Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1. - Wikidata - wikimedia - TriplyDB

Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1.

Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1.

http://www.wikidata.org/entity/Q37004257

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Metalated nitriles: SNi' cyclizations with a propargylic electrophile Metalated nitriles: S(N)i and S(N)i' installation of contiguous quaternary-tertiary and quaternary-quaternary centers.Cyclic Metalated Nitriles: Stereoselective Cyclizations to cis- and trans-Hydrindanes, Decalins, and Bicyclo[4.3.0]undecanes.Highly enantioselective metallation-substitution alpha to a chiral nitrile Substrate-controlled asymmetric total synthesis and structure revision of (+)-itomanallene A.Enantiodivergent deprotonation/acylation of α-amino nitriles.Base-dependent stereodivergent intramolecular aza-Michael reaction: asymmetric synthesis of 1,3-disubstituted isoindolines.

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Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1.

http://www.wikidata.org/entity/Q37004257

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article científic

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article scientifique

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articolo scientifico

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artigo científico

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bilimsel makale

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scientific article published on August 2008

@en

vedecký článok

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vetenskaplig artikel

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videnskabelig artikel

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vědecký článek

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name

Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1.

@en

Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1.

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type

label

Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1.

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Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1.

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prefLabel

Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1.

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Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1.

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J.TET.2008.05.110

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Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1

@en

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Wang Liu

http://www.w3.org/2001/XMLSchema#string

Yunjing Wei

http://www.w3.org/2001/XMLSchema#string

Zhiyu Zhang

http://www.w3.org/2001/XMLSchema#string

P2860

Sulfinimine-mediated asymmetric synthesis of 1,3-disubstituted tetrahydroisoquinolines: a stereoselective synthesis of cis- and trans-6,8-dimethoxy-1,3-dimethyl-1,2,3,4-tetrahydroisoquinoline.

Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.

Metalated nitriles: cation-controlled cyclizations

Total synthesis of the CP-molecules (CP-263,114 and CP-225,917, phomoidrides B and A). 2. Model studies for the construction of key structural elements and first-generation strategy.

C-metalated nitriles: electrophile-dependent alkylations and acylations.

Asymmetric synthesis of the protoberberine alkaloid (S)-(-)-xylopinine using enantiopure sulfinimines.

Nitrile anions: solvent-dependent cyclizations.

Mechanism of the interconversions between C- and N-bound transition metal alpha-cyanocarbanions.

Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles.

Configurational stability of chiral lithiated cyclopropylnitriles: a density functional study.

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7477-7488

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scholarly article

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10.1016/J.TET.2008.05.110

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26719542

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19657380

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2597827

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