A general strategy toward aromatic 1,2-ambiphilic synthons: palladium-catalyzed ortho-halogenation of PyDipSi-arenes
about
Silanol: a traceless directing group for Pd-catalyzed o-alkenylation of phenols.Double-fold C-H oxygenation of arenes using PyrDipSi: a general and efficient traceless/modifiable silicon-tethered directing group.General method for the synthesis of salicylic acids from phenols through palladium-catalyzed silanol-directed C-H carboxylationMonoprotected l-Amino Acid (l-MPAA), Accelerated Bromination, Chlorination, and Iodination of C(sp2 )-H Bonds by Iridium(III) Catalysis.Pd-catalyzed modifiable silanol-directed aromatic C-H oxygenationPd(II)-catalyzed C-H iodination using molecular I2 as the sole oxidant.The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes.Simple, Efficient and Controllable Synthesis of Iodo/Di-iodoarenes via Ipsoiododecarboxylation/Consecutive Iodination Strategy.Arene C-H functionalisation using a removable/modifiable or a traceless directing group strategy.Twofold unsymmetrical C-H functionalization of PyrDipSi-substituted arenes: a general method for the synthesis of substituted meta-halophenols.Meta-selective C-H functionalization using a nitrile-based directing group and cleavable Si-tether.Ruthenium-Catalyzed meta-Selective C-H BrominationTransition-Metal-Free Decarboxylative Iodination: New Routes for Decarboxylative Oxidative Cross-Couplings.Pd-Catalyzed C-H Alkylation of Arenes Using PyrDipSi, a Transformable and Removable Silicon-Tethered Directing Group.Silicon-Tethered Strategies for C-H Functionalization Reactions.Elements of regiocontrol in the direct heteroarylation of indoles/pyrroles: synthesis of bi- and fused polycyclic heteroarenes by twofold or tandem fourfold C-H activation.2-Pyridylmethyl ether: a readily removable and efficient directing group for amino acid ligand accelerated ortho-C-H olefination of phenols.Copper(II)-catalyzed C5 and C7 halogenation of quinolines using sodium halides under mild conditions.Cu-mediated direct regioselective C-2 chlorination of indoles.Towards Uniform Iodine Catalysis: Intramolecular C-H Amination of Arenes under Visible Light.Arylation with Diaryliodonium Salts.Carboxylic Acids as Traceless Directing Groups for Formal meta-Selective Direct ArylationA New Direction in CH Alkenylation: Silanol as a Helping Hand
P2860
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P2860
A general strategy toward aromatic 1,2-ambiphilic synthons: palladium-catalyzed ortho-halogenation of PyDipSi-arenes
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
A general strategy toward arom ...... halogenation of PyDipSi-arenes
@en
type
label
A general strategy toward arom ...... halogenation of PyDipSi-arenes
@en
prefLabel
A general strategy toward arom ...... halogenation of PyDipSi-arenes
@en
P2093
P2860
P356
P1476
A general strategy toward arom ...... halogenation of PyDipSi-arenes
@en
P2093
Alexander S Dudnik
Chunhui Huang
Natalia Chernyak
Vladimir Gevorgyan
P2860
P304
P356
10.1002/ANIE.201004426
P407
P577
2010-11-01T00:00:00Z