A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site.
about
High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes.Triggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by Ru(II) photocatalysis.Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.π-Frontier molecular orbitals in S = 2 ferryl species and elucidation of their contributions to reactivity.Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity.Intramolecular gas-phase reactions of synthetic nonheme oxoiron(IV) ions: proximity and spin-state reactivity rulesHydrogen-bonding effects on the reactivity of [X-Fe(III)-O-Fe(IV)═O] (X = OH, F) complexes toward C-H bond cleavage.Electronic Structure of the Ferryl Intermediate in the α-Ketoglutarate Dependent Non-Heme Iron Halogenase SyrB2: Contributions to H Atom Abstraction ReactivityNovel Approaches for the Accumulation of Oxygenated Intermediates to Multi-Millimolar Concentrations.Dichotomous hydrogen atom transfer vs proton-coupled electron transfer during activation of X-H bonds (X = C, N, O) by nonheme iron-oxo complexes of variable basicityEnhanced electron-transfer reactivity of nonheme manganese(IV)-oxo complexes by binding scandium ions.Spectroscopic and theoretical investigation of a complex with an [O═Fe(IV)-O-Fe(IV)═O] core related to methane monooxygenase intermediate Q.Electronic structure analysis of the oxygen-activation mechanism by Fe(II)- and α-ketoglutarate (αKG)-dependent dioxygenases.Mono- and binuclear non-heme iron chemistry from a theoretical perspective.Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes.Molecular designs for controlling the local environments around metal ionsFunctional models of α-keto acid dependent nonheme iron oxygenases: synthesis and reactivity of biomimetic iron(II) benzoylformate complexes supported by a 2,9-dimethyl-1,10-phenanthroline ligand.Oxidation of ethane to ethanol by N2O in a metal-organic framework with coordinatively unsaturated iron(II) sites.Hydrocarbon oxidation catalyzed by self-folded metal-coordinated cavitands.Mononuclear Nonheme High-Spin (S=2) versus Intermediate-Spin (S=1) Iron(IV)-Oxo Complexes in Oxidation Reactions.Formation and High Reactivity of the anti-Dioxo Form of High-Spin μ-Oxodioxodiiron(IV) as the Active Species That Cleaves Strong C-H Bonds.Hydroxylation versus Halogenation of Aliphatic C-H Bonds by a Dioxygen-Derived Iron-Oxygen Oxidant: Functional Mimicking of Iron Halogenases.Structural modeling of iron halogenases: synthesis and reactivity of halide-iron(IV)-oxo compounds.Structural characterization of a non-heme iron active site in zeolites that hydroxylates methaneWhy metal–oxos react with dihydroanthracene and cyclohexadiene at comparable rates, despite having different C–H bond strengths. A computational studyHigh-Valent Iron-Oxo and -Nitrido Complexes: Bonding and ReactivityElectronic structure analysis of multistate reactivity in transition metal catalyzed reactions: the case of C–H bond activation by non-heme iron(iv)–oxo coresRoles of carboxylate donors in O–O bond scission of peroxodi-iron(iii) to high-spin oxodi-iron(iv) with a new carboxylate-containing dinucleating ligand
P2860
Q35067238-62601A44-7420-4016-A64B-D1AD72D0A254Q35102626-B43B3BA8-F226-4F19-9517-67D8DA3D4337Q35974119-DD61C168-813B-4322-A1E7-86E98A65C2EEQ36221936-AE55267B-D7A8-4B96-BEBB-987BE12C729AQ36448772-8B66B2B8-9EBB-4B0A-BBE9-3A2D6E80292AQ36452377-48CE6B5D-5BD8-4D09-8731-387805D40A7EQ36784234-82D4E6A4-C480-4DCC-9A2E-72D2A0505CC1Q37052683-A032DA89-F58D-47C7-9E11-D47E68D3A41DQ37407850-871FD58A-EE4F-4EF2-956B-05E2C7B1FF28Q37421907-A2A67596-7A84-4AE8-B2B1-1BD2B32DBED2Q37603304-8414418E-1EA1-4334-ACDA-19B32329D3C7Q37614806-E3E04783-DF00-43B6-ACA7-2FF73838AD11Q38287167-2ED24962-0D3B-48B7-B47B-41851C32C040Q38845297-3C44697A-4BE5-4632-8795-909DC34F96FEQ38867180-38FDEB1D-89AF-4D01-B6B1-DEC230C14D54Q42373410-D3BC3CF6-3E9F-42C1-A66F-A0CD12887BD5Q44177189-3F384B84-6DE9-4ADB-9FCD-37FA92C79344Q46159368-921BD7A6-5445-4533-A86E-3912BBF3207CQ46357103-4EA88929-D1C0-47E1-8211-43E45C873E08Q46536088-EA9D7786-E7D4-4D0D-AEF0-EE85C8A2734AQ46580925-6BCFA272-C821-4730-A67F-23DCB5875028Q46603384-6AC2569D-227F-4BA5-B65F-1ADCB30851B1Q46856356-F2C165A4-29A9-48AA-9A49-6B5E04F832A1Q56863636-69FA964C-D8F2-406C-ABC1-DC802FB41DB1Q57250379-1D43F439-A8C6-4081-91D1-BAE6CADE65C2Q58009426-1FD4D0A0-C2A9-48A7-9483-608019A376C4Q58009640-34DB6409-AE72-4C7F-BA4F-38601F1BD9E0Q58227373-E5651033-2952-4C66-8114-137E918C8D54
P2860
A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site.
description
2011 nî lūn-bûn
@nan
2011 թուականի Յուլիսին հրատարակուած գիտական յօդուած
@hyw
2011 թվականի հուլիսին հրատարակված գիտական հոդված
@hy
2011年の論文
@ja
2011年論文
@yue
2011年論文
@zh-hant
2011年論文
@zh-hk
2011年論文
@zh-mo
2011年論文
@zh-tw
2011年论文
@wuu
name
A more reactive trigonal-bipyr ...... omplex with a cis-labile site.
@ast
A more reactive trigonal-bipyr ...... omplex with a cis-labile site.
@en
type
label
A more reactive trigonal-bipyr ...... omplex with a cis-labile site.
@ast
A more reactive trigonal-bipyr ...... omplex with a cis-labile site.
@en
prefLabel
A more reactive trigonal-bipyr ...... omplex with a cis-labile site.
@ast
A more reactive trigonal-bipyr ...... omplex with a cis-labile site.
@en
P2093
P2860
P356
P1476
A more reactive trigonal-bipyr ...... omplex with a cis-labile site.
@en
P2093
Eckard Münck
Emile L Bominaar
Gregory T Rohde
Jason England
Katherine M Van Heuvelen
Lawrence Que
P2860
P304
11880-11883
P356
10.1021/JA2040909
P407
P577
2011-07-19T00:00:00Z