Pd(II)-catalyzed hydroxyl-directed C-H olefination enabled by monoprotected amino acid ligands.
about
Weak coordination as a powerful means for developing broadly useful C-H functionalization reactions.Synthesis of ethoxy dibenzooxaphosphorin oxides through palladium-catalyzed C(sp(2))-H activation/C-O formation.Silanol: a traceless directing group for Pd-catalyzed o-alkenylation of phenols.Palladium(II)-catalyzed dehydrogenative alkenylation of cyclic enaminones via the Fujiwara-Moritani reaction.Scope and Mechanistic Study of the Coupling Reaction of α, β-Unsaturated Carbonyl Compounds with Alkenes: Uncovering Electronic Effects on Alkene Insertion vs Oxidative Coupling PathwaysA divergent enantioselective strategy for the synthesis of griseusins.Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes.Ligand-Accelerated ortho-C-H Olefination of Phenylacetic Acids.Palladium-catalyzed C-H functionalization using guanidine as a directing group: ortho arylation and olefination of arylguanidines.Ether-directed ortho-C-H olefination with a palladium(II)/monoprotected amino acid catalyst.Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary StereocentersThe Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes.If C-H bonds could talk: selective C-H bond oxidationC-H activation: a complementary tool in the total synthesis of complex natural products.Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate.Palladium-catalyzed cross-dehydrogenative functionalization of C(sp(2))-H Bonds.Versatile reactivity of Pd-catalysts: mechanistic features of the mono-N-protected amino acid ligand and cesium-halide base in Pd-catalyzed C-H bond functionalization.Synthesis of heterocyclic-fused benzopyrans via the Pd(II)-catalyzed C-H alkenylation/C-O cyclization of flavones and coumarins.Palladium-catalyzed dehydrogenation/oxidative cross-coupling sequence of β-heteroatom-substituted ketones.Heterocycle Formation via Palladium-Catalyzed C-H Functionalization.Ligand-accelerated cross-coupling of C(sp2)-H bonds with arylboron reagents.Pd(II)-catalyzed C-H functionalizations directed by distal weakly coordinating functional groupsConstructing multiply substituted arenes using sequential palladium(II)-catalyzed C-H olefinationCobalt-Catalyzed, Aminoquinoline-Directed Functionalization of Phosphinic Amide sp2 C-H Bonds.Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reactionCobalt-catalyzed, aminoquinoline-directed C(sp²)-H bond alkenylation by alkynes.Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation.Aerobic palladium-catalyzed dioxygenation of alkenes enabled by catalytic nitrite.Monoselective o-C-H Functionalizations of Mandelic Acid and α-Phenylglycine.Catalytic 1,4-rhodium(III) migration enables 1,3-enynes to function as one-carbon oxidative annulation partners in C-H functionalizations.Ligand-accelerated C-H activation reactions: evidence for a switch of mechanism.N-acylsulfonamide assisted tandem C-H olefination/annulation: synthesis of isoindolinones.An Improved Catalyst Architecture for Rhodium (III) Catalyzed C-H Activation and its Application to Pyridone Synthesis.Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group.Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed C-H Bond Activation.Aerobic synthesis of pyrroles and dihydropyrroles from imines: palladium(II)-catalyzed intramolecular C-H dehydrogenative cyclization.Aldehyde-selective Wacker-type oxidation of unbiased alkenes enabled by a nitrite co-catalyst.Rh-catalyzed sulfonic acid group directed ortho C-H olefination of arenes.Rhodium-catalyzed enantioselective addition to unsymmetrical α-diketones: tandem one-pot synthesis of optically active 3-tetrasubstituted isochroman derivatives.Controllable Mono-/Dialkenylation of Benzyl Thioethers through Rh-Catalyzed Aryl C-H Activation.
P2860
Q30410596-F73B502E-F5A7-4B1F-8476-B8390AA61208Q33830073-E9D078AF-C711-4DD2-A2F2-549CCB6920EBQ35166668-1EC56DC0-72A0-4CE1-8A6C-83F76FC804B5Q35607259-356AF20A-DE24-4C83-AC7A-208851AD8D19Q35773663-4B7ED8B7-F271-4D5C-ACC6-48747798493EQ36047988-AF7E0EA3-39AC-4555-AC01-993440B7C05FQ36290673-92A1DF5F-3A45-4BB7-B610-391E99A9B1A6Q37074358-7FC2F289-E9DA-4970-8919-FDFEF1A5E686Q37205354-1C5C2B35-6E23-4F2D-BBC4-3BCE8CF484F8Q37206766-EA14689E-3AF9-47D6-A44D-28A017E0D24AQ37289750-3563B86A-A55E-4B8E-BC0A-C1F90D7BA0F3Q37400739-741730A8-8C6D-4958-AC49-3EE46275C029Q37853955-340378EF-64BB-428C-80B4-310978485BB4Q38021971-814D4B9F-6CBC-43B5-9762-4AB899B59A65Q38097103-C6B96E4F-9D26-4259-AF88-87F7727C3997Q38152412-925000B6-2545-4F83-B5B0-CFA5514A1B12Q38195732-2B8341D2-B6C4-4E19-8EA5-C3E297272878Q38439206-3D90C4EC-7BBE-409E-B16E-AC6EC833488FQ38457733-CFDC3C96-CC46-4547-A2F8-C1C9BED024DCQ38891800-61248CF8-4C90-4D75-9D77-B07861C2538CQ39588170-4633419E-3699-4C07-9038-F3F4621410C9Q40657921-00FEB162-8F95-4BA0-B6B5-1EA6D9DBA454Q40773580-F9EEF4DE-96E9-4179-A4F2-BAB7A1D83B53Q41784519-3FE601C8-25D8-4224-995F-A8D373009B54Q41889268-0146D976-9C25-494D-BF37-442D7C9816AFQ41955637-9B53EC42-1531-4E59-B785-3A5B7ECDC408Q41986987-FFC53FE5-AD1E-4750-B772-40F81D2DA8A8Q42074312-BAD3A3F2-5096-4E18-B1CC-EB3997AEEC3DQ42094195-7914A604-F8F2-46E4-B5A8-457354E5D250Q42129338-DE734F0F-7B32-4297-B7BE-B58BA5AC4874Q42161197-633E28A1-6996-48E8-A5B5-1D8BB3A532EEQ42636203-93CD84D8-BA07-45D8-A651-85C0A263ECC6Q43095444-7006E971-8A83-4C49-9133-4A7FFF2F7E0AQ43796728-560478C5-DEA7-4202-84BB-54AF7D5B79F4Q44573208-3B7351CE-EE37-44F6-80C4-408C7068BB23Q44669804-A2D5B29F-5DBB-4B23-9375-1F9FD6ABAD68Q45813740-2800C4C8-AA2F-4970-B648-FE6F6C3D65A8Q45912722-571BEF90-CD6D-4E6C-B13B-837A173B4CE0Q45913153-1ACC8957-ABF8-4E74-893C-5745AD66BB7BQ46337037-85FC676D-D032-4C08-AB04-C243F03B9292
P2860
Pd(II)-catalyzed hydroxyl-directed C-H olefination enabled by monoprotected amino acid ligands.
description
2010 nî lūn-bûn
@nan
2010 թուականի Ապրիլին հրատարակուած գիտական յօդուած
@hyw
2010 թվականի ապրիլին հրատարակված գիտական հոդված
@hy
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
name
Pd(II)-catalyzed hydroxyl-dire ...... oprotected amino acid ligands.
@ast
Pd(II)-catalyzed hydroxyl-dire ...... oprotected amino acid ligands.
@en
type
label
Pd(II)-catalyzed hydroxyl-dire ...... oprotected amino acid ligands.
@ast
Pd(II)-catalyzed hydroxyl-dire ...... oprotected amino acid ligands.
@en
prefLabel
Pd(II)-catalyzed hydroxyl-dire ...... oprotected amino acid ligands.
@ast
Pd(II)-catalyzed hydroxyl-dire ...... oprotected amino acid ligands.
@en
P2860
P356
P1476
Pd(II)-catalyzed hydroxyl-dire ...... oprotected amino acid ligands.
@en
P2093
P2860
P304
P356
10.1021/JA101909T
P407
P577
2010-04-01T00:00:00Z