Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
about
Nickel/bis(oxazoline)-catalyzed asymmetric Kumada reactions of alkyl electrophiles: cross-couplings of racemic alpha-bromoketonesRapid heteroatom transfer to arylmetals utilizing multifunctional reagent scaffolds.Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides"Black Swan events" in organic synthesis.Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions.Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partnersAn improved palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.One-pot decarboxylative acylation of N-, O-, S-nucleophiles and peptides with 2,2-disubstituted malonic acids.Total synthesis of clostrubin.Practical carbon-carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation.Linchpin synthons: metalation of aryl bromides bearing a potassium trifluoroborate moiety.The Pennsylvania Green Fluorophore: a hybrid of Oregon Green and Tokyo Green for the construction of hydrophobic and pH-insensitive molecular probes.Palladium-catalyzed reactions of arylindium reagents prepared directly from aryl iodides and indium metalMetalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1.Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process.Stille coupling via C-N bond cleavage.Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.Practical catalytic asymmetric synthesis of diaryl-, aryl heteroaryl-, and diheteroarylmethanols.Synthesis of the spiroiminal moiety and approaches to the synthesis of marineosins A and B.Simple, Efficient and Controllable Synthesis of Iodo/Di-iodoarenes via Ipsoiododecarboxylation/Consecutive Iodination Strategy.Regio- and chemoselective metalation of arenes and heteroarenes using hindered metal amide bases.Functionalization of heterocyclic compounds using polyfunctional magnesium and zinc reagents.The chemistry of the polycyclic polyprenylated acylphloroglucinols.Metal-catalyzed activation of ethers via C-O bond cleavage: a new strategy for molecular diversity.Asymmetric conjugate additions and allylic alkylations using nucleophiles generated by hydro- or carbometallation.Progress and developments in the turbo Grignard reagent i-PrMgCl·LiCl: a ten-year journey.Bromine-lithium exchange: An efficient tool in the modular construction of biaryl ligands.Palladium-catalyzed intramolecular reductive olefin hydrocarbonation: benzylic hydrogen serving as a new hydrogen donor.Shuttle Catalysis-New Strategies in Organic Synthesis.Transition-Metal-Catalyzed Electrophilic Amination: Application of O-Benzoylhydroxylamines in the Construction of the C-N Bond.Total syntheses of isonaamine C and isonaamidine EEfficient and Scalable Synthesis of 4-Carboxy-Pennsylvania Green Methyl Ester: A Hydrophobic Building Block for Fluorescent Molecular ProbesSynthetic Efforts Toward [3.3.1] Bridged Bicyclic Phloroglucinol Natural Products.Perylenequinone natural products: total syntheses of the diastereomers (+)-phleichrome and (+)-calphostin D by assembly of centrochiral and axial chiral fragments.Concise and Practical Asymmetric Synthesis of a Challenging Atropisomeric HIV Integrase Inhibitor.Bromination of hydrocarbons with CBr4, initiated by light-emitting diode irradiation.Total Syntheses of Naamidine G and 14-Methoxynaamidine G.Ring opening of pymisyl-protected aziridines with organocuprates.Transition-metal-free synthesis of conjugated polymers from bis-Grignard reagents by using TEMPO as oxidant.A convenient synthesis of benzonitriles via electrophilic cyanation with N-cyanobenzimidazole.
P2860
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P2860
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
description
2003 nî lūn-bûn
@nan
2003 թուականի Սեպտեմբերին հրատարակուած գիտական յօդուած
@hyw
2003 թվականի սեպտեմբերին հրատարակված գիտական հոդված
@hy
2003年の論文
@ja
2003年論文
@yue
2003年論文
@zh-hant
2003年論文
@zh-hk
2003年論文
@zh-mo
2003年論文
@zh-tw
2003年论文
@wuu
name
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
@ast
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
@en
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
@nl
type
label
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
@ast
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
@en
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
@nl
prefLabel
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
@ast
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
@en
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
@nl
P2093
P2860
P356
P1476
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.
@en
P2093
Felix Kopp
Florian F Kneisel
Ioannis Sapountzis
Nina Gommermann
Tobias Korn
Viet Anh Vu
Wolfgang Dohle
P2860
P304
P356
10.1002/ANIE.200300579
P407
P50
P577
2003-09-01T00:00:00Z