about
Total synthesis of (+)-roxaticin via C-C bond forming transfer hydrogenation: a departure from stoichiometric chiral reagents, auxiliaries, and premetalated nucleophiles in polyketide construction.Genetic screening strategy for rapid access to polyether ionophore producers and products in actinomycetesThe thiopyran route to polypropionatesSteps towards the synthetic biology of polyketide biosynthesis.Polyketide construction via hydrohydroxyalkylation and related alcohol C-H functionalizations: reinventing the chemistry of carbonyl addition.Progress in Understanding the Genetic Information and Biosynthetic Pathways behind Amycolatopsis Antibiotics, with Implications for the Continued Discovery of Novel Drugs.Super silyl stereo-directing groups for complete 1,5-syn and -anti stereoselectivities in the aldol reactions of beta-siloxy methyl ketones with aldehydes.Diastereoselective Ni-catalyzed 1,4-hydroboration of chiral dienols.Stereoselective one-pot synthesis of polypropionates.A highly enantio- and diastereoselective 1,3-dimethylallylation of aldehydes.Total synthesis of (+)-trienomycins A and F via C-C bond-forming hydrogenation and transfer hydrogenation.The supersilyl group as a carboxylic acid protecting group: application to highly stereoselective aldol and Mannich reactions.Rapid total syntheses utilizing "supersilyl" chemistry.β-Siloxy-α-haloketones through highly diastereoselective single and double mukaiyama aldol reactions.An Effective Bifunctional Aldehyde Linchpin for Type II Anion Relay Chemistry: Development and Application to the Synthesis of a C16-C29 Fragment of Rhizopodin.A triple-aldol cascade reaction for the rapid assembly of polyketides.Rapid and stereochemically flexible synthesis of polypropionates: super-silyl-governed aldol cascades.Diastereo- and enantioselective ruthenium-catalyzed hydrohydroxyalkylation of 2-silyl-butadienes: carbonyl syn-crotylation from the alcohol oxidation level.Direct generation of acyclic polypropionate stereopolyads via double diastereo- and enantioselective iridium-catalyzed crotylation of 1,3-diols: beyond stepwise carbonyl addition in polyketide construction.Stereoselective construction of all-anti polypropionate modules: synthesis of the C5-C10 fragment of streptovaricin U.Synthesis of 3-hydroxy-5-alkoxyhomophthalates by domino '2 : 1-coupling/intramolecular aldol condensation' reactions of 1,3-bis(trimethylsilyloxy)-1,3-butadienes with tetraalkoxymethanes.Emergent Catalytic Behavior of Self-Assembled Low Molecular Weight Peptide-Based Aggregates and Hydrogels.Iterative assembly line synthesis of polypropionates with full stereocontrol.Stereocontrolled Synthesis of Polypropionate Fragments based on a Building Block Assembly Strategy using Lithiation-Borylation Methodologies.Ru-catalyzed hydrogenation of 3,5-diketo amides: simultaneous control of chemo- and enantioselectivity
P2860
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P2860
description
2005 nî lūn-bûn
@nan
2005年の論文
@ja
2005年学术文章
@wuu
2005年学术文章
@zh-cn
2005年学术文章
@zh-hans
2005年学术文章
@zh-my
2005年学术文章
@zh-sg
2005年學術文章
@yue
2005年學術文章
@zh
2005年學術文章
@zh-hant
name
Polyketide stereotetrads in natural products.
@ast
Polyketide stereotetrads in natural products.
@en
type
label
Polyketide stereotetrads in natural products.
@ast
Polyketide stereotetrads in natural products.
@en
prefLabel
Polyketide stereotetrads in natural products.
@ast
Polyketide stereotetrads in natural products.
@en
P356
P1476
Polyketide stereotetrads in natural products
@en
P2093
Kaisa Karisalmi
P304
P356
10.1039/B417466F
P50
P577
2005-04-25T00:00:00Z