Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis.
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Elaboration of copper-oxygen mediated C-H activation chemistry in consideration of future fuel and feedstock generationHydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel CellDesign and synthesis of a dinucleating ligand system with varying terminal donor functions that provides no bridging donor and its application to the synthesis of a series of Fe(III)-μ-O-Fe(III) complexes.Fast O2 binding at dicopper complexes containing Schiff-base dinucleating ligands.Observed enhancement of the reactivity of a biomimetic diiron complex by the addition of water - mechanistic insights from theoretical modelingHydroxo-bridged dicopper(II,III) and -(III,III) complexes: models for putative intermediates in oxidation catalysis.Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity.Rapid X-ray photoreduction of dimetal-oxygen cofactors in ribonucleotide reductase.Superoxo, mu-peroxo, and mu-oxo complexes from heme/O2 and heme-Cu/O2 reactivity: copper ligand influences in cytochrome c oxidase models.A single mutation in the castor Delta9-18:0-desaturase changes reaction partitioning from desaturation to oxidase chemistry.Dioxygen reactivity of new bispidine-copper complexes.Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water.Geometric and electronic structure of [{Cu(MeAN)}2(μ-η2:η2(O2(2-)))]2+ with an unusually long O-O bond: O-O bond weakening vs activation for reductive cleavage.Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation.Cu-ZSM-5: A biomimetic inorganic model for methane oxidationTriptycene-based Bis(benzimidazole) Carboxylate-Bridged Biomimetic Diiron(II) Complexes.X-ray absorption edge spectroscopy and computational studies on LCuO2 species: Superoxide-Cu(II) versus peroxide-Cu(III) bonding.Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group.Why did Nature choose manganese to make oxygen?Mononuclear Cu-O2 complexes: geometries, spectroscopic properties, electronic structures, and reactivitySpectroscopic definition of the biferrous and biferric sites in de novo designed four-helix bundle DFsc peptides: implications for O2 reactivity of binuclear non-heme iron enzymesLessons from nature: unraveling biological CH bond activationModeling the syn disposition of nitrogen donors in non-heme diiron enzymes. Synthesis, characterization, and hydrogen peroxide reactivity of diiron(III) complexes with the syn N-donor ligand H2BPG2DEV.Synthesis and Structures of Dimeric Iron(III)-Oxo and -Imido Complexes Containing Intramolecular Hydrogen Bonds.L-edge X-ray absorption spectroscopy and DFT calculations on Cu2O2 species: direct electrophilic aromatic attack by side-on peroxo bridged dicopper(II) complexes.O2 activation by binuclear Cu sites: noncoupled versus exchange coupled reaction mechanismsAccess to a Cu(II)-O-Cu(II) motif: spectroscopic properties, solution structure, and reactivity.Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters.Role of metal-oxo complexes in the cleavage of C-H bonds.Recent advances in heterogeneous selective oxidation catalysis for sustainable chemistry.Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes.Copper-Mediated Selective Hydroxylation of a Non-activated C-H Bond in Steroids: A DFT Study of Schönecker's Reaction.Vanadium-Catalyzed C(sp(3))-H Fluorination Reactions.Steric and electronic control over the reactivity of a thiolate-ligated Fe(II) complex with dioxygen and superoxide: reversible mu-oxo dimer formation.Isolation and characterization of a dihydroxo-bridged iron(III,III)(μ-OH)2 diamond core derived from dioxygen.Preparation and structures of dinuclear complexes containing M(II)-OH centers.Synthesis, structure, and physical properties for a series of monomeric iron(III) hydroxo complexes with varying hydrogen-bond networks.Heterobimetallic dioxygen activation: synthesis and reactivity of mixed Cu-Pd and Cu-Pt bis(mu-oxo) complexesAn unusual peroxo intermediate of the arylamine oxygenase of the chloramphenicol biosynthetic pathway.A Highly Selective Vanadium Catalyst for Benzylic C-H Oxidation.
P2860
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P2860
Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis.
description
2002 nî lūn-bûn
@nan
2002 թուականի Ապրիլին հրատարակուած գիտական յօդուած
@hyw
2002 թվականի ապրիլին հրատարակված գիտական հոդված
@hy
2002年の論文
@ja
2002年論文
@yue
2002年論文
@zh-hant
2002年論文
@zh-hk
2002年論文
@zh-mo
2002年論文
@zh-tw
2002年论文
@wuu
name
Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis.
@ast
Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis.
@en
type
label
Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis.
@ast
Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis.
@en
prefLabel
Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis.
@ast
Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis.
@en
P2860
P1433
P1476
Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis.
@en
P2093
Lawrence Que
William B Tolman
P2860
P304
P356
10.1002/1521-3773(20020402)41:7<1114::AID-ANIE1114>3.0.CO;2-6
P577
2002-04-01T00:00:00Z