Terminal hydride in [FeFe]-hydrogenase model has lower potential for H2 production than the isomeric bridging hydride.
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Proton-coupled electron transferTerminal vs bridging hydrides of diiron dithiolates: protonation of Fe2(dithiolate)(CO)2(PMe3)4.Small molecule mimics of hydrogenases: hydrides and redox.Artificial hydrogenases.Computational investigation of [FeFe]-hydrogenase models: characterization of singly and doubly protonated intermediates and mechanistic insights.Reaction of Aryl Diazonium Salts and Diiron(I) Dithiolato Carbonyls: Evidence for Radical Intermediates.Combining acid-base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase.Stereochemistry of electrophilic attack at 34e⁻ dimetallic complexes: the case of diiron dithiolato carbonyls + MeS⁺.Isomerization of the hydride complexes [HFe2(SR)2(PR3)(x)(CO)(6-x)]+ (x = 2, 3, 4) relevant to the active site models for the [FeFe]-hydrogenasesSynthetic models for the active site of the [FeFe]-hydrogenase: catalytic proton reduction and the structure of the doubly protonated intermediate.Nickel phlorin intermediate formed by proton-coupled electron transfer in hydrogen evolution mechanism.Diiron azadithiolates as models for the [FeFe]-hydrogenase active site and paradigm for the role of the second coordination sphereProton reduction to hydrogen in biological and chemical systems.Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.[FeFe] hydrogenase: protonation of {2Fe3S} systems and formation of super-reduced hydride states.Hydride-containing models for the active site of the nickel-iron hydrogenases.Hydrogen activation by biomimetic diiron dithiolates.Aza- and oxadithiolates are probable proton relays in functional models for the [FeFe]-hydrogenases.Di/mono-nuclear iron(I)/(II) complexes as functional models for the 2Fe2S subunit and distal Fe moiety of the active site of [FeFe] hydrogenases: protonations, molecular structures and electrochemical properties.Bridging-hydride influence on the electronic structure of an [FeFe] hydrogenase active-site model complex revealed by XAES-DFT.Biomimetic model for [FeFe]-hydrogenase: asymmetrically disubstituted diiron complex with a redox-active 2,2'-bipyridyl ligand.Isolation, observation, and computational modeling of proposed intermediates in catalytic proton reductions with the hydrogenase mimic Fe2(CO)6S2C6H4.Mechanistic studies on proton transfer in a [FeFe] hydrogenase mimic complex.Copper complexes as catalyst precursors in the electrochemical hydrogen evolution reaction.Interplay between Terminal and Bridging Diiron Hydrides in Neutral and Oxidized States.Reactions of [FeFe]-hydrogenase models involving the formation of hydrides related to proton reduction and hydrogen oxidation.Sterically Stabilized Terminal Hydride of a Diiron Dithiolate.Selenium makes the difference: protonation of [FeFe]-hydrogenase mimics with diselenolato ligands.Electronic and molecular structure relations in diiron compounds mimicking the [FeFe]-hydrogenase active site studied by X-ray spectroscopy and quantum chemistry.Hyperfine interactions and electron distribution in Fe(II)Fe (I) and Fe (I)Fe (I) models for the active site of the [FeFe] hydrogenases: Mössbauer spectroscopy studies of low-spin Fe(I.).[FeFe]-Hydrogenase H-Cluster Mimics with Unique Planar μ-(SCH2 )2 ER2 Linkers (E=Ge and Sn).Highly functionalizable penta-coordinate iron hydrogen production catalysts with low overpotentials.Interplay of hemilability and redox activity in models of hydrogenase active sites.
P2860
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P2860
Terminal hydride in [FeFe]-hydrogenase model has lower potential for H2 production than the isomeric bridging hydride.
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年論文
@yue
2008年論文
@zh-hant
2008年論文
@zh-hk
2008年論文
@zh-mo
2008年論文
@zh-tw
2008年论文
@wuu
2008年论文
@zh
2008年论文
@zh-cn
name
Terminal hydride in [FeFe]-hyd ...... the isomeric bridging hydride.
@ast
Terminal hydride in [FeFe]-hyd ...... the isomeric bridging hydride.
@en
type
label
Terminal hydride in [FeFe]-hyd ...... the isomeric bridging hydride.
@ast
Terminal hydride in [FeFe]-hyd ...... the isomeric bridging hydride.
@en
prefLabel
Terminal hydride in [FeFe]-hyd ...... the isomeric bridging hydride.
@ast
Terminal hydride in [FeFe]-hyd ...... the isomeric bridging hydride.
@en
P2860
P356
P1433
P1476
Terminal hydride in [FeFe]-hyd ...... the isomeric bridging hydride.
@en
P2093
Bryan E Barton
Thomas B Rauchfuss
P2860
P304
P356
10.1021/IC800030Y
P407
P577
2008-03-12T00:00:00Z