A Mononuclear Carboxylate-Rich Oxoiron(IV) Complex: a Structural and Functional Mimic of TauD Intermediate 'J'
about
High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe(IV)=O Complexes.Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity.Molecular imaging of labile iron(II) pools in living cells with a turn-on fluorescent probe.Dichotomous hydrogen atom transfer vs proton-coupled electron transfer during activation of X-H bonds (X = C, N, O) by nonheme iron-oxo complexes of variable basicityDo Spin State and Spin Density Affect Hydrogen Atom Transfer Reactivity?Applications of density functional theory to iron-containing molecules of bioinorganic interest.Dramatically accelerated selective oxygen-atom transfer by a nonheme iron(IV)-oxo complex: tuning of the first and second coordination spheresAromatic C-F Hydroxylation by Nonheme Iron(IV)-Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations.Secondary coordination sphere influence on the reactivity of nonheme iron(II) complexes: an experimental and DFT approach.Controlled ligand distortion and its consequences for structure, symmetry, conformation and spin-state preferences of iron(II) complexes.Mechanistic elucidation of C-H oxidation by electron rich non-heme iron(IV)-oxo at room temperature.The mechanism of stereospecific C-H oxidation by Fe(Pytacn) complexes: bioinspired non-heme iron catalysts containing cis-labile exchangeable sites.A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N3 O Macrocyclic Ligand.A Non-Heme Iron Photocatalyst for Light-Driven Aerobic Oxidation of Methanol.Spontaneous reduction of mononuclear high-spin iron(III) complexes to mononuclear low-spin iron(II) complexes in aqueous media and nuclease activity via self-activation.A Highly Reactive Oxoiron(IV) Complex Supported by a Bioinspired N3 O Macrocyclic Ligand
P2860
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P2860
A Mononuclear Carboxylate-Rich Oxoiron(IV) Complex: a Structural and Functional Mimic of TauD Intermediate 'J'
description
2012 nî lūn-bûn
@nan
2012年の論文
@ja
2012年学术文章
@wuu
2012年学术文章
@zh-cn
2012年学术文章
@zh-hans
2012年学术文章
@zh-my
2012年学术文章
@zh-sg
2012年學術文章
@yue
2012年學術文章
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2012年學術文章
@zh-hant
name
A Mononuclear Carboxylate-Rich ...... Mimic of TauD Intermediate 'J'
@ast
A Mononuclear Carboxylate-Rich ...... Mimic of TauD Intermediate 'J'
@en
type
label
A Mononuclear Carboxylate-Rich ...... Mimic of TauD Intermediate 'J'
@ast
A Mononuclear Carboxylate-Rich ...... Mimic of TauD Intermediate 'J'
@en
prefLabel
A Mononuclear Carboxylate-Rich ...... Mimic of TauD Intermediate 'J'
@ast
A Mononuclear Carboxylate-Rich ...... Mimic of TauD Intermediate 'J'
@en
P2093
P2860
P50
P356
P1433
P1476
A Mononuclear Carboxylate-Rich ...... Mimic of TauD Intermediate 'J'
@en
P2093
Eckard Münck
Emile L Bominaar
Lawrence Que
P2860
P304
P356
10.1039/C2SC01044E
P577
2012-02-20T00:00:00Z