Palladium(II)-catalyzed dehydrogenative alkenylation of cyclic enaminones via the Fujiwara-Moritani reaction.
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Biomimetic Aerobic C-H Olefination of Cyclic Enaminones at Room Temperature: Development toward the Synthesis of 1,3,5-Trisubstituted Benzenes.Regioselective C5-alkylation and C5-methylcarbamate formation of 2,3-dihydro-4-pyridones and C3-alkylation and C3-methylcarbamate formation of 4-(pyrrolidin-1-yl)furan-2(5H)-one.Dehydrogenative alkenylation of uracils via palladium-catalyzed regioselective C-H activation.Palladium-catalyzed direct C-H arylation of cyclic enaminones with aryl iodidesBoron-Heck reaction of cyclic enaminones: regioselective direct arylation via oxidative palladium(II) catalysis.Direct access to functionalized azepanes by cross-coupling with α-halo eneformamides.Transition metal-catalyzed C(vinyl)-C(vinyl) bond formation via double C(vinyl)-H bond activation.Palladium-catalyzed cross-dehydrogenative functionalization of C(sp(2))-H Bonds.Synthesis of heterocyclic-fused benzopyrans via the Pd(II)-catalyzed C-H alkenylation/C-O cyclization of flavones and coumarins.A Pd-catalyzed one-pot dehydrogenative aromatization and ortho-functionalization sequence of N-acetyl enamides.Synthesis of heterocyclic-fused benzofurans via C-H functionalization of flavones and coumarins.Palladium-catalyzed dehydrogenation/oxidative cross-coupling sequence of β-heteroatom-substituted ketones.A facile route to isoflavone quinones via the direct cross-coupling of chromones and quinones.Cyclic enaminones. Part II: applications as versatile intermediates in alkaloid synthesis.Enantioselective synthesis of 3,4-dihydro-1,2-oxazepin-5(2H)-ones and 2,3-dihydropyridin-4(1H)-ones from β-substituted β-hydroxyaminoaldehydes.Copper-assisted palladium(II)-catalyzed direct arylation of cyclic enaminones with arylboronic acids.One-pot catalysis of dehydrogenation of cyclohexanones to phenols and oxidative Heck coupling: expedient synthesis of coumarins.Palladium-catalyzed direct C-3 oxidative alkenylation of phosphachromones.Synthesis of conjugated dienes via a biomimetic aerobic oxidative coupling of two C(vinyl)-H bonds.Catalytic intermolecular β-C-H alkenylation of α-enamino-ketones with simple alkynes.A Sequential Cycloaddition Strategy for the Synthesis of Alsmaphorazine B Traces a Path Through a Family of Alstonia Alkaloids.Directed C-C bond cleavage of a cyclopropane intermediate generated from N-tosylhydrazones and stable enaminones: expedient synthesis of functionalized 1,4-ketoaldehydes.A direct cross-coupling reaction of electron-deficient alkenes using an oxidizing directing group.Weinreb amide directed cross-coupling reaction between electron-deficient alkenes catalyzed by a rhodium catalyst.Expedient access to α,β-difunctionalized azepenes using α-halo eneformamides: application to the one-pot synthesis of 2-benzazepanes.Palladium-catalyzed acid-free Fujiwara-Moritani alkenylation of 4-thiazolidinones.Pd(II)-catalyzed intramolecular oxidative Heck dearomative reaction: approach to thiazole-fused pyrrolidinones with a C2-azaquarternary center.Regioselective C3 alkenylation of 4 H-pyrido[1,2-a]pyrimidin-4-ones via palladium-catalyzed C-H activation.Modular access to vicinally functionalized allylic (thio)morpholinonates and piperidinonates by substrate-controlled annulation of 1,3-azadienes with hexacyclic anhydrides.
P2860
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P2860
Palladium(II)-catalyzed dehydrogenative alkenylation of cyclic enaminones via the Fujiwara-Moritani reaction.
description
2011 nî lūn-bûn
@nan
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
2011年论文
@zh
2011年论文
@zh-cn
name
Palladium(II)-catalyzed dehydr ...... he Fujiwara-Moritani reaction.
@ast
Palladium(II)-catalyzed dehydr ...... he Fujiwara-Moritani reaction.
@en
type
label
Palladium(II)-catalyzed dehydr ...... he Fujiwara-Moritani reaction.
@ast
Palladium(II)-catalyzed dehydr ...... he Fujiwara-Moritani reaction.
@en
prefLabel
Palladium(II)-catalyzed dehydr ...... he Fujiwara-Moritani reaction.
@ast
Palladium(II)-catalyzed dehydr ...... he Fujiwara-Moritani reaction.
@en
P2860
P356
P1433
P1476
Palladium(II)-catalyzed dehydr ...... he Fujiwara-Moritani reaction.
@en
P2093
Micah J Niphakis
P2860
P304
P356
10.1021/OL202677G
P407
P577
2011-10-13T00:00:00Z