A triple-aldol cascade reaction for the rapid assembly of polyketides.
about
Bioinspired iterative synthesis of polyketidesSynthesis of 2-isoxazolines: enantioselective and racemic methods based on conjugate additions of oximes.Assembly-line synthesis of organic molecules with tailored shapesEnantioselective aldol reactions catalyzed by chiral phosphine oxides.The impact of the Mukaiyama aldol reaction in total synthesis.Lessons from the synthetic chemist nature.Rapid, one-pot synthesis of β-siloxy-α-haloaldehydes.Super silyl stereo-directing groups for complete 1,5-syn and -anti stereoselectivities in the aldol reactions of beta-siloxy methyl ketones with aldehydes.Short Enantioselective Total Synthesis of Tatanan A and 3-epi-Tatanan A Using Assembly-Line Synthesis.Asymmetric Synthesis of Dipropionate Derivatives through Catalytic Hydrogenation of Enantioenriched E-Ketene Heterodimers.Iodonium metathesis reactions.The supersilyl group as a carboxylic acid protecting group: application to highly stereoselective aldol and Mannich reactions.Rapid total syntheses utilizing "supersilyl" chemistry.β-Siloxy-α-haloketones through highly diastereoselective single and double mukaiyama aldol reactions.Stereodivergent approach to the avermectins based on "super silyl" directed aldol reactionsRapid and stereochemically flexible synthesis of polypropionates: super-silyl-governed aldol cascades.Synthesis of β-hydroxy-α-haloesters through super silyl ester directed syn-selective aldol reaction.Direct generation of acyclic polypropionate stereopolyads via double diastereo- and enantioselective iridium-catalyzed crotylation of 1,3-diols: beyond stepwise carbonyl addition in polyketide construction.Generation of organolithium compounds bearing super silyl ester and their application to Matteson rearrangement.The calculation of (29)Si NMR chemical shifts of tetracoordinated silicon compounds in the gas phase and in solution.Versatile process for the stereodiverse construction of 1,3-polyols: iterative chain elongation with chiral building blocks.Copper-Catalyzed Oxy-Alkenylation of Homoallylic Alcohols to Generate Functional syn-1,3-Diol Derivatives.Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes: a cationic cascade cyclization.Enantioselective double aldol reaction catalyzed by chiral phosphine oxide.A highly diastereoselective "super silyl" governed aldol reaction: synthesis of α,β-dioxyaldehydes and 1,2,3-triols.Rh-Catalyzed AldehydeAldehyde Cross-Aldol Reaction under Base-Free Conditions: In Situ Aldehyde-Derived Enolate Formation through Orthogonal ActivationRhodium-Catalyzed Cross-Aldol Reaction: In Situ Aldehyde-Enolate Formation from Allyloxyboranes and Primary Allylic AlcoholsRhodium-Catalyzed Cross-Aldol Reaction: In Situ Aldehyde-Enolate Formation from Allyloxyboranes and Primary Allylic Alcohols
P2860
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P2860
A triple-aldol cascade reaction for the rapid assembly of polyketides.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
A triple-aldol cascade reaction for the rapid assembly of polyketides.
@en
A triple-aldol cascade reaction for the rapid assembly of polyketides.
@nl
type
label
A triple-aldol cascade reaction for the rapid assembly of polyketides.
@en
A triple-aldol cascade reaction for the rapid assembly of polyketides.
@nl
prefLabel
A triple-aldol cascade reaction for the rapid assembly of polyketides.
@en
A triple-aldol cascade reaction for the rapid assembly of polyketides.
@nl
P2860
P356
P1476
A triple-aldol cascade reaction for the rapid assembly of polyketides.
@en
P2093
Brian J Albert
Hisashi Yamamoto
P2860
P304
P356
10.1002/ANIE.200907076
P407
P577
2010-04-01T00:00:00Z