PyDipSi: a general and easily modifiable/traceless Si-tethered directing group for C-H acyloxylation of arenes.
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Silanol: a traceless directing group for Pd-catalyzed o-alkenylation of phenols.Synthesis of catechols from phenols via Pd-catalyzed silanol-directed C-H oxygenation.Double-fold C-H oxygenation of arenes using PyrDipSi: a general and efficient traceless/modifiable silicon-tethered directing group.General method for the synthesis of salicylic acids from phenols through palladium-catalyzed silanol-directed C-H carboxylationPd-catalyzed modifiable silanol-directed aromatic C-H oxygenationGeneral and practical carboxyl-group-directed remote C-H oxygenation reactions of arenes.The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes.Removable directing groups in organic synthesis and catalysis.Arene C-H functionalisation using a removable/modifiable or a traceless directing group strategy.Cross-dehydrogenative coupling for the intermolecular C-O bond formation.Advances in the development of catalytic tethering directing groups for C-H functionalization reactions.Twofold unsymmetrical C-H functionalization of PyrDipSi-substituted arenes: a general method for the synthesis of substituted meta-halophenols.A general strategy toward aromatic 1,2-ambiphilic synthons: palladium-catalyzed ortho-halogenation of PyDipSi-arenesMeta-selective C-H functionalization using a nitrile-based directing group and cleavable Si-tether.Monoselective o-C-H Functionalizations of Mandelic Acid and α-Phenylglycine.Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group.Ruthenium(II)-catalyzed C-H alkenylations of phenols with removable directing groups.Ketimido metallophthalocyanines: an approach to phthalocyanine-supported mononuclear high-valent ruthenium complexes.Broadening the catalyst and reaction scope of regio- and chemoselective C-H oxygenation: a convenient and scalable approach to 2-acylphenols by intriguing Rh(II) and Ru(II) catalysis.Silver ion promoted, Pd(II)-catalyzed arylation of arenes with a free amine as directing group in aqueous medium.Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine.Rhodium-catalyzed oxidative coupling through C-H activation and annulation directed by phosphonamide and phosphinamide groups.Pd-Catalyzed C-H Alkylation of Arenes Using PyrDipSi, a Transformable and Removable Silicon-Tethered Directing Group.Silicon-Tethered Strategies for C-H Functionalization Reactions.Nitroarenes as the Nitrogen Source in Intermolecular Palladium-Catalyzed Aryl C-H Bond Aminocarbonylation Reactions.Enantioselective Synthesis of β-Fluoro Amines via β-Amino α-Fluoro Nitroalkanes and a Traceless Activating Group Strategy.Silylations of Arenes with Hydrosilanes: From Transition-Metal-Catalyzed C¢X Bond Cleavage to Environmentally Benign Transition-Metal-Free C¢H Bond Activation.2-Pyridylmethyl ether: a readily removable and efficient directing group for amino acid ligand accelerated ortho-C-H olefination of phenols.Rhodium(iii)-catalyzed and MeOH-involved regioselective mono-alkenylation of N-arylureas with acrylates.Palladium-catalyzed C-H bond functionalization of C6-arylpurines.Palladium-Catalyzed Directed para C-H Functionalization of Phenols.Palladium-catalyzed direct C-H arylation of 3-aryl-2H-benzo[1,2,4]thiadiazine 1,1-dioxides: an efficient strategy to the synthesis of benzothiadiazine-1,1-dioxide derivatives.C-H functionalization directed by transformable nitrogen heterocycles: synthesis of ortho-oxygenated arylnaphthalenes from arylphthalazines.Ni-catalysed regioselective 1,2-diarylation of unactivated olefins by stabilizing Heck intermediates as pyridylsilyl-coordinated transient metallacycles.Towards Uniform Iodine Catalysis: Intramolecular C-H Amination of Arenes under Visible Light.Ruthenium-Catalyzed Monoalkenylation of Aromatic Ketones by Cleavage of Carbon-Heteroatom Bonds with Unconventional Chemoselectivity.Palladium-catalyzed ortho-functionalization of azoarenes with aryl acylperoxides.RhIII-Catalyzed site-selective amidation with nitrone as a traceless directing group: an approach to functionalized arylaldehydes.Carboxylic Acids as Traceless Directing Groups for Formal meta-Selective Direct ArylationA New Direction in CH Alkenylation: Silanol as a Helping Hand
P2860
Q35166668-85C98A48-0E78-41DB-BE68-F91D6D531233Q35648469-C7713351-9F61-4D36-B505-DAC6CD8A1106Q36021897-40E99FF7-25E7-4D93-ABFC-8742E14E02A5Q36047548-A5A91F70-980A-4840-BA4E-E991A2646751Q36452868-696146F9-D71F-4D3E-BDF9-A759866D4A9FQ37374955-399B2132-F354-4AB4-82BC-E73884311FEDQ37400739-70E6B7B8-BABA-499B-9325-8A68279A6855Q37848783-AA6CCFE5-7B06-4619-B358-C5CD4AB3C2BEQ38225214-AE9FF4C0-D6D0-4B1A-B442-A4DAC8948E2EQ38351637-A401C0F9-B625-42B0-AC46-F397AC542B3CQ38923098-86A2E024-8474-4A19-9AAB-396C059A750DQ41819937-39C7DC85-2037-4630-B112-781D8C7A5A76Q41844226-658959C4-3B02-4682-982E-DB2BC07190D7Q41966616-48B3E756-D9D5-4702-8D42-86CC13C92B50Q42094195-2FDA2CD9-386B-463A-AA0F-3BF546BBE1B2Q43796728-B854A2ED-DC26-41B4-A22B-8D69E9C7122AQ43923336-C6A67BF5-C8D3-40DF-9F1C-F1DDA27460C0Q45968419-6B7FED6F-3CA0-4378-86C6-E54E2F927E27Q46026417-F55E5719-C69E-4354-837D-A5355F74D53AQ46195268-CA0A9D97-CA9B-4A52-ADD2-613132439B5CQ46439792-CFF7680D-9595-4BFE-BA19-9A8BE29063CBQ46522333-BB73BFA1-18A8-4CD6-AFF1-FFF71CCF28D1Q48210165-CE439E8F-F93E-4FF0-B77B-E06AF35986BFQ48299900-2612CF85-23B6-4FEF-95AE-59465BF45815Q48330716-DF96DD1E-C801-43E8-9DBB-4827326F2151Q48974117-004A2A49-3CDD-4369-8FF6-02DFCBE9EF2AQ50267622-1C7C66D9-41F1-498F-83D6-0A891BB2AC9CQ50488022-88A74DEF-8D14-45D8-A43F-93CE83C25318Q50504068-8C80EE3F-7F1C-4155-8784-5FB0A093C437Q50523172-C0B0DEDE-9C3E-43CA-BD4E-728279C5D539Q50854910-E740741B-EC4C-4AE5-8858-97C96480864AQ50893587-467E7EE9-7237-4E52-8ACA-CCEC0E373C7CQ51770104-9166A11C-8D21-4F6E-94D8-9E9BA6DD5F87Q52599538-83FF347D-CA53-4B35-8F91-4598C4E6C111Q52870599-378C8CE6-1FA7-4C05-A65B-BE280027B9C5Q52933558-9E2D2AE7-712F-4A05-9EAB-EE8F304FAAA6Q53514063-160849DF-81D2-40E4-BFF3-0C8C06DD444AQ53707640-A3AB20E4-2D3C-4B75-9A0B-0AB6B9EB6A46Q58347063-C7191693-2269-432E-8EEA-F9884CB43322Q59203437-127705C1-000E-4E0E-AB52-9D99AF5BD884
P2860
PyDipSi: a general and easily modifiable/traceless Si-tethered directing group for C-H acyloxylation of arenes.
description
2010 nî lūn-bûn
@nan
2010 թուականի Յունիսին հրատարակուած գիտական յօդուած
@hyw
2010 թվականի հունիսին հրատարակված գիտական հոդված
@hy
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
name
PyDipSi: a general and easily ...... r C-H acyloxylation of arenes.
@ast
PyDipSi: a general and easily ...... r C-H acyloxylation of arenes.
@en
type
label
PyDipSi: a general and easily ...... r C-H acyloxylation of arenes.
@ast
PyDipSi: a general and easily ...... r C-H acyloxylation of arenes.
@en
prefLabel
PyDipSi: a general and easily ...... r C-H acyloxylation of arenes.
@ast
PyDipSi: a general and easily ...... r C-H acyloxylation of arenes.
@en
P2093
P2860
P356
P1476
PyDipSi: a general and easily ...... r C-H acyloxylation of arenes.
@en
P2093
Alexander S Dudnik
Chunhui Huang
Natalia Chernyak
Vladimir Gevorgyan
P2860
P304
P356
10.1021/JA1033167
P407
P577
2010-06-01T00:00:00Z