Enantioselective construction of remote quaternary stereocentres
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Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide.Palladium-Catalyzed Enantioselective Heck Alkenylation of Trisubstituted Allylic Alkenols: A Redox-Relay Strategy to Construct Vicinal StereocentersCoupling of sterically hindered trisubstituted olefins and benzocyclobutenones by C-C activation: total synthesis and structural revision of cycloinumakiol.Investigating the nature of palladium chain-walking in the enantioselective redox-relay Heck reaction of alkenyl alcoholsSynthesis of highly functionalized tri- and tetrasubstituted alkenes via Pd-catalyzed 1,2-hydrovinylation of terminal 1,3-dienes.Development and Investigation of a Site Selective Palladium-Catalyzed 1,4-Difunctionalization of Isoprene using Pyridine-Oxazoline Ligands.Palladium-Catalyzed Cross-Coupling of α-Bromocarbonyls and Allylic Alcohols for the Synthesis of α-Aryl Dicarbonyl Compounds.ORGANIC CHEMISTRY. Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic aminesEnantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium SaltsRelative reactivity of alkenyl alcohols in the palladium-catalyzed redox-relay Heck reaction.Palladium-catalyzed enantioselective 1,1-fluoroarylation of aminoalkenes.Rh-Catalyzed Desymmetrization of α-Quaternary Centers by Isomerization-Hydroacylation.Catalytic enantioselective synthesis of quaternary carbon stereocentresA direct approach to amines with remote stereocentres by enantioselective CuH-catalysed reductive relay hydroaminationAlkenyl carbonyl derivatives in enantioselective redox relay Heck reactions: accessing α,β-unsaturated systemsPalladium-catalyzed enantioselective Heck alkenylation of acyclic alkenols using a redox-relay strategy.Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary StereocentersEnantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers.Enantioselective oxidative boron Heck reactions.Remote functionalization through alkene isomerization.Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Alkenes.Formation of C(sp(3) )-C(sp(3) ) Bonds through Nickel-Catalyzed Decarboxylative Olefin Hydroalkylation Reactions.Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes.Palladium-Catalyzed Enantioselective Redox-Relay Heck Alkynylation of Alkenols To Access Propargylic Stereocenters.Stereospecific Cross Couplings To Set Benzylic, All-Carbon Quaternary Stereocenters in High Enantiopurity.Diazafluorenone-Promoted Oxidation Catalysis: Insights into the Role of Bidentate Ligands in Pd-Catalyzed Aerobic Aza-Wacker Reactions.Palladium-Catalyzed Enantioselective Redox-Relay Heck Arylation of 1,1-Disubstituted Homoallylic Alcohols.Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reactionChain Walking of Allylrhodium Species Towards Esters During Rhodium-Catalyzed Nucleophilic Allylations of IminesThe development and mechanistic investigation of a palladium-catalyzed 1,3-arylfluorination of chromenes.A unique Pd-catalysed Heck arylation as a remote trigger for cyclopropane selective ring-openingZirconocene-assisted remote cleavage of C-C and C-O bonds: application to acyclic stereodefined metalated hydrocarbons.Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates.Access to enantioenriched 2,3- and 2,5-dihydrofurans with a fully substituted C2 stereocenter by Pd-catalyzed asymmetric intermolecular Heck reaction.Stereodefined acyclic trisubstituted metal enolates towards the asymmetric formation of quaternary carbon stereocentres.Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol.Palladium-Catalyzed Enantioselective Narasaka-Heck Reaction/Direct C-H Alkylation of Arenes: Iminoarylation of Alkenes.Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer.Diastereoselective Synthesis of Highly Substituted Tetrahydrofurans by Pd-Catalyzed Tandem Oxidative Cyclization-Redox Relay Reactions Controlled by Intramolecular Hydrogen Bonding.Terminal-Selective Functionalization of Alkyl Chains by Regioconvergent Cross-Coupling.
P2860
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P2860
Enantioselective construction of remote quaternary stereocentres
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2014 nî lūn-bûn
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2014 թուականի Ապրիլին հրատարակուած գիտական յօդուած
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2014 թվականի ապրիլին հրատարակված գիտական հոդված
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2014年の論文
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2014年論文
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2014年論文
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2014年論文
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2014年論文
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2014年論文
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2014年论文
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name
Enantioselective construction of remote quaternary stereocentres
@ast
Enantioselective construction of remote quaternary stereocentres
@en
Enantioselective construction of remote quaternary stereocentres.
@nl
type
label
Enantioselective construction of remote quaternary stereocentres
@ast
Enantioselective construction of remote quaternary stereocentres
@en
Enantioselective construction of remote quaternary stereocentres.
@nl
prefLabel
Enantioselective construction of remote quaternary stereocentres
@ast
Enantioselective construction of remote quaternary stereocentres
@en
Enantioselective construction of remote quaternary stereocentres.
@nl
P2093
P2860
P356
P1433
P1476
Enantioselective construction of remote quaternary stereocentres
@en
P2093
Harshkumar H Patel
Matthew S Sigman
Tian-Sheng Mei
P2860
P2888
P304
P356
10.1038/NATURE13231
P407
P577
2014-04-09T00:00:00Z
P5875
P6179
1001746296