Modern aldol methods for the total synthesis of polyketides.
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Lithium Enolates Derived from Pyroglutaminol: Mechanism and Stereoselectivity of an Azaaldol AdditionMethod of continuous variation: characterization of alkali metal enolates using ¹H and ¹⁹F NMR spectroscopies.A new class of ligands for aqueous, lanthanide-catalyzed, enantioselective Mukaiyama aldol reactionsTotal synthesis of (+)-roxaticin via C-C bond forming transfer hydrogenation: a departure from stoichiometric chiral reagents, auxiliaries, and premetalated nucleophiles in polyketide construction.Direct β-functionalization of cyclic ketones with aryl ketones via the merger of photoredox and organocatalysis.Highly stereoselective synthesis of anti,anti-dipropionate stereotriads: a solution to the long-standing problem of challenging mismatched double asymmetric crotylboration reactionsAdvances in the synthesis of glycosidic macrolides: clavosolides A-D and cyanolide A.Convergent synthesis of deoxypropionates.Solid-State and Solution Structures of Glycinimine-Derived Lithium Enolates.Directed evolution of aldolases for exploitation in synthetic organic chemistryMutasynthesis, chemobiosynthesis, and back to semi-synthesis: combining synthetic chemistry and biosynthetic engineering for diversifying natural products.Solution structures of lithium enolates, phenolates, carboxylates, and alkoxides in the presence of N,N,N',N'-tetramethylethylenediamine: a prevalence of cyclic dimers.Lithium enolates of simple ketones: structure determination using the method of continuous variationStructure determination using the method of continuous variation: lithium phenolates solvated by protic and dipolar aprotic ligandsStructures of beta-amino ester enolates: new strategies using the method of continuous variation.Enediolate-dilithium amide mixed aggregates in the enantioselective alkylation of arylacetic acids: structural studies and a stereochemical model.Polyol synthesis with beta-oxyanionic alkyllithium reagents: syntheses of aculeatins A, B, and D.Lithium phenolates solvated by tetrahydrofuran and 1,2-dimethoxyethane: structure determination using the method of continuous variationLithium Enolates Derived from Weinreb Amides: Insights into Five-Membered Chelate RingsThe thiopyran route to polypropionatesRecent developments in the field of oxa-Michael reactions.Developing novel organocatalyzed aldol reactions for the enantioselective synthesis of biologically active molecules.The impact of the Mukaiyama aldol reaction in total synthesis.Catalytic enantioselective decarboxylative reactions using organocatalysts.Sequential catalysis for stereoselective synthesis of complex polyketides.Total syntheses of natural products containing spirocarbocycles.Total syntheses of the archazolids: an emerging class of novel anticancer drugs.Transition metal catalysis-a unique road map in the stereoselective synthesis of 1,3-polyols.A mild, diastereoselective construction of cyclic and spirocyclic ketals employing a tandem photoisomerization/cyclization tactic.Boron enolate chemistry toward the syntheses of polyketide stereotetrads.Total synthesis of 6-deoxyerythronolide B via C-C bond-forming transfer hydrogenationCrystal structure of (-)-(S)-4-[(2S,3S,4S,Z)-3-hydroxy-4-methyl-hept-5-en-2-yl]-1,3-dioxolan-2-oneDiastereoselective Ni-catalyzed 1,4-hydroboration of chiral dienols.Enantioselective, organocatalytic oxy-michael addition to gamma/delta-hydroxy-alpha,beta-enones: boronate-amine complexes as chiral hydroxide synthons.Asymmetric Synthesis of Dipropionate Derivatives through Catalytic Hydrogenation of Enantioenriched E-Ketene Heterodimers.Practical asymmetric synthesis of β-hydroxy γ-amino acids via complimentary aldol reactions.Substrate structure-activity relationships guide rational engineering of modular polyketide synthase ketoreductases.An Effective Bifunctional Aldehyde Linchpin for Type II Anion Relay Chemistry: Development and Application to the Synthesis of a C16-C29 Fragment of Rhizopodin.Ugi/aldol sequence: expeditious entry to several families of densely substituted nitrogen heterocycles.Organocatalytic, enantioselective synthesis of benzoxaboroles via Wittig/oxa-Michael reaction Cascade of α-formyl boronic acids.
P2860
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P2860
Modern aldol methods for the total synthesis of polyketides.
description
2006 nî lūn-bûn
@nan
2006 թուականի Նոյեմբերին հրատարակուած գիտական յօդուած
@hyw
2006 թվականի նոյեմբերին հրատարակված գիտական հոդված
@hy
2006年の論文
@ja
2006年論文
@yue
2006年論文
@zh-hant
2006年論文
@zh-hk
2006年論文
@zh-mo
2006年論文
@zh-tw
2006年论文
@wuu
name
Modern aldol methods for the total synthesis of polyketides.
@ast
Modern aldol methods for the total synthesis of polyketides.
@en
Modern aldol methods for the total synthesis of polyketides.
@nl
type
label
Modern aldol methods for the total synthesis of polyketides.
@ast
Modern aldol methods for the total synthesis of polyketides.
@en
Modern aldol methods for the total synthesis of polyketides.
@nl
prefLabel
Modern aldol methods for the total synthesis of polyketides.
@ast
Modern aldol methods for the total synthesis of polyketides.
@en
Modern aldol methods for the total synthesis of polyketides.
@nl
P356
P1476
Modern aldol methods for the total synthesis of polyketides.
@en
P2093
Bernd Schetter
Rainer Mahrwald
P304
P356
10.1002/ANIE.200602780
P407
P577
2006-11-01T00:00:00Z