The discovery of novel reactivity in the development of C-C bond-forming reactions: in situ generation of zinc acetylides with Zn(II)/R(3)N.
about
Asymmetric functional organozinc additions to aldehydes catalyzed by 1,1'-bi-2-naphthols (BINOLs).A facile asymmetric approach to the multicyclic core structure of mangicol A.Highly enantioselective alkyne additions to aldehydes in the presence of 1,1'-bi-2-naphthol and hexamethylphosphoramide.1,1'-Binaphthyl Ligands with Bulky 3,3'-Tertiaryalkyl Substituents for the Asymmetric Alkyne Addition to Aromatic Aldehydes.In Situ Generated Zinc(II) Catalyst for Incorporation of CO2 into 2-Oxazolidinones with Propargylic Amines at Atmospheric Pressure.A. M. Zaitsev: lasting contributions of a synthetic virtuoso a century after his death.ProPhenol-catalyzed asymmetric additions by spontaneously assembled dinuclear main group metal complexes.Transition-metal-catalyzed synthesis of aspergillide B: an alkyne addition strategy.Direct addition of alkynes to imines and related C=N electrophiles: A convenient access to propargylamines.Palladium(0)-catalyzed synthesis of chiral ene-allenes using alkenyl trifluoroborates.Synthesis of naphthalenes and 2-naphthols by the electrophilic cyclization of alkynes.The Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups.Development of Zn-ProPhenol-catalyzed asymmetric alkyne addition: synthesis of chiral propargylic alcohols.Cu(I)-catalyzed direct addition and asymmetric addition of terminal alkynes to imines.Infrared spectroscopic investigations on the metallation of terminal alkynes by Zn(OTf)2.Chemoselectivity and the curious reactivity preferences of functional groups.Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.Chiral alkynylcarbinols from marine sponges: asymmetric synthesis and biological relevance.Identification of chiral alkenyl- and alkynylcarbinols as pharmacophores for potent cytotoxicity.Enantiospecific Alkynylation of Alkylboronic Esters.Construction of 1,5-enynes by stereospecific Pd-catalyzed allyl-propargyl cross-couplings.Gold-catalyzed one-step practical synthesis of oxetan-3-ones from readily available propargylic alcohols.Identification of an Unexpected 2-Oxonia[3,3]sigmatropic Rearrangement/Aldol Pathway in the Formation of Oxacyclic Rings. Total Synthesis of (+)-Aspergillin PZ.A versatile synthetic platform based on strained propargyl amines.Rh-catalyzed direct enantioselective alkynylation of α-ketiminoesters.Mechanistic study on the cleavage and reorganization of C(sp3)-H and C=N bonds in carbodiimides: synthesis of 1,2-dihydrothiopyrimidines and 2,3-dihydropyrimidinthiones through four-component coupling.Total synthesis, stereochemical assignment, and biological activity of chamuvarinin and structural analogues.Dinuclear zinc complex catalyzed asymmetric methylation and alkynylation of aromatic aldehydes.Preparation of Solid Polyfunctional Alkynylzinc Pivalates with Enhanced Air and Moisture Stability for Organic Synthesis.Direct Zinc(II)-Catalyzed Enantioconvergent Additions of Terminal Alkynes to α-Keto Esters.Copper/Guanidine-Catalyzed Asymmetric Alkynylation of Isatins.A Lewis acid activated reaction of Zn with EtI to promote highly enantioselective alkyne additions to aldehydes.Strong Lewis acid air-stable cationic titanocene perfluoroalkyl(aryl)sulfonate complexes as highly efficient and recyclable catalysts for C-C bond forming reactions.A quick access to the spirotricyclic core analogue of mangicol A by a Rh(I)-catalyzed tandem Pauson-Khand/[4+2] cycloaddition.One-pot zinc-promoted asymmetric alkynylation/brook-type rearrangement/ene-allene cyclization: highly selective formation of three new bonds and two stereocenters in acyclic systems.Ligand accelerated indium(iii)-catalyzed asymmetric alkynylation of aldehydes with 2-methyl-3-butyn-2-ol as an ethyne equivalent donor
P2860
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P2860
The discovery of novel reactivity in the development of C-C bond-forming reactions: in situ generation of zinc acetylides with Zn(II)/R(3)N.
description
2000 nî lūn-bûn
@nan
2000 թուականի Յունիսին հրատարակուած գիտական յօդուած
@hyw
2000 թվականի հունիսին հրատարակված գիտական հոդված
@hy
2000年の論文
@ja
2000年論文
@yue
2000年論文
@zh-hant
2000年論文
@zh-hk
2000年論文
@zh-mo
2000年論文
@zh-tw
2000年论文
@wuu
name
The discovery of novel reactiv ...... acetylides with Zn(II)/R(3)N.
@ast
The discovery of novel reactiv ...... acetylides with Zn(II)/R(3)N.
@en
type
label
The discovery of novel reactiv ...... acetylides with Zn(II)/R(3)N.
@ast
The discovery of novel reactiv ...... acetylides with Zn(II)/R(3)N.
@en
prefLabel
The discovery of novel reactiv ...... acetylides with Zn(II)/R(3)N.
@ast
The discovery of novel reactiv ...... acetylides with Zn(II)/R(3)N.
@en
P2093
P356
P1476
The discovery of novel reactiv ...... acetylides with Zn(II)/R(3)N.
@en
P2093
Carreira EM
Tomooka CS
P304
P356
10.1021/AR990078O
P407
P577
2000-06-01T00:00:00Z