Diiron azadithiolates as models for the [FeFe]-hydrogenase active site and paradigm for the role of the second coordination sphere
about
Stepwise isotope editing of [FeFe]-hydrogenases exposes cofactor dynamicsAn iron(ii) hydride complex of a ligand with two adjacent β-diketiminate binding sites and its reactivity.A pendant proton shuttle on [Fe4N(CO)12]- alters product selectivity in formate vs. H2 production via the hydride [H-Fe4N(CO)12].Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.Crystal structure of [μ2-3,3-dimethyl-4-(propan-2-yl-idene)thietane-2,2-dithiol-ato-κ(4) S:S':S:S']bis[tricarbonyl-iron(I)](Fe-Fe)Synthesis of Diiron(I) Dithiolato Carbonyl ComplexesMechanism of H2 Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides.Rational Synthesis of the Carbonyl(perthiolato)diiron [Fe2(S3CPh2)(CO)6] and Related Complexes.Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes.Exploring secondary-sphere interactions in Fe-N x H y complexes relevant to N2 fixation[FeFe]-Hydrogenase H-cluster mimics mediated by naphthalene monoimide derivatives of peri-substituted dichalcogenides.Influence of the Dithiolate Bridge on the Oxidative Processes of Diiron Models Related to the Active Site of [FeFe] Hydrogenases.Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators.Synthetic [NiFe] models with a fluxional CO ligand.From Enzymes to Functional Materials-Towards Activation of Small Molecules.Development of air-stable hydrogen evolution catalysts.Gold(I) Hydrides as Proton Acceptors in Dihydrogen Bond Formation.Sterically Stabilized Terminal Hydride of a Diiron Dithiolate.Synthesis, structural characterization and conversion of dinuclear iron-sulfur clusters containing the disulfide ligand: [Cp*Fe(μ-η2:η2-bdt)(cis-μ-η1:η1-S2)FeCp*], [Cp*Fe(μ-S(C6H4S2))(cis-μ-η1:η1-S2)FeCp*], and [{Cp*Fe(bdt)}2(trans-μ-η1:η1-S2)].Catalytic Activity of Thiolate-Bridged Diruthenium Complexes Bearing Pendent Ether Moieties in the Oxidation of Molecular Dihydrogen.Comparative studies on the contribution of NHS hydrogen bonds in tungsten and molybdenum benzenedithiolate complexes.Small iron-carbonyl clusters bearing imidazolium-2-trithioperoxycarboxylate ligands.Electronic and molecular structure relations in diiron compounds mimicking the [FeFe]-hydrogenase active site studied by X-ray spectroscopy and quantum chemistry.Dual-emitting quantum dot/carbon nanodot-based nanoprobe for selective and sensitive detection of Fe(3+) in cells.Reduced thione ligation is preferred over neutral phosphine ligation in diiron biomimics regarding electronic functionality: a spectroscopic and computational investigation.Characterization of a Borane σ Complex of a Diiron Dithiolate: Model for an Elusive Dihydrogen Adduct.Structural and functional synthetic model of mono-iron hydrogenase featuring an anthracene scaffold.Synthesis and coordination chemistry of (PNEt2)2-bridged [2]ferrocenophanes.Redox and Acid-Base Properties of Binuclear 4-Terphenyldithiophenolate Complexes of Nickel.
P2860
Q28828282-B2EA2CEB-CACF-4F61-9E66-F4BD1A9AB51BQ31036452-51494A58-8892-4B62-B144-EAA7C97C004FQ33814070-617C1DB0-C898-4278-986E-39C6F9AA42E9Q35955713-B6E5AD0D-1810-4328-9EC9-29828626C6A6Q36280581-76D03DE9-B858-41B3-AD69-D51ED8F7263AQ37067812-D891D45E-9FF4-4D65-A37D-62B1DC7F7EF7Q37267957-365645EA-BC62-4944-B6CF-45B8218E9927Q37384059-B72742EF-FB2F-4B55-B7C7-12037D57119BQ38880043-AAC3381A-756D-4CAD-BD40-8A8962111252Q39455495-516A3492-14ED-4587-BB22-99B7F4EC2C7FQ42314601-D053F45B-7900-45F6-BCC3-DDCE8702DDCDQ46336786-1711A977-123D-49FF-86C2-907771BCEE67Q46437132-F975F4BA-2B86-49FA-8240-3EA2F3674F29Q46526445-03B071B9-863A-4D51-AB8D-1C89B9CB8444Q47620559-DA6FC668-9690-4CC2-8243-0C81BFA03F4FQ47925076-5BA7F2C8-4787-4876-8C0C-961F6F590E2AQ47997780-0D3B0C13-FB08-4942-8916-101F4D95C7C5Q48060872-453FA406-06A2-4858-9121-9E215B2E432FQ48135195-A97A99C4-69CB-4E58-A3D4-948C4018437EQ48157450-EC63AA52-D497-4F59-8B64-420B88D6E1D5Q48277361-341B0463-F45E-42F0-9EE1-A44433BC0F37Q48312571-0C230501-9DC5-4585-9875-89AB640DCE6EQ49946097-0F0B2092-67DF-48E0-8A06-BC91A17F379EQ50107356-6CA0DE1C-4CC4-4492-974F-156CE475A576Q50201781-0AE27ACB-EF09-4F2F-BD2E-2EF672EC85F5Q51084319-F4872C1B-D60D-4014-875C-8647BF54E7B0Q51830773-681F5EA5-D297-4218-8D60-630E2FF73A43Q52641329-9580DFF9-FCFE-45C5-B671-D1BCD8EE8D68Q52811159-17BF731C-6E9E-45A4-98CF-35EFA663363FQ53579532-E0DD20B2-8C7D-411D-9336-6266F62BBB96
P2860
Diiron azadithiolates as models for the [FeFe]-hydrogenase active site and paradigm for the role of the second coordination sphere
description
2015 nî lūn-bûn
@nan
2015年の論文
@ja
2015年論文
@yue
2015年論文
@zh-hant
2015年論文
@zh-hk
2015年論文
@zh-mo
2015年論文
@zh-tw
2015年论文
@wuu
2015年论文
@zh
2015年论文
@zh-cn
name
Diiron azadithiolates as model ...... the second coordination sphere
@ast
Diiron azadithiolates as model ...... the second coordination sphere
@en
type
label
Diiron azadithiolates as model ...... the second coordination sphere
@ast
Diiron azadithiolates as model ...... the second coordination sphere
@en
prefLabel
Diiron azadithiolates as model ...... the second coordination sphere
@ast
Diiron azadithiolates as model ...... the second coordination sphere
@en
P2860
P1476
Diiron azadithiolates as model ...... the second coordination sphere
@en
P2093
Thomas B Rauchfuss
P2860
P304
P356
10.1021/ACS.ACCOUNTS.5B00177
P407
P577
2015-06-16T00:00:00Z