Gold-catalyzed one-step practical synthesis of oxetan-3-ones from readily available propargylic alcohols.
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Recent advances in the gold-catalyzed additions to C-C multiple bonds.Experimental and computational evidence for gold vinylidenes: generation from terminal alkynes via a bifurcation pathway and facile C-H insertionsMechanism of gold(I)-catalyzed rearrangements of acetylenic amine-N-oxides: computational investigations lead to a new mechanism confirmed by experiment.Meeting the challenge of intermolecular gold(I)-catalyzed cycloadditions of alkynes and allenes[3,3]-Sigmatropic rearrangement versus carbene formation in gold-catalyzed transformations of alkynyl aryl sulfoxides: mechanistic studies and expanded reaction scopeRhodium(i)-catalyzed stereoselective [4+2] cycloaddition of oxetanols with alkynes through C(sp3)-C(sp3) bond cleavage.Gold α-oxo carbenoids in catalysis: catalytic oxygen-atom transfer to alkynes.Asymmetric synthesis of 2-substituted oxetan-3-ones via metalated SAMP/RAMP hydrazones.A flexible and stereoselective synthesis of azetidin-3-ones through gold-catalyzed intermolecular oxidation of alkynes.A non-diazo approach to α-oxo gold carbenes via gold-catalyzed alkyne oxidation.Gold-Catalyzed Oxidation/C-H Functionalization of Ynones: Efficient and Rapid Access to Functionalized Polycyclic Salicyl Ketones.New Approaches to the Synthesis of Metal Carbenes.Single-step microwave-mediated synthesis of oxazoles and thiazoles from 3-oxetanone: a synthetic and computational study.Gold-catalyzed Intermolecular Oxidations of 2-Ketonyl-1-ethynyl Benzenes with N-Hydoxyanilines to Yield 2-Aminoindenones via Gold Carbene Intermediates.Gold Catalysed Redox Synthesis of Imidazo[1,2-a]pyridine using Pyridine N-Oxide and Alkynes.Tempering the reactivities of postulated α-oxo gold carbenes using bidentate ligands: implication of tricoordinated gold intermediates and the development of an expedient bimolecular assembly of 2,4-disubstituted oxazolesOptimizing P,N-bidentate ligands for oxidative gold catalysis: efficient intermolecular trapping of α-oxo gold carbenes by carboxylic acids.Gold-catalyzed regioselective oxidation of propargylic carboxylates: a reliable access to α-carboxy-α,β-unsaturated ketones/aldehydes.Generation of rhodium(I) carbenes from ynamides and their reactions with alkynes and alkenesGold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.A Non-Diazo Strategy to Cyclopropanation via Oxidatively Generated Gold Carbene: the Benefit of A Conformationally Rigid P,N-Bidentate Ligand.Gold-Catalyzed Oxidation of Propargylic Ethers with Internal C-C Triple Bonds: Impressive Regioselectivity Enabled by Inductive Effect.Gold-catalyzed highly regioselective oxidation of C-C triple bonds without acid additives: propargyl moieties as masked α,β-unsaturated carbonyls.Rapid access to chroman-3-ones through gold-catalyzed oxidation of propargyl aryl ethers.Expanding the horizon of intermolecular trapping of in situ generated α-oxo gold carbenes: efficient oxidative union of allylic sulfides and terminal alkynes via C-C bond formationUmpolung reactivity of indole through gold catalysis.Gold-catalyzed nitrene transfer to activated alkynes: formation of α,β-unsaturated amidines.Gold-catalyzed regioselective oxidation of terminal allenes: formation of α-methanesulfonyloxy methyl ketones.Enantioselective oxidative gold catalysis enabled by a designed chiral P,N-bidentate ligand.Gold-catalyzed rearrangement of allylic oxonium ylides: efficient synthesis of highly functionalized dihydrofuran-3-ones.Gold-catalyzed oxidative cyclizations on 1,4-enynes: evidence for a γ-substituent effect on Wagner-Meerwein rearrangements.Rhodium-catalyzed oxygenative addition to terminal alkynes for the synthesis of esters, amides, and carboxylic acids.Gold-catalyzed oxidative cycloadditions to activate a quinoline framework.Catalytic enantioselective intermolecular desymmetrization of 3-substituted oxetanes.Gold-catalyzed formal cycloaddition of 2-ethynylbenzyl ethers with organic oxides and α-diazoesters.Biarylphosphonite gold(I) complexes as superior catalysts for oxidative cyclization of propynyl arenes into indan-2-ones.Mechanistic intricacies of gold-catalyzed intermolecular cycloadditions between allenamides and dienes.Cascade hydroamination/redox reaction for the synthesis of cyclic aminals catalyzed by a combined gold complex and Brønsted acid.Gold-catalyzed oxidative rearrangement involving 1,2-acyl migration: efficient synthesis of functionalized dihydro-γ-carbolines from α-(2-indolyl) propargylic alcohols and imines.A Direct Synthesis of Highly Substituted π-Rich Aromatic Heterocycles from Oxetanes.
P2860
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P2860
Gold-catalyzed one-step practical synthesis of oxetan-3-ones from readily available propargylic alcohols.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Gold-catalyzed one-step practi ...... vailable propargylic alcohols.
@en
Gold-catalyzed one-step practi ...... vailable propargylic alcohols.
@nl
type
label
Gold-catalyzed one-step practi ...... vailable propargylic alcohols.
@en
Gold-catalyzed one-step practi ...... vailable propargylic alcohols.
@nl
prefLabel
Gold-catalyzed one-step practi ...... vailable propargylic alcohols.
@en
Gold-catalyzed one-step practi ...... vailable propargylic alcohols.
@nl
P2860
P356
P1476
Gold-catalyzed one-step practi ...... available propargylic alcohols
@en
P2093
P2860
P304
P356
10.1021/JA1033952
P407
P50
P577
2010-06-01T00:00:00Z