-B935-411004FFE235Q44575617-36DC4693-B9DA-4919-8A5B-42A1984835BDQ45066301-0BC35D47-F7A4-484F-B1E5-92B68133A90EQ46672437-F5B02A24-741E-4C51-AADD-17BEDCADE323Q46947733-6EFDA5EE-3E20-4597-9F58-02FE7816957EQ50242519-9EA99D1E-42D1-465D-BFF4-A92A9C740DF8Q51131015-50A8367A-03E6-4E91-BDA3-6EAC63D5C206Q51558295-A02A4F5B-929E-4753-B49F-5EEDB1A6AE36Q51720421-78A54849-9580-4DC2-ADEB-94923CDE1A81Q52745793-1CE2C0E6-98E8-4417-807C-2A484C1C25A7Q52878281-004014EC-54C5-4BFA-BB2F-62ADA9C6D98CQ53579971-5CADFE26-CA7C-4AA6-9F90-51B2AD109233Q54524892-5993071D-E7E6-48AB-948F-672EA5CBDD1AQ56427201-B8D6227B-941B-475B-AAE3-F0DC26B1789DQ57366045-B8C5B0E2-5417-49AC-929E-4DCDF0DC76D0Q57905310-D68EF1FA-A4F1-4CB3-874D-C42B752BDD23Q58385237-B0797A9C-2675-4FF5-A2FD-00F02617053BQ58568273-1F39FEF8-AD53-4928-8944-89857E914D03
P2860
Synthetic and structural studies on [Fe2(SR)2(CN)x(CO)6-x](x-) as active site models for Fe-only hydrogenases.
description
2001 nî lūn-bûn
@nan
2001 թուականի Դեկտեմբերին հրատարակուած գիտական յօդուած
@hyw
2001 թվականի դեկտեմբերին հրատարակված գիտական հոդված
@hy
2001年の論文
@ja
2001年論文
@yue
2001年論文
@zh-hant
2001年論文
@zh-hk
2001年論文
@zh-mo
2001年論文
@zh-tw
2001年论文
@wuu
name
Synthetic and structural studi ...... dels for Fe-only hydrogenases.
@ast
Synthetic and structural studi ...... dels for Fe-only hydrogenases.
@en
type
label
Synthetic and structural studi ...... dels for Fe-only hydrogenases.
@ast
Synthetic and structural studi ...... dels for Fe-only hydrogenases.
@en
prefLabel
Synthetic and structural studi ...... dels for Fe-only hydrogenases.
@ast
Synthetic and structural studi ...... dels for Fe-only hydrogenases.
@en
P2093
P356
P1476
Synthetic and structural studi ...... odels for Fe-only hydrogenases
@en
P2093
J D Lawrence
S R Wilson
T B Rauchfuss
P304
12518-12527
P356
10.1021/JA016071V
P407
P577
2001-12-01T00:00:00Z