The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathway
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Intramolecular C-H and C-F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron ComplexesExcited state potential energy surfaces and their interactions in Fe(IV)=O active sitesNonheme oxo-iron(IV) intermediates form an oxyl radical upon approaching the C-H bond activation transition state.Characterization of a tricationic trigonal bipyramidal iron(IV) cyanide complex, with a very high reduction potential, and its iron(II) and iron(III) congeners.Nuclear resonance vibrational spectroscopy on the Fe(IV)=O S=2 non-heme site in TMG3tren: experimentally calibrated insights into reactivity.Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes.A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site.Substrate-triggered activation of a synthetic [Fe2(μ-O)2] diamond core for C-H bond cleavage.Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.π-Frontier molecular orbitals in S = 2 ferryl species and elucidation of their contributions to reactivity.Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity.Intramolecular gas-phase reactions of synthetic nonheme oxoiron(IV) ions: proximity and spin-state reactivity rulesA Mononuclear Carboxylate-Rich Oxoiron(IV) Complex: a Structural and Functional Mimic of TauD Intermediate 'J'Electronic Structure of the Ferryl Intermediate in the α-Ketoglutarate Dependent Non-Heme Iron Halogenase SyrB2: Contributions to H Atom Abstraction ReactivityNovel Approaches for the Accumulation of Oxygenated Intermediates to Multi-Millimolar Concentrations.Geometric and electronic structure contributions to function in non-heme iron enzymes.Spectroscopic and theoretical investigation of a complex with an [O═Fe(IV)-O-Fe(IV)═O] core related to methane monooxygenase intermediate Q.An Ultra-Stable Oxoiron(IV) Complex and Its Blue Conjugate Base.Electronic structure analysis of the oxygen-activation mechanism by Fe(II)- and α-ketoglutarate (αKG)-dependent dioxygenases.Mono- and binuclear non-heme iron chemistry from a theoretical perspective.Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants.Aromatic C-F Hydroxylation by Nonheme Iron(IV)-Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations.Structural and Spectroscopic Characterization of a High-Spin {FeNO}(6) Complex with an Iron(IV)-NO(-) Electronic Structure.Prediction of high-valent iron K-edge absorption spectra by time-dependent density functional theory.Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization.M≡E and M=E Complexes of Iron and Cobalt that Emphasize Three-fold Symmetry (E = O, N, NR).Molecular designs for controlling the local environments around metal ionsFormation, structure, and EPR detection of a high spin Fe(IV)-oxo species derived from either an Fe(III)-oxo or Fe(III)-OH complex.Electron paramagnetic resonance and Mössbauer spectroscopy and density functional theory analysis of a high-spin Fe(IV)-oxo complex.Iron(II) complexes supported by sulfonamido tripodal ligands: endogenous versus exogenous substrate oxidation.A change in the oxidation state of iron: scandium is not innocent.O2 Activation by Non-Heme Iron Enzymes.Functional models of α-keto acid dependent nonheme iron oxygenases: synthesis and reactivity of biomimetic iron(II) benzoylformate complexes supported by a 2,9-dimethyl-1,10-phenanthroline ligand.Characterization of a high-spin non-heme {FeNO}(8) complex: implications for the reactivity of iron nitroxyl species in biology.Oxidation of ethane to ethanol by N2O in a metal-organic framework with coordinatively unsaturated iron(II) sites.Direct photochemical activation of non-heme Fe(iv)[double bond, length as m-dash]O complexes.Interplay of Electronic Cooperativity and Exchange Coupling in Regulating the Reactivity of Diiron(IV)-oxo Complexes towards C-H and O-H Bond Activation.Ethane C-H bond activation on the Fe(iv)-oxo species in a Zn-based cluster of metal-organic frameworks: a density functional theory study.
P2860
Q28834032-2E8C3706-70C4-40C5-A23B-19B964962FE1Q34498588-B36AE8E1-7836-46BD-B117-CE8E90134E99Q34534021-3F119D3F-3494-40B1-8076-B3DC84E993B3Q34728822-48E329BC-224E-4399-8B05-21803DD3ABF1Q34895057-12737D24-E849-4E85-BA4D-F51ABB0FAE53Q34990257-8B03032C-EB07-4670-929F-FC4DA431ECF7Q35067238-57736354-1FB5-40F0-B8F1-3A783DB9C08DQ35147804-BE72F8C7-7879-4000-A360-6C6064065B21Q35332343-9017525C-112A-4351-BE3B-E951C475DB5AQ35974119-C18B4278-2CC7-470B-86AD-0D55D0A03BDFQ36143079-04210D56-C69E-4909-9F31-3D351DDFF9DBQ36221936-2427837F-81FA-4E78-9381-0085FA1052D6Q36448772-87094D5E-5A11-4C2C-98FE-896C4BC52AC8Q36452377-2DA1DCE5-6B2E-4414-92DE-1AA976E40F33Q36482216-610833D3-A7ED-4DE0-B337-0F0B9D7C7D24Q37052683-EA376118-2986-4A91-8040-66B4E0EECE3CQ37407850-6FBBF505-FB57-44A6-A811-31A83D6FB6B1Q37528070-4793BB0F-A966-4297-BDEE-0C4FFBBD5172Q37614806-10D4CD0E-C1EE-414F-A0C2-C31ECF54A8EBQ37641797-55317F30-89DE-4749-8D03-76C22062CFE8Q38287167-8909B695-5E9D-4EFF-AFC8-0D6B37CDD598Q38845297-72B4D68A-6663-4742-9F48-D6228C53669BQ39078942-867FDB3F-0F43-43D7-9FA2-DF6689D422ABQ39363247-08C0B829-CD89-4702-93BF-55B27461AA5BQ39833589-42D81EE3-FE7C-4D32-BEE6-530964CFAEAFQ39907147-A4BED3A6-52F3-4AE1-B5B5-EA7673246EF5Q40965669-0D9BDB94-76B3-455A-AA89-6189484A196EQ41875658-9E00629F-F032-4198-A60D-8790F2BA2382Q42373410-9FEE0CFA-3EE3-43D9-A017-3225E519701BQ42424341-A2BB49EF-3E38-4926-9012-2C01DA43AA93Q42782178-7E069E66-06F9-46FF-8208-83700C9B499BQ42952260-7C434BCC-BD2C-4B43-93F8-37E87DAA939CQ43416231-517A071B-2C12-4CD2-9092-471357E7C5C4Q43534168-07538624-EDFC-4D28-A2C5-B834BF42676EQ44177189-0F0C5CE8-04FB-43DB-B201-1D0E53E6B5D3Q44533584-DF7213FA-8080-415A-BFA5-7D40C1E9A038Q46159368-B86C8A9B-14C2-4459-B237-7822B05CD6A9Q46269557-99357915-5B68-43E1-BF5E-C12A20BE720AQ46367055-3374CA57-FAAD-4B10-8A73-3E3512DC7750Q46430737-052C5DDC-9233-4273-A286-48741449C366
P2860
The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathway
description
2010 nî lūn-bûn
@nan
2010 թուականի Յունիսին հրատարակուած գիտական յօդուած
@hyw
2010 թվականի հունիսին հրատարակված գիտական հոդված
@hy
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
name
The crystal structure of a hig ...... tion of its self-decay pathway
@ast
The crystal structure of a hig ...... tion of its self-decay pathway
@en
type
label
The crystal structure of a hig ...... tion of its self-decay pathway
@ast
The crystal structure of a hig ...... tion of its self-decay pathway
@en
prefLabel
The crystal structure of a hig ...... tion of its self-decay pathway
@ast
The crystal structure of a hig ...... tion of its self-decay pathway
@en
P2093
P2860
P356
P1476
The crystal structure of a hig ...... tion of its self-decay pathway
@en
P2093
Eckard Münck
Erik R Farquhar
Jason England
Lawrence Que
Victor G Young
P2860
P304
P356
10.1021/JA100366C
P407
P50
P577
2010-06-01T00:00:00Z